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1. 发明申请

WO2010074728A1 METHOD OF PREPARING STIMULUS-RESPONSIVE POLYMERIC PARTICLES 审中-公开
标题翻译：制备刺激性聚合物颗粒的方法
公开(公告)号：WO2010074728A1
公开(公告)日：2010-07-01
申请号：PCT/US2009/006598
申请日：2009-12-17
申请人： EASTMAN KODAK COMPANY , CLARKE, Andrew , DESROUSSEAUX, Stephanie, Veronique , GIBSON, Danuta , HIGGINS, John, Martin , HOWE, Andrew, M. , WEAR, Trevor, John
发明人： CLARKE, Andrew , DESROUSSEAUX, Stephanie, Veronique , GIBSON, Danuta , HIGGINS, John, Martin , HOWE, Andrew, M. , WEAR, Trevor, John
IPC分类号： C08F2/22 , C08J3/24 , C08L101/14 , B01J13/00 , C09D11/00 , C08F2/26 , C08F220/54 , C08F222/38 , C08F265/10 , C08L33/24
CPC分类号： C08F2/22 , B01J13/14 , C08F2/20 , C08F222/38 , C08F265/10 , C09D11/30 , C08F222/385
摘要： The invention relates to method of making a polymeric compound, comprising discrete particles responsive to an external stimulus, that is resistant to aggregation in high-shear fields, which includes the addition of a polymerization initiator to a reaction mixture comprising a monomer corresponding to the polymeric compound, wherein the method comprises the portion-wise addition of aliquots of a cross-linking agent to the reaction mixture, wherein an aliquot is added after the polymerization has progressed substantially to completion. The polymer particles are largely immune to the effects of transient shear rates at least as high as 10 6 s -1 , whilst maintaining their thermal responsiveness and being present at moderate concentration. In addition, the structural and chemical modifications brought by the delayed portion-wise addition of the cross-linking agent allow an improvement in stability in a high-shear field, even in the absence of a formulation additive such as a surfactant.
摘要翻译：本发明涉及制备聚合化合物的方法，其包含响应于外部刺激的离散颗粒，其对高剪切场中的聚集具有抗性，其包括向包含对应于聚合物的单体的反应混合物中加入聚合引发剂化合物，其中所述方法包括向反应混合物中分批加入交联剂的等分试样，其中在聚合进行到基本完成之后加入等分试样。聚合物颗粒很大程度上免受瞬态剪切速率的影响，至少高达106s-1，同时保持其热响应性并以适中的浓度存在。此外，即使在不存在制剂添加剂如表面活性剂的情况下，通过延迟分批加入交联剂引起的结构和化学改性也可提高高剪切场的稳定性。

2. 发明申请

WO2011053609A1 AQUEOUS INK COMPOSITION 审中-公开
标题翻译：水份墨水组合物
公开(公告)号：WO2011053609A1
公开(公告)日：2011-05-05
申请号：PCT/US2010/054179
申请日：2010-10-27
申请人： ESTMAN KODAK COMPANY , HIGGINS, John, Martin , GIBSON, Danuta , HOWE, Andrew, Michael , CLARKE, Andrew , WEAR, Trevor , DESROUSSEAUX, Stephanie, Veronique
发明人： HIGGINS, John, Martin , GIBSON, Danuta , HOWE, Andrew, Michael , CLARKE, Andrew , WEAR, Trevor , DESROUSSEAUX, Stephanie, Veronique
IPC分类号： C09D11/00
CPC分类号： C09D11/03 , C09D11/30
摘要： The incorporation of a polyol redispersant, being an alcohol having at least four hydroxyl groups which are preferably underivatised, e.g. a saccharide such as sucrose, into an aqueous ink composition which comprises property- enhancing polymers (e.g. for robustness, waterfastness and adhesion) substantially enhances the redispersability of residues of the ink composition. Such use and ink compositions are described, which find particular application in continuous inkjet printing (where redispersiblity of residues is essential) and which are useful for printing on impermeable substrates whereby such ink compositions can be advantageously absent a liquid humectant.
摘要翻译：多元醇再分散剂的引入，其是具有至少四个优选未衍生的羟基的醇，例如，诸如蔗糖的糖类成为包含特性增强聚合物（例如用于坚固性，耐水性和粘附性）的水性油墨组合物显着增强了油墨组合物残余物的再分散性。描述了这种使用和油墨组合物，其在连续喷墨印刷（其中残余物的可再分散性是必需的）中有特别的应用，并且其可用于在不渗透的基材上进行印刷，由此这种油墨组合物可有利地不存在液体保湿剂。

3. 发明申请

WO2011022046A1 STRUCTURAL INKS 审中-公开
标题翻译：结构墨水
公开(公告)号：WO2011022046A1
公开(公告)日：2011-02-24
申请号：PCT/US2010/002245
申请日：2010-08-13
申请人： EASTMAN KODAK COMPANY , BOWER, Christopher , COLDRICK, Philip, J. , DESROUSSEAUX, Stephanie, Veronique , HOWE, Andrew, Michael
发明人： BOWER, Christopher , COLDRICK, Philip, J. , DESROUSSEAUX, Stephanie, Veronique , HOWE, Andrew, Michael
IPC分类号： C09D11/00 , C09D11/10
CPC分类号： C09D11/106 , C09D11/30
摘要： A composition comprising a plurality of discrete carrier-swellable polymer particles (preferably polyNIPAM particles) and a corresponding carrier (e.g. water), which particles have a low polydispersity index and are present in an amount of at least 0.1% by weight of the composition may be used to impart structural-image properties (such as structural colour) to a substrate by coating or printing methods. Additional benefits of adherence to low-energy surface substrates and enhanced rheological properties for printing compositions may also be provided. The compositions and methods used in the invention allow visual effects or security applications to be incorporated into substrates in a low-cost and convenient manner.
摘要翻译：包含多个离散的载体可溶胀聚合物颗粒（优选聚NIPAM颗粒）和相应的载体（例如水）的组合物，该颗粒具有低多分散指数并且以组合物的至少0.1重量％的量存在。用于通过涂布或印刷方法将结构图像性质（例如结构颜色）赋予基底。还可以提供粘附于低能量表面底物和增强印刷组合物的流变性能的附加益处。本发明中使用的组合物和方法允许以低成本和方便的方式将视觉效果或安全性应用结合到基质中。

4. 发明申请

WO2009157990A1 INKJET PRINTING SYSTEM 审中-公开
标题翻译：喷墨打印系统
公开(公告)号：WO2009157990A1
公开(公告)日：2009-12-30
申请号：PCT/US2009/003727
申请日：2009-06-23
申请人： EASTMAN KODAK COMPANY , HIGGINS, John, Martin , CLARKE, Andrew , DESROUSSEAUX, Stephanie, Veronique , HOWE, Andrew Michael , GIBSON, Danuta , WEAR, Trevor John
发明人： HIGGINS, John, Martin , CLARKE, Andrew , DESROUSSEAUX, Stephanie, Veronique , HOWE, Andrew Michael , GIBSON, Danuta , WEAR, Trevor John
IPC分类号： B41J11/00
CPC分类号： B41J11/0015
摘要： The present invention relates to an inkjet printing system comprising (a) at least one inkjet printing unit each comprising at least one inkjet printhead; (b) an ink-receiving element comprising a substrate; (c) an aqueous inkjet ink composition which comprises a polymeric compound comprising discrete particles responsive to a stimulated temperature change, and a functional material, wherein the functional material may be incorporated as part of the polymeric particles, the particles causing the composition to have a first rheological state and a different second rheological state in response to the stimulated change in temperature, the first rheological state being associated with a first lower viscosity of the composition, wherein the particles have a first lower volume, enabling the composition to pass through an inkjet printhead orifice and the second rheological state being associated with a second higher viscosity of the composition, wherein the particles have a second higher volume, enabling immobilisation of droplets of the composition on a substrate therefor; and (d) means for cooling the substrate prior to or during ink deposition, such that upon contact with the substrate the ink composition undergoes a change in rheological state from the first to the second rheological state enabling immobilisation of droplets of the ink composition on the substrate. The inkjet system is particularly suitable for a continuous inkjet printing system for printing onto a wide range of surfaces including impermeable surfaces, such as polyethylene or propylene, rubber, aluminium or steel as normally used in packaging and poorly-absorbing papers, such as lithographic papers. By cooling the substrate prior to or during ink deposition, the temperature of the substrate can be selected such that the ink can adopt its second, higher viscosity, rather than the prevailing, variable, ambient conditions.
摘要翻译：本发明涉及一种喷墨打印系统，其包括（a）至少一个喷墨打印单元，每个喷墨打印单元包括至少一个喷墨打印头; （b）一种包含基底的油墨接收元件; （c）水性喷墨油墨组合物，其包含包含响应于受刺激的温度变化的离散颗粒的聚合化合物和功能材料，其中所述功能材料可以作为所述聚合物颗粒的一部分结合，所述颗粒使所述组合物具有第一流变状态和不同的第二流变状态响应于受激化的温度变化，第一流变状态与组合物的第一较低粘度相关联，其中所述颗粒具有第一较低体积，使组合物能够通过喷墨打印头孔口和第二流变状态与组合物的第二较高粘度相关联，其中所述颗粒具有第二较高的体积，使组合物液滴能够固定在基材上; 和（d）在油墨沉积之前或期间冷却基材的装置，使得当与基材接触时，油墨组合物经历从第一流变状态到第二流变状态的流变状态的变化，从而使油墨组合物的液滴能够固定在基质。喷墨系统特别适用于连续喷墨印刷系统，用于在通常用于包装和不良吸收的纸张如平版印刷纸中的通常使用的诸如聚乙烯或丙烯，橡胶，铝或钢的不透水表面的宽范围的表面上印刷。通过在油墨沉积之前或期间冷却基板，可以选择基板的温度，使得油墨可以采用其第二，较高粘度而不是主要的，可变的环境条件。

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