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    • 3. 发明授权
    • System and method for in-line molten metal processing using salt reactant in a deep box degasser
    • 在深箱式脱气机中使用盐反应物进行在线熔融金属加工的系统和方法
    • US07785394B2
    • 2010-08-31
    • US12035848
    • 2008-02-22
    • Dawn Corleen ChesonisDavid H. DeYoung
    • Dawn Corleen ChesonisDavid H. DeYoung
    • C22B9/05C22B9/10C22B21/06C22B26/22
    • C22B9/103C22B9/05C22B9/055C22B21/062C22B21/064C22B21/066
    • An in-line deep box treatment of molten metal wherein, instead of gaseous Cl2, a solid salt reactant containing a halide salt (e.g., MgCl2) as one of its components may be injected into the molten metal along with an inert gas (typically argon) through the existing degasser impellor. The salt flux may be metered into the inert gas stream at a controlled rate. A salt injector flux tank may be retrofitted to current rotary degassing equipments without requiring a specialized rotor design or changes in the degasser unit design. Using the halide salt-based solid flux, the benefits of alkali, alkaline earth, and inclusion removal may be achieved without the industrial hygiene, environmental, and safety issues associated with storing and using the gaseous and hazardous Cl2 during molten metal degassing.
    • 熔融金属的在线深箱处理,其中代替气态Cl 2,含有作为其组分之一的卤化物盐(例如,MgCl 2)的固体盐反应物可以与惰性气体(典型地为氩气)一起注入熔融金属 )通过现有的脱气机。 可以以受控的速率将盐通量计量加入到惰性气体流中。 盐喷射器通量罐可以改装到当前的旋转脱气设备,而不需要专门的转子设计或脱气器单元设计的改变。 使用基于卤化物盐的固体助熔剂,可以实现碱金属,碱土金属和夹杂物去除的优点,而不会在熔融金属脱气过程中储存和使用气态和危险的Cl2相关的工业卫生,环境和安全问题。
    • 5. 发明授权
    • Three-stage process for burning fuel containing sulfur to reduce
emission of particulates and sulfur-containing gases
    • 燃烧含硫燃料以减少颗粒物和含硫气体排放的三阶段工艺
    • US4542704A
    • 1985-09-24
    • US681672
    • 1984-12-14
    • Melvin H. BrownDavid H. DeYoung
    • Melvin H. BrownDavid H. DeYoung
    • C10L9/10C10L1/12C10L1/32C10L10/00F23B99/00F23C6/04F23C99/00F23D1/00
    • F23C6/04C10L1/326
    • A three-stage combustion process is disclosed for burning a fuel containing sulfur characterized by low sulfur emission and good ash removal. The process comprises mixing the sulfur containing fuel with an additive capable of reacting with sulfur; burning the mixture in a first combustion stage with less than 75% theoretical air and at a temperature below the melting point of the ash but sufficiently high to cause reaction between the additive and any sulfur in the fuel to facilitate removal of the sulfur compounds formed; removing at least a portion of the sulfur compounds formed in the first stage; passing combustible gases from the first stage to a second stage; burning the gases in the second stage with less than 100% theoretical air at a temperature above the melting point of the ash to form a liquid slag which is removable from the second stage; and burning combustible gases from the second stage in a third stage with an excess of air to ensure complete combustion of the fuel.
    • 公开了一种三级燃烧过程,用于燃烧含硫的燃料,其特征在于低硫排放和良好的除灰。 该方法包括将含硫燃料与能够与硫反应的添加剂混合; 在低于75%的理论空气和低于灰分熔点的温度的第一燃烧阶段中燃烧混合物,但足够高以使添加剂与燃料中任何硫之间的反应促进所形成的硫化合物的除去; 去除在第一阶段中形成的至少一部分硫化合物; 将可燃气体从第一阶段传递到第二阶段; 在高于灰分熔点的温度下以小于100%的理论空气燃烧第二阶段的气体以形成可从第二阶段移除的液态炉渣; 并在第三级燃烧具有过量空气的第二级的可燃气体,以确保燃料的完全燃烧。
    • 6. 发明授权
    • Aluminum alloys having improved cast surface quality
    • 具有改善的铸造表面质量的铝合金
    • US06412164B1
    • 2002-07-02
    • US09685283
    • 2000-10-10
    • David H. DeYoungWilliam F. McGinnisRay T. RichterJeffrey J. Wiesner
    • David H. DeYoungWilliam F. McGinnisRay T. RichterJeffrey J. Wiesner
    • B22D700
    • C22C1/03C22C1/026C22C21/00Y10T29/49988
    • Aluminum alloy compositions are disclosed, which include small amounts of calcium that result in improved surface properties of the cast aluminum. The calcium, and up to 0.25% grain refiners, are added along with alkaline earth metals, transition metals and/or rare earth metals to the aluminum alloy as a melt. The addition results in improved appearance, substantially reduced surface imperfections and reduced surface oxidation in cast ingot aluminum and aluminum alloys. The addition of small amounts of these additives, surprisingly were found to substantially eliminate vertical folds, pits and ingot cracking in more than one ingot casting technique. The additions also improved the appearance of the ingots, including reflectance. As a result, the ingots could be reduced or worked essentially right out of the casting without first conditioning the surface by, for example, scalping. Also disclosed is a method of improving the surface properties and preventing surface imperfections and cracking of cast aluminum alloys. The method includes the steps of adding calcium to a molten aluminum alloy that is essentially free of Be and casting the aluminum alloy using any commonly used technique.
    • 公开了铝合金组合物,其包括导致改善铸铝表面性能的少量钙。 钙和高达0.25%的晶粒细化剂与碱土金属,过渡金属和/或稀土金属一起作为熔体与铝合金一起加入。 添加结果导致铸造铝和铝合金的外观改善,表面缺陷显着减少和表面氧化降低。 发现少量这些添加剂令人惊奇地发现,在多于一种铸锭技术中基本上消除了垂直折痕,凹坑和锭裂纹。 添加物还改善了锭的外观,包括反射率。 结果,可以通过例如剥皮来首先对表面进行调理,从而可以将铸锭基本上正确地压出或加工成铸件。 还公开了改进表面性能并防止铸铝合金的表面缺陷和开裂的方法。 该方法包括以下步骤:向基本上不含Be的熔融铝合金添加钙,并使用任何常用技术浇铸铝合金。
    • 8. 发明授权
    • Production of lithium by direct electrolysis of lithium carbonate
    • 通过直接电解碳酸锂生产锂
    • US4988417A
    • 1991-01-29
    • US291527
    • 1988-12-29
    • David H. DeYoung
    • David H. DeYoung
    • C25C3/02C25C7/04
    • C25C3/02C25C7/04
    • A method of electrolytically producing lithium includes providing an electrolytic cell having an anode compartment and a cathode compartment. The compartments are separated by a porous electrically nonconductive membrane which will be wetted by the electrolyte and permit migration of lithium ions therethrough. Lithium carbonate is introduced into the anode compartment and produces delivery of lithium ions from the anode compartment to the cathode compartment where such ions are converted into lithium metal. The membrane is preferably a non-glass oxide membrane such as a magnesium oxide membrane. The membrane serves to resist undesired backflow of the lithium from the cathode compartment through the membrane into the anode compartment. Undesired communication between the anode and cathode is further resisted by separating the air spaces thereover. This may be accomplished by applying an inert gas purge and a positive pressure in the cathode compartment.The apparatus preferably includes an electrolytic cell with an anode compartment and a cathode compartment and an electrically nonconductive membrane which is wettable by the electrolyte and will permit migration of the lithium ion therethrough while resisting reverse passage of lithium therethrough.
    • 电解生产锂的方法包括提供具有阳极室和阴极室的电解池。 隔室由多孔非导电膜隔开,其将被电解质润湿并允许锂离子通过其迁移。 将碳酸锂引入阳极室,并产生从阳极室到阴极室的锂离子输送,其中这些离子转化为锂金属。 膜优选为非玻璃氧化物膜,例如氧化镁膜。 膜用于防止锂从阴极室通过膜进入阳极室的不期望的回流。 阳极和阴极之间的不期望的通信通过分离其上的空气空间进一步抵抗。 这可以通过在阴极室中施加惰性气体吹扫和正压来实现。 该装置优选地包括具有阳极室和阴极室的电解池和可被电解质润湿的不导电膜,并且允许锂离子通过其中而阻止锂从其中反向通过。