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1. 发明授权

US08445594B2 High-density polyethylene compositions, method of making the same, articles made therefrom, and method of making such articles 有权
标题翻译：高密度聚乙烯组合物，其制造方法，由其制成的制品及其制造方法
公开(公告)号：US08445594B2
公开(公告)日：2013-05-21
申请号：US12067832
申请日：2007-05-02
申请人： William J. Michie, Jr. , Thomas W. Kay , Stephanie M. Whited , Dale M. Elley-Bristow , David T. Gillespie , Lonnie G. Hazlitt
发明人： William J. Michie, Jr. , Thomas W. Kay , Stephanie M. Whited , Dale M. Elley-Bristow , David T. Gillespie , Lonnie G. Hazlitt
IPC分类号： C08F8/00 , C08L23/04
CPC分类号： C08L23/08 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2203/10 , Y10T428/24992 , Y10T428/273 , C08L2666/06
摘要： The instant invention is a high-density polyethylene composition, method of producing the same, articles made therefrom, and method of making such articles. The high-density polyethylene composition of the instant invention includes a first component, and a second component. The first component is a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm3, and a melt index (I21.6) in the range of 0.5 to 10 g/10 minutes. The second component is a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm3, and a melt index (I2) in the range of 50 to 1500 g/10 minutes. The high-density polyethylene composition has a melt index (I2) of at least 1, a density in the range of 0.950 to 0.960 g/cm3, and g′ of 1.
摘要翻译：本发明是高密度聚乙烯组合物，其制造方法，由其制成的制品及其制造方法。本发明的高密度聚乙烯组合物包括第一组分和第二组分。第一组分是密度在0.915至0.940g / cm 3范围内的熔融指数（I 21.6）在0.5至10g / 10分钟范围内的高分子量乙烯α-烯烃共聚物。第二组分是密度在0.965至0.980g / cm 3范围内的熔融指数（I 2）在50至1500g / 10分钟范围内的低分子量乙烯聚合物。高密度聚乙烯组合物的熔体指数（I 2）至少为1，密度在0.950至0.960g / cm3，g'为1。

2. 发明授权

US07847029B2 Elastomeric resin compositions with improved resistance to draw resonance 有权
标题翻译：具有改善的拉伸共振阻力的弹性体树脂组合物
公开(公告)号：US07847029B2
公开(公告)日：2010-12-07
申请号：US11722526
申请日：2005-12-23
申请人： Thomas I. Butler , Andy C. Chang , Jozef J. I. Van Dun , Ronald J. Weeks , Jeffrey D. Weinhold , Rajen M. Patel , David T. Gillespie
发明人： Thomas I. Butler , Andy C. Chang , Jozef J. I. Van Dun , Ronald J. Weeks , Jeffrey D. Weinhold , Rajen M. Patel , David T. Gillespie
IPC分类号： C08L23/00 , C08L23/04 , C08F8/00 , C08F110/02
CPC分类号： C08L23/0815 , C08L23/06 , C08L2666/06
摘要： This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines due to improved resistance to draw resonance. The compositions of the present invention comprise an elastomeric polyolefin resin and a high pressure low density type resin. The preferred compositions of the present invention comprise from 88 to 99 percent elastomer or plastomer and from 1 to 12 percent by weight of a high pressure low density type resin.
摘要翻译：本发明涉及聚烯烃组合物。特别地，本发明涉及弹性聚合物组合物，其可以由于提高的拉伸共振抗性而更容易地在流延膜线，挤出层压或涂布线上加工。本发明的组合物包含弹性聚烯烃树脂和高压低密度树脂。本发明的优选组合物包含88-99％的弹性体或塑性体和1-12％（重量）的高压低密度型树脂。

3. 发明申请

US20080125553A1 Process For Producing Low Density Polyethylene Compositions and Polymers Produced Therefrom 有权
标题翻译：生产低密度聚乙烯组合物和聚合物的方法
公开(公告)号：US20080125553A1
公开(公告)日：2008-05-29
申请号：US11666527
申请日：2005-10-04
申请人： Christopher W. Conrad , David T. Gillespie , Christopher R. Eddy
发明人： Christopher W. Conrad , David T. Gillespie , Christopher R. Eddy
IPC分类号： C08F10/02 , C08F2/02
CPC分类号： C08F110/02 , C08F4/34 , C08F2/001 , C08F2500/12 , C08F2500/11 , C08F2500/04
摘要： The present invention relates to an ethylene homo or copolymer characterized as having long chain branching, and having a molecular weight distribution, Mw/Mn, and a GPC-LALLS CDF, which satisfies the following relationship: y≧0.0663x-0.015, wherein y=GPC-LALLS CDF and x=Mw/Mn measured by conventional GPC, a line drawn from where the LS chromatogram intersects with molecular weight 350,000 and molecular weight 1,150,000 has a positive slope, preferably with a melt index between 0.15 and 2000 g/10 minutes and having long chain branching. In addition, the invention relates to a free radical initiation polymerization process for the preparation of ethylene polymers or copolymers, comprising reacting ethylene and optionally one or more comonomers at a high pressure, conveniently between 13,000 psig and 100,000 psig, and at reactor temperatures of 115° C. to 400° C., preferably 125-400° C., more preferably 140-350° C., especially 165-320° C., in a reactor system comprising at least one tubular, and at least one autoclave reactor, wherein the monomer(s) feed into the reactors is divided into multiple monomer feed streams, and wherein at least one feed stream into the tubular reactor consists essentially of unreacted monomer.
摘要翻译：本发明涉及特征在于具有长支链，并具有分子量分布Mw / Mn和GPC-LALLS CDF的乙烯均聚物或共聚物，其满足以下关系：y> = 0.0663x-0.015，其中 y = GPC-LALLS CDF和x =通过常规GPC测量的Mw / Mn，从其中LS色谱图与分子量为350,000和分子量为1,150,000相交的线绘制的线具有正斜率，优选熔体指数在0.15和2000g / 10分钟，具有长链分支。此外，本发明涉及用于制备乙烯聚合物或共聚物的自由基引发聚合方法，包括使乙烯和任选的一种或多种共聚单体在高压下，方便地在13000psig至100,000psig之间，反应器温度为115℃ 在包含至少一个管状和至少一个高压釜反应器的反应器系统中，在约400℃，优选125-400℃，更优选140-350℃，特别是165-320℃ ，其中进入反应器的单体被分成多个单体进料流，并且其中至少一个进入管式反应器的进料流基本上由未反应的单体组成。

4. 发明授权

US08076421B2 Film layers made from polymer formulations 有权
标题翻译：由聚合物配方制成的薄膜层
公开(公告)号：US08076421B2
公开(公告)日：2011-12-13
申请号：US10590750
申请日：2005-03-18
申请人： Mridula Kapur , David A. Eversdyk , Wenbin Liang , Kenneth S. Laverdure , David T. Gillespie
发明人： Mridula Kapur , David A. Eversdyk , Wenbin Liang , Kenneth S. Laverdure , David T. Gillespie
IPC分类号： C08L23/00 , C08L23/04 , C08L23/08
CPC分类号： C08J5/18 , B32B27/00 , C08J2323/08 , C08L23/06 , C08L23/0815 , C08L2205/02 , Y10T428/31938 , C08L2666/06
摘要： Film layers made from formulated polymer compositions are disclosed. Film layers made from such formulated compositions have surprisingly good (for example, low) water vapor transmission rates and are particularly useful for packaging dry goods such as cereal. The polymer compositions preferably have at least one homogeneous ethylene homopolymer and at least one heterogeneously branched ethylene polymer. The homogeneous ethylene homopolymer has a molecular weight much higher than that of the heterogeneously branched ethylene polymer, although the density of each is preferably higher than about 0.95 g/cm3.
摘要翻译：公开了由配制的聚合物组合物制成的薄膜层。由这种配制的组合物制成的薄膜层具有惊人的良好（例如，低）水蒸汽透过率，并且特别适用于包装诸如谷物的干货。聚合物组合物优选具有至少一种均匀的乙烯均聚物和至少一种非均匀支化的乙烯聚合物。均匀的乙烯均聚物的分子量远高于非均匀支化的乙烯聚合物的分子量，尽管它们的密度优选高于约0.95g / cm 3。

5. 发明申请

US20080293890A1 Elastomeric Resin Compositions with Improved Resistance to Draw Resonance 有权
标题翻译：具有改善的拉伸共振抗性的弹性体树脂组合物
公开(公告)号：US20080293890A1
公开(公告)日：2008-11-27
申请号：US11722526
申请日：2005-12-23
申请人： Thomas I. Butler , Andy C. Chang , Jozef J. I. Van Dun , Ronald J. Weeks , Jeffrey D. Weinhold , Rajen M. Patel , David T. Gillespie
发明人： Thomas I. Butler , Andy C. Chang , Jozef J. I. Van Dun , Ronald J. Weeks , Jeffrey D. Weinhold , Rajen M. Patel , David T. Gillespie
IPC分类号： C08L23/12 , C08L23/06
CPC分类号： C08L23/0815 , C08L23/06 , C08L2666/06
摘要： This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines due to improved resistance to draw resonance. The compositions of the present invention comprise an elastomeric polyolefin resin and a high pressure low density type resin. The preferred compositions of the present invention comprise from 88 to 99 percent elastomer or plastomer and from 1 to 12 percent by weight of a high pressure low density type resin.
摘要翻译：本发明涉及聚烯烃组合物。特别地，本发明涉及弹性聚合物组合物，其可以由于提高的拉伸共振抗性而更容易地在流延膜线，挤出层压或涂布线上加工。本发明的组合物包含弹性聚烯烃树脂和高压低密度树脂。本发明的优选组合物包含88-99％的弹性体或塑性体和1-12％（重量）的高压低密度型树脂。

6. 发明申请

US20080166817A1 Apparatus and Method for Polymer Characterization 有权
标题翻译：聚合物表征的装置和方法
公开(公告)号：US20080166817A1
公开(公告)日：2008-07-10
申请号：US11794417
申请日：2006-01-19
申请人： David T. Gillespie , Colin Li Pi Shan , Lonnie G. Hazlitt , Alexander W. Degroot , Peter B. Arnoudse , Charles Allen Williams
发明人： David T. Gillespie , Colin Li Pi Shan , Lonnie G. Hazlitt , Alexander W. Degroot , Peter B. Arnoudse , Charles Allen Williams
IPC分类号： G01N21/47 , G01N30/02
CPC分类号： G01N30/468 , G01N25/147 , G01N30/463 , G01N30/54 , G01N33/442 , G01N2030/008 , G01N2030/3007
摘要： Apparatus for GPC/TREF and TREF/GPC characterization of a polymer sample. The apparatus provides for the automated and integrated use of multiple TREF columns and a GPC system employing a multiple flow through detectors. In addition, a method for TREF/GPC characterization of a polymer sample by GPC analysis of TREF fractions at increasing TREF elution temperatures from multiple TREF columns operated in a coordinated and synchronized temperature cycle for increased sample throughput. Also, a method for GPC/TREF characterization of a polymer sample by GPC fractionation followed by TREF fractionation of the GPC fractionations.
摘要翻译：用于GPC / TREF和TREF / GPC表征聚合物样品的装置。该装置提供了多个TREF柱的自动化和集成使用以及采用多个流过检测器的GPC系统。此外，通过在增加TREF洗脱温度的TREF洗脱温度下，通过GPC分析TREF级分，通过在协同和同步的温度循环中操作以提高样品通量的多个TREF柱来对聚合物样品进行TREF / GPC表征的方法。此外，通过GPC分级随后进行GPC分馏的TREF分馏，GPC / TREF表征聚合物样品的方法。

7. 发明授权

US07776987B2 Resin compositions for extrusion coating 有权
标题翻译：用于挤出涂层的树脂组合物
公开(公告)号：US07776987B2
公开(公告)日：2010-08-17
申请号：US10566937
申请日：2004-09-03
申请人： Thomas Oswald , James L. Cooper , Jeffrey D. Weinhold , David T. Gillespie
发明人： Thomas Oswald , James L. Cooper , Jeffrey D. Weinhold , David T. Gillespie
IPC分类号： C08F110/02 , C08F8/00 , C08L23/00 , C08L23/04
CPC分类号： C09D123/08 , C08J5/18 , C08J2300/00 , C08J2323/06 , C08L23/06 , C08L23/08 , C08L23/0815 , C09D123/06 , C08L2666/06
摘要： A composition is disclosed which is particularly suited for use in extrusion coating. The composition comprises a polymeric material having a rheology such that the slope S of a natural log-natural log plot of loss modulus (or G″) versus storage modulus (or G′) is greater than [0.635*(melt index)+13.2]/[(melt index)+16.6], and wherein the polymeric material has a CDF RI fraction less than 0.23 of a GPC chromatogram which has a molecular weight above 85,000 g/mol, and a CDF LS fraction of more than 0.07 at a conventional GPC molecular weight of 1,750,000 g/mol or greater. The compositions exhibit reduced neck-in when used in extrusion coating and the neck-in is independent of melt strength, thereby facilitating improved extrusion processes.
摘要翻译：公开了一种特别适用于挤出涂层的组合物。组合物包含具有流变学性质的聚合材料，使得损耗模量（或G“）对储能模量（或G'）的自然对数 - 自然对数图的斜率S大于[0.635 *（熔体指数）+13.2 ] / [（熔体指数）+16.6]，其中聚合物材料的CDF RI分数低于GPC色谱图的0.23，其分子量高于85,000g / mol，且在常规GPC分子量为1750,000g / mol以上。当用于挤出涂布时，组合物显示减少的颈缩，并且颈缩不依赖于熔体强度，从而有助于改进挤出工艺。

8. 发明申请

US20100056727A1 POLYOLEFIN COMPOSITIONS, ARTICLES MADE THEREFROM AND METHODS FOR PREPARING THE SAME 审中-公开
标题翻译：聚烯烃组合物及其制备方法及其制备方法
公开(公告)号：US20100056727A1
公开(公告)日：2010-03-04
申请号：US12064308
申请日：2006-08-18
申请人： Colin LiPiShan , Mridula (Babli) Kapur , Stephane Costeux , David T. Gillespie
发明人： Colin LiPiShan , Mridula (Babli) Kapur , Stephane Costeux , David T. Gillespie
IPC分类号： C08L23/06
CPC分类号： C08L23/08 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2666/06
摘要： The invention provides compositions for blow molding applications and other applications, where such compositions comprise a high density ethylene polymer and a high molecular weight ethylene polymer. In these compositions, the high density ethylene polymer has a density greater than the density of the high molecular weight ethylene polymer, and the high molecular weight ethylene polymer has a weight average molecular weight greater than the weight average molecular weight of the high density ethylene polymer, and in addition, the high density ethylene polymer has a density from 0.94 g/cm3 to 0.98 g/cm3, and a molecular weight distribution, Mw/Mn, greater than 8, and the high molecular weight ethylene polymer has a weight average molecular weight greater than 200,000 g/mole, and a molecular weight ratio, Mz/Mw, less than 5.
摘要翻译：本发明提供用于吹塑应用和其它应用的组合物，其中这种组合物包含高密度乙烯聚合物和高分子量乙烯聚合物。在这些组合物中，高密度乙烯聚合物的密度大于高分子量乙烯聚合物的密度，高分子量乙烯聚合物的重均分子量大于高密度乙烯聚合物的重均分子量另外，高密度乙烯聚合物的密度为0.94g / cm 3至0.98g / cm 3，分子量分布Mw / Mn大于8，高分子量乙烯聚合物的重均分子量重量大于200,000g / mol，分子量比Mz / Mw小于5。

9. 发明申请

US20080221273A1 High-Density Polyethylene Compositions, Method of Making the Same, Articles Made Therefrom, and Method of Making Such Articles 有权
公开(公告)号：US20080221273A1
公开(公告)日：2008-09-11
申请号：US12067832
申请日：2007-05-02
申请人： William J. Michie Jr. , Thomas W. Kay , Stephanie M. Whited , Dale M. Elley-Bristow , David T. Gillespie , Lonnie G. Hazlitt
发明人： William J. Michie Jr. , Thomas W. Kay , Stephanie M. Whited , Dale M. Elley-Bristow , David T. Gillespie , Lonnie G. Hazlitt
IPC分类号： C08L23/04 , C08F2/00 , B29C43/00 , B29C45/00
CPC分类号： C08L23/08 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2203/10 , Y10T428/24992 , Y10T428/273 , C08L2666/06
摘要： The instant invention is a high-density polyethylene compositions, and method of making the same. The high-density polyethylene composition of the instant invention includes a first component, and a second component. The first component is a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm3, and a melt index (I21) in the range of 0.5 to 10 g/10 minutes. The second component is a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm3, and a melt index (I2) in the range of 50 to 1500 g/10 minutes. The high-density polyethylene composition has a melt index (I2) of at least 1, a density in the range of 0.950 to 0.960 g/cm3, and g′ of equal or greater than 1. The method of producing a high-density polyethylene composition include the following steps: (1) introducing ethylene, and an alpha-olefin comonomer into a first reactor; (2) copolymerizing the ethylene with the alpha-olefin comonomer in the first reactor thereby producing a first component, wherein the first component being a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm3, and a melt index (I21) in the range of 0.5 to 10 g/10 minutes; (3) introducing the first component and additional ethylene into a second reactor; (4) polymerizing the additional ethylene in the second reactor thereby producing a second component, wherein the second component being a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm3, and a melt index (I2) in the range of 50 to 1500 g/10 minutes; and (5) thereby producing the high-density polyethylene composition, wherein the high-density polyethylene composition having a melt index (I2) of at least 1, a density in the range of 0.950 to 0.960 g/cm3, and g′ of equal or greater than 1.

10. 发明授权

US08323569B2 Apparatus for method for polymer characterization 有权
标题翻译：用于聚合物表征的方法的装置
公开(公告)号：US08323569B2
公开(公告)日：2012-12-04
申请号：US13160883
申请日：2011-06-15
申请人： David T. Gillespie , Colin Lipishan , Lonnie G. Hazlitt , Alexander W. Degroot , Peter B. Arnoudse , Charles A. Williams
发明人： David T. Gillespie , Colin Lipishan , Lonnie G. Hazlitt , Alexander W. Degroot , Peter B. Arnoudse , Charles A. Williams
IPC分类号： G01N30/02 , G01N30/30
CPC分类号： G01N30/468 , G01N25/147 , G01N30/463 , G01N30/54 , G01N33/442 , G01N2030/008 , G01N2030/3007
摘要： Apparatus for GPC/TREF and TREF/GPC characterization of a polymer sample. The apparatus provides for the automated and integrated use of multiple TREF columns and a GPC system employing a multiple flow through detectors. In addition, a method for TREF/GPC characterization of a polymer sample by GPC analysis of TREF fractions at increasing TREF elution temperatures from multiple TREF columns operated in a coordinated and synchronized temperature cycle for increased sample throughput. Also, a method for GPC/TREF characterization of a polymer sample by GPC fractionation followed by TREF fractionation of the GPC fractionations.
摘要翻译：用于GPC / TREF和TREF / GPC表征聚合物样品的装置。该装置提供了多个TREF柱的自动化和集成使用以及采用多个流过检测器的GPC系统。此外，通过在增加TREF洗脱温度的TREF洗脱温度下，通过GPC分析TREF级分，通过在协同和同步的温度循环中操作以提高样品通量的多个TREF柱来对聚合物样品进行TREF / GPC表征的方法。此外，通过GPC分级随后进行GPC分馏的TREF分馏，GPC / TREF表征聚合物样品的方法。

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