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1. 发明授权

US4451632A High vinylidene chloride content interpolymer coating resins and method of preparation 失效
标题翻译：高偏二氯乙烯含量互聚物涂料树脂及其制备方法
公开(公告)号：US4451632A
公开(公告)日：1984-05-29
申请号：US395442
申请日：1982-07-06
申请人： Dale S. Gibbs , Warren L. Treptow
发明人： Dale S. Gibbs , Warren L. Treptow
IPC分类号： C08F214/08 , C08F14/08
CPC分类号： C08F214/08
摘要： A process for preparing, in aqueous emulsion, controlled interpolymer compositions. The interpolymer compositions have polymerized therein from about 86 to 92 mole percent, vinylidene chloride, from about 14 to 8 mole percent of a comonomer mixture of methyl methacrylate and a comonomer selected from the group consisting of acrylonitrile, methacrylic acid and methacrylonitrile in a ratio of the comonomer to methyl methacrylate of from about 0.5:1 to 2:1, and from about 0.5 to 1.0 weight percent itaconic acid, based on weight of vinylidene chloride plus comonomer mixture. The interpolymers are prepared in a three step process. The third step, or Step III, wherein monomer feeding is step-wise reduced for a portion of the step and a polymerization initiator is added at generally the same constant rate as the rate of addition in Steps I and II, generally reduces the amount of unreacted mixed monomers remaining after monomer addition is completed. As such, the detrimental results produced when a large amount of polymer composition variation in the direction of high vinylidene chloride fractions are markedly reduced.
摘要翻译：在水乳液中制备控制互聚物组合物的方法。互聚物组合物在其中聚合约86至92摩尔％偏二氯乙烯，约14至8摩尔％的甲基丙烯酸甲酯和选自丙烯腈，甲基丙烯酸和甲基丙烯腈的共聚单体混合物的比例为基于偏二氯乙烯加共聚单体混合物的重量，共聚单体为甲基丙烯酸甲酯的约0.5:1至2:1，以及约0.5至1.0重量％的衣康酸。互聚物以三步法制备。第三步骤或步骤III，其中步骤中单体进料逐步还原，并且聚合引发剂以与步骤I和II中的加入速率基本相同的恒定速率加入，通常减少单体添加后剩余的未反应的混合单体完成。因此，当高偏二氯乙烯部分的方向上的大量聚合物组合物变化显着降低时产生的有害结果。

2. 发明授权

US4296013A Vinylidene chloride polymer microgels 失效
标题翻译：偏二氯乙烯聚合物微凝胶
公开(公告)号：US4296013A
公开(公告)日：1981-10-20
申请号：US103020
申请日：1979-12-13
申请人： Dale S. Gibbs
发明人： Dale S. Gibbs
IPC分类号： C08F214/08 , C09D127/08 , C08L27/08
CPC分类号： C09D127/08 , C08F214/08
摘要： Discrete, crosslinked vinylidene chloride polymer microgels, having a latex particle size of less than 1 micron and a gel content of about 1 to 99 percent, such microgels being obtained by emulsion polymerizing (a) about 50 to about 95 parts by weight of vinylidene chloride, (b) about 5 to about 50 parts by weight of a copolymerizable ethylenically unsaturated comonomer, and (c) about 0.1 to about 10 parts by weight of a copolymerizable crosslinking polyfunctional comonomer. Such microgels have been found to have wide applicability as additives for synthetic foams and fibers, and for the preparation of improved coatings, films, and redispersible latexes.
摘要翻译：离散的交联偏二氯乙烯聚合物微凝胶，其胶乳粒度小于1微米，凝胶含量为约1至99％，这种微凝胶通过乳液聚合（a）约50至约95重量份的偏二氯乙烯，（b）约5至约50重量份的可共聚烯属不饱和共聚单体，和（c）约0.1至约10重量份可共聚的交联多官能共聚单体。已经发现这种微凝胶作为合成泡沫和纤维的添加剂具有广泛的适用性，并且用于制备改进的涂料，膜和可再分散的胶乳。

3. 发明授权

US4273901A Dispersible vinylidene chloride polymer microgel powders as additives for polymers 失效
标题翻译：可分散偏氯乙烯聚合物微凝胶粉末作为聚合物的添加剂
公开(公告)号：US4273901A
公开(公告)日：1981-06-16
申请号：US91281
申请日：1979-11-05
申请人： Dale S. Gibbs , Jack H. Benson , Reet T. Fernandez
发明人： Dale S. Gibbs , Jack H. Benson , Reet T. Fernandez
IPC分类号： C08F214/08 , C08J3/11 , C08J9/00 , C08L75/00 , C08K5/05 , C08G18/06 , C08K5/13
CPC分类号： C08J9/0061 , C08F214/08 , C08J3/11 , C08L75/00 , C08J2327/08 , C08J2375/04 , C08J2427/00
摘要： A crosslinked vinylidene chloride polymer microgel powder is recovered from a latex and dispersed with moderate shear in a nonsolvent for vinylidene chloride polymers, such as a polyol used in the preparation of polyurethane materials. A dispersion of the powder and a polyol is eminently suited for use in the preparation of polyurethane foams to impart enhanced flame-retardancy and load-bearing properties thereto.
摘要翻译：从胶乳中回收交联的偏二氯乙烯聚合物微粒凝胶粉末，并用中等剪切分散在偏二氯乙烯聚合物的非溶剂中，例如用于制备聚氨酯材料的多元醇。粉末和多元醇的分散体非常适合用于制备聚氨酯泡沫以赋予其更好的阻燃性和承载性能。

4. 发明授权

US4017442A Structured-particle latexes 失效
标题翻译：结构粒子胶乳
公开(公告)号：US4017442A
公开(公告)日：1977-04-12
申请号：US569724
申请日：1975-04-21
申请人： Dale S. Gibbs , Earl H. Wagener , Ritchie A. Wessling
发明人： Dale S. Gibbs , Earl H. Wagener , Ritchie A. Wessling
IPC分类号： C08C1/06 , C08F291/00 , C08L33/08
CPC分类号： C08C1/06 , C08F291/00
摘要： Structured-particle latexes are prepared from nonionic or slightly cationic latexes, either preformed or polymerized in situ, by emulsion polymerizing monomeric materials which include an ethylenically unsaturated, activated-halogen monomer such as vinylbenzyl chloride in the absence of a sufficient amount of a surfactant to initiate new particles whereby the activated-halogen monomer is copolymerized on the surface of the existing particles which are dispersed in aqueous media. To the resulting structured particle latex may then be added conventional cationic surfactants to provide greater stability. The cationic latexes are suitable for coatings.
摘要翻译：通过在不存在足够量的表面活性剂的情况下通过乳液聚合包括烯属不饱和的活性卤素单体如乙烯基苄基氯的单体材料，由非离子或微阳离子胶乳制备结构粒子胶乳，引发新的颗粒，由此活性卤素单体在分散在水性介质中的现有颗粒的表面上共聚。然后可以向得到的结构化颗粒胶乳中加入常规阳离子表面活性剂以提供更大的稳定性。阳离子胶乳适用于涂料。

5. 发明授权

US4351929A Crystallizable controlled composition interpolymers of vinylidene chloride and methyl methacrylate and method of preparing same 失效
标题翻译：偏二氯乙烯和甲基丙烯酸甲酯的结晶控制组合物互聚物及其制备方法
公开(公告)号：US4351929A
公开(公告)日：1982-09-28
申请号：US262265
申请日：1981-05-11
申请人： Dale S. Gibbs , Duane F. Foye
发明人： Dale S. Gibbs , Duane F. Foye
IPC分类号： C08F2/22 , C08F214/08
CPC分类号： C08F214/08
摘要： Crystallizable, controlled composition interpolymers consisting essentially of (a) from about 88 to about 92 mole percent vinylidene chloride, (b) from about 8 to about 12 mole percent methyl methacrylate, and (c) up to about 3 weight percent, based on the combined weight of (a) and (b), of one or more ethylenically unsaturated comonomers; such interpolymers having a relative viscosity of at least about 1.40.degree. at 25.degree. C. as a 1 percent solution in tetrahydrofuran and being capable of forming substantially haze-free solutions when present in an amount of about 20 percent solids in a solvent mixture consisting of 65 percent by weight tetrahydrofuran and 35 percent by weight toluene.
摘要翻译：基于（a）约88-约92摩尔％偏二氯乙烯，（b）约8至约12摩尔％甲基丙烯酸甲酯和（c）至多约3重量％，基于（a）和（b）的组合重量，一种或多种烯键式不饱和共聚单体; 这种互聚物在25℃下的相对粘度为至少约1.40℃，为1％四氢呋喃溶液，并且当以约20％固体的量存在时，能够形成基本上无雾的溶液，所述溶剂混合物由 65重量％的四氢呋喃和35重量％的甲苯。

6. 发明授权

US4232129A Dispersible vinylidene chloride polymer microgel powders as additives for urethane polymer foam 失效
标题翻译：可分散偏氯乙烯聚合物微凝胶粉末作为聚氨酯聚合物泡沫的添加剂
公开(公告)号：US4232129A
公开(公告)日：1980-11-04
申请号：US942512
申请日：1978-09-15
申请人： Dale S. Gibbs , Jack H. Benson , Reet T. Fernandez
发明人： Dale S. Gibbs , Jack H. Benson , Reet T. Fernandez
IPC分类号： C08F14/00 , C08F2/22 , C08F14/08 , C08F214/08 , C08J3/11 , C08J9/00 , C08L1/00 , C08L27/00 , C08L27/08 , C08L67/00 , C08K5/05 , C08K5/13
CPC分类号： C08J9/0061 , C08F214/08 , C08J3/11 , C08J2327/08 , C08J2375/04 , C08J2427/00
摘要： A crosslinked vinylidene chloride polymer microgel powder is recovered from a latex and dispersed with moderate shear in a nonsolvent for vinylidene chloride polymers, such as a polyol used in the preparation of polyurethane materials. A dispersion of the powder and a polyol is eminently suited for use in the preparation of polyurethane foams to impart enhanced flame-retardancy and load-bearing properties thereto.
摘要翻译：从胶乳中回收交联的偏二氯乙烯聚合物微粒凝胶粉末，并用中等剪切分散在偏二氯乙烯聚合物的非溶剂中，例如用于制备聚氨酯材料的多元醇。粉末和多元醇的分散体非常适合用于制备聚氨酯泡沫以赋予其更好的阻燃性和承载性能。

7. 发明授权

US4214096A Novel isothiouronium salts 失效
标题翻译：新型异硫脲盐
公开(公告)号：US4214096A
公开(公告)日：1980-07-22
申请号：US48954
申请日：1979-06-15
申请人： Thomas C. Klingler , Ritchie A. Wessling , Dale S. Gibbs
发明人： Thomas C. Klingler , Ritchie A. Wessling , Dale S. Gibbs
IPC分类号： B01F17/00 , C07C335/32 , C09D5/44 , C07C157/02 , C07C157/05 , C07C161/00
CPC分类号： C07C335/32 , B01F17/0057 , C09D5/448
摘要： Novel isothiouronium salts are herein described which correspond to the formula ##STR1## wherein R and R' are each independently hydrocarbyl or inertly-substituted hydrocarbyl of at least 4 carbon atoms; R.sub.1 -R.sub.4 are each independently alkyl or hydroxyalkyl of 1 to 4 carbon atoms, or R.sub.1 and R.sub.3 are joined to form a 5- or 6-membered heterocyclic ring; n is 0 or 1; and A.sup..crclbar. is an inert neutralizing anion. The isothiouronium salts are surprisingly effective dispersing agents and are used in forming electrodepositable latexes.
摘要翻译：本文描述了新的异硫脲鎓盐，其对应于下式：其中R和R'各自独立地为至少4个碳原子的烃基或惰性取代的烃基; R 1 -R 4各自独立地为具有1至4个碳原子的烷基或羟烷基，或者R 1和R 3连接形成5-或6-元杂环; n为0或1; 而A（ - ）是惰性中和阴离子。异硫脲盐是惊人的有效的分散剂，并用于形成可电沉积胶乳。

8. 发明授权

US4186156A Crystallizable vinylidene chloride polymer powders and acrylic fibers containing same 失效
标题翻译：可结晶的偏二氯乙烯聚合物粉末和含有它的丙烯酸纤维
公开(公告)号：US4186156A
公开(公告)日：1980-01-29
申请号：US942513
申请日：1978-09-15
申请人： Dale S. Gibbs
发明人： Dale S. Gibbs
IPC分类号： C08L33/20 , D01F1/07 , D01F6/54
CPC分类号： D01F6/54 , C08L33/20 , D01F1/07
摘要： A crystallizable vinylidene chloride polymer powder is recovered from a latex obtained by emulsion polymerizing in sequence (a) a first monomer mixture comprising a predominant amount of vinylidene chloride and an ethylenically unsaturated comonomer which is copolymerizable therewith, such as acrylonitrile; (b) a minor amount of a polyfunctional monomer for providing graft sites on the product of (a); and (c) a second monomer mixture which is predominantly acrylonitrile, the amount of the second monomer mixture being in the range of about 10 to about 25 percent of the weight of the first monomer mixture. The so-formed solvent is admixed with an acrylic polymer and a suitable solvent and then spun into fibers having improved flame-retardancy.
摘要翻译：从通过乳液聚合获得的胶乳中回收可结晶的偏二氯乙烯聚合物粉末（a）包含主要量的偏二氯乙烯和可与其共聚的烯属不饱和共聚单体如丙烯腈的第一单体混合物; （b）少量多官能单体，用于在（a）的产物上提供移植部位; 和（c）主要是丙烯腈的第二单体混合物，第二单体混合物的量在第一单体混合物的重量的约10至约25％的范围内。将如此形成的溶剂与丙烯酸聚合物和合适的溶剂混合，然后纺成具有改进的阻燃性的纤维。

9. 发明授权

US4056501A Cationic structured-particle latexes 失效
标题翻译：阳离子结构化颗粒
公开(公告)号：US4056501A
公开(公告)日：1977-11-01
申请号：US569723
申请日：1975-04-21
申请人： Dale S. Gibbs , Earl H. Wagener , Ritchie A. Wessling
发明人： Dale S. Gibbs , Earl H. Wagener , Ritchie A. Wessling
IPC分类号： C08C1/06 , C08F291/00 , C08L9/08
CPC分类号： C08C1/06 , C08F291/00
摘要： Structured-particle latexes are prepared from nonionic or slightly cationic latexes, either preformed or polymerized in situ, by emulsion polymerizing monomeric materials which include an ethylenically unsaturated, activated-halogen monomer such as vinylbenzyl chloride in the absence of a sufficient amount of a surfactant to initiate new particles whereby the activated-halogen monomer is copolymerized on the surface of the existing particles which are dispersed in an aqueous media. The resulting structured-particle latex may then be reacted with a nucleophile such as dimethyl sulfide or trimethyl amine to form a latex having stabilizing "onium" groups such as sulfonium groups or quaternary ammonium groups chemically bound at or near the surface of the polymer particles which are dispersed in aqueous media. The cationic latexes are suitable for coatings and organic pigments.

10. 发明授权

US4017372A Process for electrodeposition of cross-linked polymer coatings 失效
标题翻译：电沉积交联聚合物涂层的方法
公开(公告)号：US4017372A
公开(公告)日：1977-04-12
申请号：US569722
申请日：1975-04-21
申请人： Earl H. Wagener , Ritchie A. Wessling , Dale S. Gibbs
发明人： Earl H. Wagener , Ritchie A. Wessling , Dale S. Gibbs
IPC分类号： C09D5/44 , C25D13/06
CPC分类号： C09D5/4488
摘要： A method for electrodeposition of an adherent, water-resistant, cross-linked, organic coating on an electroconductive surface comprising (a) placing the elecroconductive surface to be coated in contact with an aqueous dispersion containing a water-insoluble, essentially electrically non-conductive, film-forming, organic polymer as cation-active, structured particles wherein a substantial portion of the cation-activity is provided by pH independent cationic groups which are chemically bound to the polymer at or near the particle surface and (b) passing an electric current from an electrode through the latex to the electroconductive surface in such a direction that the electroconductive surface is negatively charged, i.e., becomes a cathode in an electrophoretic cell. By use of alternating current both electrodes become coated with an adherent coating of polymer.
摘要翻译：一种用于在导电表面上电粘附，防水，交联的有机涂层的方法，包括（a）将待涂覆的导电表面与含有水不溶性，基本上不导电的水分散体接触成膜，有机聚合物作为阳离子活性的结构化颗粒，其中大部分阳离子活性由pH独立的阳离子基团提供，所述阳离子基团与颗粒表面处或附近的聚合物化学结合，和（b）通过电电流从电极通过胶乳到导电表面，使得导电表面带负电，即在电泳池中成为阴极。通过使用交流电，两个电极都涂覆有聚合物的粘附涂层。

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