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    • 10. 发明申请
    • Stable and high solids aqueous dispersions of blocked polyisocyanates
    • 封闭多异氰酸酯的稳定和高固体含水分散体
    • US20020025996A1
    • 2002-02-28
    • US09982237
    • 2001-10-19
    • DEGUSSA-HUELS AKTIENGESELLSCHAFT
    • Hartwig LangeKlaus JanischewskiDirk Reichel
    • C08J003/00
    • C07C263/18C08G18/348C08G18/706C08G18/721C08G18/792C08G18/8077C09D175/04C07C265/14
    • A stable and high-solids aqueous dispersion of blocked isocyanates, containing auxiliary solvent, is prepared by (1) preparing a solution of a polyisocyanate mixture of from 20-70% by weight of a blocked, hydrophilically modified polyisocyanate (A) and from 30-80% by weight of a blocked, hydrophobic polyisocyanate (B) in an auxiliary solvent (G) and (2) adding water to this solution, with intensive mixing, in an amount which is such as to give a two-phase system comprising a disperse polyisocyanate phase and a continuous, aqueous phase containing auxiliary solvent. In a preferred embodiment of the invention dispersions are prepared which are virtually free from auxiliary solvent, by first adding a portion of water to the solution (1), substantially removing the auxiliary solvent with intensive mixing and then adding a second portion of water with intensive mixing to the mixture comprising the polyisocyanates (A) and (B) and the first portion of water.
    • 含有辅助溶剂的封闭异氰酸酯的稳定且高固含量的水分散体是通过(1)制备20-70重量%的封端的亲水改性多异氰酸酯(A)和30重量%的多异氰酸酯混合物 -80重量%的在助溶剂(G)中的封闭的疏水性多异氰酸酯(B)和(2)以强烈混合的方式向该溶液中加入水,其量使得产生两相系统,其包含 分散的多异氰酸酯相和含有辅助溶剂的连续的水相。 在本发明的优选实施方案中,通过首先向溶液(1)中加入一部分水,基本上除去辅助溶剂,同时强烈混合,然后加入第二部分水,制备基本上不含辅助溶剂的分散体 与包含多异氰酸酯(A)和(B)的混合物和第一部分水混合。