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    • 6. 发明公开
    • Single polymer film structures for use in stand-up-pouches
    • EinzelpolymerfolienverbundefürStandbeutel
    • EP2762308A1
    • 2014-08-06
    • EP14166395.5
    • 2011-05-06
    • Dow Brasil Indústria e Comércio de Produtos Químicos Ltda.
    • Rosa, Rosana
    • B32B27/32B65D75/00
    • B32B27/32B32B7/02B32B27/08B32B27/327B32B2250/05B32B2250/242B32B2307/31B32B2307/558B32B2307/72B32B2307/7246B32B2439/00B32B2439/40
    • 1. A monofilm suitable for use in stand up pouches comprising:
      a) a first surface layer (X) comprised from 50 to 100 percent (by weight of the layer (X)) of a linear low density polyethylene having a density from 0.89 to 0.91 g/cm 3 and a melt index of less than 1.3 dg/min, and a peak melting point in a range of from 85 °C to 105 °C, and a molecular weight distribution, Mw/Mn range of 2.0 to 3.0; and
      b) a core layer (Y) comprising from 60 to 100 percent (by weight of the layer (Y)) of a first multimodal polyethylene polymer having a multimodal distribution in terms of molecular weight, wherein said first multimodal polyethylene comprises units derived from ethylene and at least one C 3 -C 10 alpha-olefin (preferably C 6 -C 8 ), and wherein the first multimodal polyethylene polymer has a density in the range of 0.950- 0.965 g/cm 3 , a melt index of less than 1.20 dg/min, a peak melting point greater than 120°C, and a molecular weight distribution, M w/ M n ratio greater than 5.0; and
      c) a second surface layer (Z) which comprises:
      i) from 50 to 100 percent (by weight of the layer (Z)) of a second multimodal polyethylene polymer having a multimodal distribution in terms of molecular weight, wherein said second multimodal polyethylene comprises units derived from ethylene and at least one C 3 - C 10 alpha-olefin (preferably C 6 -C 8 ), said second multimodal polyethylene polymer having a density in the range of 0.950- 0.965 g/cm 3 , a melt index of less than 1.20 dg/min, and a peak melting point in the range of from 120°C to 135°C, and a molecular weight distribution, M w/ M n ratio greater than 5.0; and
      ii) from 0 to 50 percent (by weight of the layer (Z)) of a copolymer comprising units derived from ethylene and at least one C 3 - C 10 alpha-olefin (preferably C 6 -C 8 ), and wherein the m polyethylene polymer has a density in the range of 0.91- to 0.95 g/cm 3 , a melt index of less than 1.2 dg/min, a peak melting point greater than 110°C, and a molecular weight distribution, M w /M n ratio greater than 3.0.
    • 1.适合用于立式小袋的单丝,其包含:a)包含50-100%(重量的层(X))的线性低密度聚乙烯的第一表面层(X),密度为0.89至 0.91g / cm 3,熔体指数小于1.3dg / min,峰值熔点在85℃至105℃范围内,分子量分布Mw / Mn范围为2.0-3.0; 和b)包含60-100%(按重量计的层(Y))的分子量为多峰分布的第一多峰聚乙烯聚合物的核心层(Y),其中所述第一多峰聚乙烯包含衍生自 乙烯和至少一种C 3 -C 10α-烯烃(优选C 6 -C 8),并且其中第一多峰聚乙烯聚合物的密度在0.950-0.965g / cm 3的范围内,熔体指数小于 1.20dg / min,峰值熔点大于120℃,分子量分布M w / M n比大于5.0; 和c)第二表面层(Z),其包含:i)按分子量计,具有多峰分布的第二多峰聚乙烯聚合物的50-100重量%(Z)层),其中所述第二多峰 聚乙烯包含衍生自乙烯和至少一种C 3 -C 10α-烯烃(优选C 6 -C 8)的单元,所述第二多峰聚乙烯聚合物的密度范围为0.950-0.965g / cm 3,熔体指数 小于1.20dg / min,峰值熔点在120℃至135℃的范围内,分子量分布M w / M n比大于5.0; 和ii)0至50%(层(Z)的重量)共聚物,其包含衍生自乙烯和至少一种C 3 -C 10α-烯烃(优选C 6 -C 8)的单元的共聚物,并且其中 m聚乙烯聚合物的密度范围为0.91-0.95g / cm 3,熔体指数小于1.2dg / min,峰值熔点大于110℃,分子量分布为M w / M n比大于3.0。