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1. 发明授权

US6037068A Superconducting metal-ceramic laminate 失效
标题翻译：超导金属陶瓷层压板
公开(公告)号：US6037068A
公开(公告)日：2000-03-14
申请号：US107904
申请日：1998-06-19
申请人： L. Pierre de Rochemont , Michael J. Suscavage , Daniel F. Ryder, Jr. , Mikhail Klugerman
发明人： L. Pierre de Rochemont , Michael J. Suscavage , Daniel F. Ryder, Jr. , Mikhail Klugerman
IPC分类号： C23C16/40 , C23C16/56 , H01L39/02 , H01L39/14 , H01L39/24 , B32B9/00
CPC分类号： H01L39/143 , C23C16/408 , C23C16/56 , H01L39/02 , H01L39/2451 , H01L39/2477 , Y10S428/93 , Y10S505/701 , Y10S505/702 , Y10S505/703 , Y10S505/704 , Y10T428/2929 , Y10T428/2931
摘要： This invention permits superconducting ceramics, as well as other ceramic materials, to be spray deposited onto indefinitely large sheets of metallic substrate from a carboxylic acid salt solution. Elemental metal precursors of the superconductor are introduced into the solution as carboxylic acid salts. The deposit formed on the malleable metallic substrate is then thermomechanically calcined to form c-axis textured metal-superconductor composite sheet structures. These composite sheet structures can be formed by pressing together two ceramic-substrate structures, ceramic face-to-face, to form a metal-ceramic-metal sheet structure, or by overlaying a metal sheet over the deposited structure. Once the structure has been thermomechanically calcined, the c-axis of the superconductor is oriented parallel to the vector defining the plane of the metal sheet, i.e., perpendicular to the surface of the plane. These sheets of c-axis textured superconductor can then be mechanically worked as continuous superconducting filaments into larger composite structures with predetermined c-axis orientation. The fact that the c-axis of the superconductor is given predetermined orientation allows surface topologies to be mechanically constructed from these sheets that maximize the performance of the superconductor for a predetermined application or magnetic field environment.
摘要翻译：本发明允许将超导陶瓷以及其它陶瓷材料从羧酸盐溶液喷涂到无限大的金属基材片上。将超导体的元素金属前体作为羧酸盐引入溶液中。然后将在韧性金属基材上形成的沉积物进行热机械煅烧以形成c轴织构的金属 - 超导体复合片材结构。这些复合片材结构可以通过将两个陶瓷 - 衬底结构陶瓷面对面地组合在一起形成金属 - 陶瓷 - 金属片结构，或者通过在沉积结构上覆盖金属片来形成。一旦结构被热力学煅烧，超导体的c轴平行于限定金属板的平面，即垂直于平面的表面的向量取向。然后可以将这些c轴纹理超导体片材作为连续超导细丝机械加工成具有预定c轴取向的更大的复合结构。超导体的c轴被给定为预定取向的事实允许表面拓扑结构由这些片材机械地构造，以使预定应用或磁场环境中的超导体的性能最大化。

2. 发明授权

US5866252A Super conducting metal-ceramic composite 失效
标题翻译：超导金属陶瓷复合材料
公开(公告)号：US5866252A
公开(公告)日：1999-02-02
申请号：US733867
申请日：1996-10-18
申请人： L. Pierre de Rochemont , Michael J. Suscavage , Daniel F. Ryder, Jr. , Mikhail Klugerman
发明人： L. Pierre de Rochemont , Michael J. Suscavage , Daniel F. Ryder, Jr. , Mikhail Klugerman
IPC分类号： C23C16/40 , C23C16/56 , H01L39/02 , H01L39/14 , H01L39/24 , H01B12/00
CPC分类号： H01L39/143 , C23C16/408 , C23C16/56 , H01L39/02 , H01L39/2451 , H01L39/2477 , Y10S428/93 , Y10S505/701 , Y10S505/702 , Y10S505/703 , Y10S505/704 , Y10T428/2929 , Y10T428/2931
摘要： This invention permits superconducting ceramics, as well as other ceramic materials, to be spray deposited onto indefinitely large sheets of metallic substrate from a carboxylic acid salt solution. Elemental metal precursors of the superconductor are introduced into the solution as carboxylic acid salts. The deposit formed on the malleable metallic substrate is then thermomechanically calcined to form c-axis textured metal-superconductor composite sheet structures. These composite sheet structures can be formed by pressing together two ceramic-substrate structures, ceramic face-to-face, to form a metal-ceramic-metal sheet structure, or by overlaying a metal sheet over the deposited structure. Once the structure has been thermomechanically calcined, the c-axis of the superconductor is oriented parallel to the vector defining the plane of the metal sheet, i.e., perpendicular to the surface of the plane. These sheets of c-axis textured superconductor can then be mechanically worked as continuous superconducting filaments into larger composite structures with predetermined c-axis orientation. The fact that the c-axis of the superconductor is given predetermined orientation allows surface topologies to be mechanically constructed from these sheets that maximize the performance of the superconductor for a predetermined application or magnetic field environment.
摘要翻译：本发明允许将超导陶瓷以及其它陶瓷材料从羧酸盐溶液喷涂到无限大的金属基材片上。将超导体的元素金属前体作为羧酸盐引入溶液中。然后将在韧性金属基材上形成的沉积物进行热机械煅烧以形成c轴织构的金属 - 超导体复合片材结构。这些复合片材结构可以通过将两个陶瓷 - 衬底结构陶瓷面对面地组合在一起形成金属 - 陶瓷 - 金属片结构，或者通过在沉积结构上覆盖金属片来形成。一旦结构被热力学煅烧，超导体的c轴平行于限定金属板的平面，即垂直于平面的表面的向量取向。然后可以将这些c轴纹理超导体片材作为连续超导细丝机械加工成具有预定c轴取向的更大的复合结构。超导体的c轴被给定为预定取向的事实允许表面拓扑结构由这些片材机械地构造，以使预定应用或磁场环境中的超导体的性能最大化。

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