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1. 发明公开

EP1732957A1 METHOD OF CONTROLLING OLEFIN POLYMERIZATION 有权
标题翻译：用于控制的烯烃聚合
公开(公告)号：EP1732957A1
公开(公告)日：2006-12-20
申请号：EP05732744.7
申请日：2005-04-05
申请人： UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION , Davis, Mark B. , Madden, James D.
发明人： DAVIS, Mark, B. , MADDEN, James, D.
IPC分类号： C08F10/00 , C08F2/00
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6555 , C08F2/38 , C08F2500/01 , C08F2500/02 , C08F2500/05 , C08F2500/12 , C08F210/14
摘要： A method of making polyolefin with a target melt flow index and melt flow rate is disclosed. The method polymerizes one or more olefinic monomers in a single reactor containing a bicomponent catalyst system. The catalyst system includes a first catalyst component and a second catalyst component each characterized by a catalyst productivity and a chain-transfer-agent response. The single reactor has a chain-transfer-agent concentration and a temperature. The productivity of the second catalyst component is substantially different temperature dependent than that of the first catalyst component. The chain-transfer-agent response of the second catalyst component is substantially different sensitive than that of the first catalyst component. The temperature of the reactor is adjusted so that the melt flow ratio approaches the target value. The chain transfer agent concentration in the reactor is adjusted so that the melt index approaches the target value.

2. 发明申请

WO2010006097A1 POLYETHYLENE COMPOSITIONS, METHOD OF PRODUCING THE SAME, FIBERS MADE THEREFROM, AND METHOD OF MAKING THE SAME 审中-公开
标题翻译：聚乙烯组合物，其制造方法，其制造的纤维及其制造方法
公开(公告)号：WO2010006097A1
公开(公告)日：2010-01-14
申请号：PCT/US2009/050003
申请日：2009-07-09
申请人： DOW GLOBAL TECHNOLOGIES INC. , PEPPER, Randy, E. , KAPUR, Mridula , CLAASEN, Gert, J. , KNICKERBOCKER, Edward, N. , WIKER, Nathan, J. , MICHIE, William, J., Jr. , DAVIS, Mark, B.
发明人： PEPPER, Randy, E. , KAPUR, Mridula , CLAASEN, Gert, J. , KNICKERBOCKER, Edward, N. , WIKER, Nathan, J. , MICHIE, William, J., Jr. , DAVIS, Mark, B.
IPC分类号： C08L23/04 , D01F6/04 , D01F6/46 , D04H1/00
CPC分类号： D01F6/30 , C08F210/02 , C08L23/04 , C08L23/0815 , C08L2205/02 , C08L2205/16 , C08L2314/06 , D01D5/08 , D01D5/10 , D01D5/12 , D01D10/02 , D01F6/04 , D04H1/56 , D04H3/007 , D04H3/16 , Y10T428/249921 , Y10T442/30 , Y10T442/3976 , Y10T442/60 , C08L2666/06
摘要： The instant invention is a polyethylene composition, method of producing the same, fibers made therefrom, and method of making the same. The polyethylene composition according to instant invention comprises: (a) less than or equal to 100 percent by weight of the units derived from ethylene; and (b) less than 20 percent by weight of units derived from one or more α-olefin comonomers. The polyethylene composition according to instant invention has a density in the range of 0.920 to 0.970 g/cm 3 , a molecular weight distribution (M w /M n ) in the range of 1.70 to 3.5, a melt index (I 2 ) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (M z /M w ) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition. The process for producing the inventive polyethylene composition comprises the steps of: (1) (co)polymerizing ethylene and optionally one or more α- olefin comonomers in the presence of a hafnium based metallocene catalyst via a gas phase (co)polymerization process in a single stage reactor; and (2) thereby producing the polyethylene composition having a density in the range of 0.920 to 0.970 g/cm3, a molecular weight distribution (M w /M n ) in the range of 1.70 to 3.5, a melt index (I 2 ) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (M z /M w ) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition. The fibers according to the instant invention comprise a polyethylene composition comprising: (a) less than or equal to 100 percent by weight of the units derived from ethylene; and (b) less than 20 percent by weight of units derived from one or more α-olefin comonomers; wherein the polyethylene composition has a density in the range of 0.920 to 0.970 g/cm 3 , a molecular weight distribution (M w/ M n ) in the range of 1.70 to 3.5, a melt index (I 2 ) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (M z /M w ) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition. The process for making a fiber according to instant invention comprises the steps of: (1) selecting a polyethylene composition comprising: (a) less than or equal to 100 percent by weight of the units derived from ethylene; and (b) less than 20 percent by weight of units derived from one or more α-olefin comonomers; wherein the polyethylene composition has a density in the range of 0.920 to 0.970 g/cm 3, a molecular weight distribution (M w /M n ) in the range of 1.70 to 3.5, a melt index (I 2 ) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (M z/ M w ) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition; (2) spinning the polyethylene composition into a fiber; and (3) thereby forming the fiber.
摘要翻译：本发明是聚乙烯组合物，其制造方法，由其制成的纤维及其制造方法。根据本发明的聚乙烯组合物包含：（a）小于或等于100重量％的衍生自乙烯的单元; 和（b）少于20重量％的衍生自一种或多种α-烯烃共聚单体的单元。本发明的聚乙烯组合物的密度范围为0.920〜0.970g / cm3，分子量分布（Mw / Mn）为1.70〜3.5，熔体指数（I2）为0.2〜 1000g / 10分钟，小于2.5的分子量分布（Mz / Mw），存在于组合物主链中的每1000个碳原子的乙烯基不饱和度小于0.1个乙烯基。制备本发明的聚乙烯组合物的方法包括以下步骤：（1）在铪基金属茂催化剂存在下，通过气相（共）聚合方法在（a）共聚物中共聚合乙烯和任选的一种或多种α-烯烃共聚单体单级反应器; 和（2）由此制备密度在0.920至0.970g / cm3范围内的聚乙烯组合物，分子量分布（Mw / Mn）在1.70至3.5的范围内，熔体指数（I2）在 0.2至1000g / 10分钟，小于2.5的分子量分布（Mz / Mw），存在于组合物主链中的每1000个碳原子的乙烯基不饱和度小于0.1个乙烯基。根据本发明的纤维包含聚乙烯组合物，其包含：（a）小于或等于100重量％的衍生自乙烯的单元; 和（b）少于20重量％的衍生自一种或多种α-烯烃共聚单体的单元; 其中，所述聚乙烯组合物的密度为0.920〜0.970g / cm 3，分子量分布（Mw / Mn）为1.70〜3.5，熔体指数（I2）为0.2〜1000g / 10分钟，小于2.5的范围内的分子量分布（Mz / Mw），存在于组合物的骨架中的每1000个碳原子的乙烯基不饱和度小于0.1个乙烯基。根据本发明的制备纤维的方法包括以下步骤：（1）选择聚乙烯组合物，其包含：（a）小于或等于100重量％的衍生自乙烯的单元; 和（b）少于20重量％的衍生自一种或多种α-烯烃共聚单体的单元; 其中，所述聚乙烯组合物的密度为0.920〜0.970g / cm 3，分子量分布（Mw / Mn）为1.70〜3.5，熔体指数（I2）为0.2〜1000g / 10分钟，小于2.5的范围内的分子量分布（Mz / Mw），存在于组合物的骨架中的每1000个碳原子的乙烯基不饱和度小于0.1个乙烯基; （2）将聚乙烯组合物纺丝成纤维; 和（3）从而形成纤维。

3. 发明申请

WO2009082451A2 METHOD FOR CONTROLLING BIMODAL CATALYST ACTIVITY DURING POLYMERIZATION 审中-公开
标题翻译：在聚合过程中控制二元催化剂活性的方法
公开(公告)号：WO2009082451A2
公开(公告)日：2009-07-02
申请号：PCT/US2008/013792
申请日：2008-12-17
申请人： UNIVATION TECHNOLOGIES, LLC , BLOOD, Mark, W. , SAVATSKY, Bruce, J. , OSKAM, John, H. , DAVIS, Mark, B. , JACKSON, Douglas, H. , LYNN, Timothy, R. , ZILKER, Daniel, P.
发明人： BLOOD, Mark, W. , SAVATSKY, Bruce, J. , OSKAM, John, H. , DAVIS, Mark, B. , JACKSON, Douglas, H. , LYNN, Timothy, R. , ZILKER, Daniel, P.
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/659 , C08F4/65925 , C08F110/02 , C08F4/65904 , C08F2/34 , C08F2/38 , C08F2500/05
摘要： A method of performing a polymerization reaction in a gas phase polymerization reactor to produce a bimodal polymer while controlling activity of a bimodal polymerization catalyst composition in the reactor by controlling concentration of at least one induced condensing agent ('ICA') in the reactor is provided. In some embodiments, the ICA is isopentane (or another hydrocarbon compound) and the bimodal catalyst composition includes a Group 15 and metal containing catalyst compound (or other HMW catalyst for catalyzing polymerization of a high molecular weight fraction of the product), and a metallocene catalyst compound (or other LMW catalyst for catalyzing polymerization of a low molecular weight fraction of the product).
摘要翻译：提供了在气相聚合反应器中进行聚合反应以制备双峰聚合物的方法，同时通过控制反应器中至少一种诱导的缩合剂（'ICA'）的浓度来控制反应器中双峰聚合催化剂组合物的活性。在一些实施方案中，ICA是异戊烷（或另一种烃化合物），双峰催化剂组合物包括第15族和含金属的催化剂化合物（或用于催化产物的高分子量级分聚合的其它HMW催化剂）和茂金属催化剂化合物（或用于催化产物的低分子量级分的聚合的其它LMW催化剂）。

4. 发明申请

WO2005118127A3 AN ANGULAR FLOW DISTRIBUTION BOTTOM HEAD 审中-公开
标题翻译：直角流分布底部头
公开(公告)号：WO2005118127A3
公开(公告)日：2007-03-15
申请号：PCT/US2005010402
申请日：2005-03-29
申请人： UNIVATION TECH LLC , DAVIS MARK B , PERRY WESLEY J
发明人： DAVIS MARK B , PERRY WESLEY J
IPC分类号： B01J8/08 , B01J8/18 , B01J8/24 , B01J8/44
CPC分类号： B01J8/1827
摘要： An angled annular deflector (9) for angular flow distribution in a fluidized bed polymerization reactor. The angled annular deflector (9) has an outer surface (27) with a conical shape and an inner cavity (15) along a central axis, said cavity open at both ends. The angled annular deflector (9) being adapted to associate with a cone-shaped bottom portion (3) of a fluidized bed polymerization reactor vessel and when in said association the outer surface (27) of said angled annular deflector (9) is at an angle to be substantially parallel to an inner wall (224) of the cone-shaped bottom portion (3).
摘要翻译：在流化床聚合反应器中用于角流量分布的成角度的环形偏转器（9）。成角度的环形偏转器（9）具有圆锥形的外表面（27）和沿着中心轴线的内腔（15），所述空腔在两端敞开。角度的环形偏转器（9）适于与流化床聚合反应器容器的锥形底部（3）相关联，并且当处于所述关联时，所述成角度的环形偏转器（9）的外表面（27）处于角度基本上平行于锥形底部（3）的内壁（224）。

5. 发明申请

WO2009067201A1 METHODS FOR MAKING POLYOLEFINS 审中-公开
标题翻译：制备聚烯烃的方法
公开(公告)号：WO2009067201A1
公开(公告)日：2009-05-28
申请号：PCT/US2008/012898
申请日：2008-11-19
申请人： UNIVATION TECHNOLOGIES, LLC , DAVIS, Mark, B. , KAO, Sun-chueh , KWALK, Tae Hoon
发明人： DAVIS, Mark, B. , KAO, Sun-chueh , KWALK, Tae Hoon
IPC分类号： C08F10/00 , C08F2/38
CPC分类号： C08F10/00 , C08F4/659 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F210/16 , C08F2420/02 , C08F2/38 , C08F2/00 , C08F4/65904 , C08F2500/12 , C08F2500/07
摘要： A method for making a polyolefin composition according to one embodiment includes altering the concentration of the chain transfer agent present in the reactor to control the HMW and LMW fractions of the polyolefin composition.
摘要翻译：制备根据一个实施方案的聚烯烃组合物的方法包括改变存在于反应器中的链转移剂的浓度以控制聚烯烃组合物的HMW和LMW级分。

6. 发明申请

WO2008063463A1 SYSTEM FOR FLUIDIZING SOLID PARTICLES INCLUDING NOVEL OUTLET FOR VESSEL 审中-公开
标题翻译：用于流化固体颗粒的系统，包括用于容器的新型出口
公开(公告)号：WO2008063463A1
公开(公告)日：2008-05-29
申请号：PCT/US2007/023750
申请日：2007-11-13
申请人： UNIVATION TECHNOLOGIES, LLC , HAGERTY, Robert, O. , DAVIS, Mark, B. , DECHELLIS, Marc, L. , HUSSEIN, David, F.
发明人： HAGERTY, Robert, O. , DAVIS, Mark, B. , DECHELLIS, Marc, L. , HUSSEIN, David, F.
IPC分类号： F27B15/00
CPC分类号： B01J8/1872 , B01J2208/00061 , B01J2208/00256 , B01J2208/00274 , B01J2219/00247 , C08F10/00 , C08F2/34
摘要： A system for fluidizing solid particles is provided, wherein the fluidized bed system includes a fluidized bed vessel, a fluidized bed section, a disengagement section, a recycle line, and a tapered outlet. Also provided is a method of fluidizing solids by providing a system as described above, fluidizing a bed comprising solid particles, and removing a recycle stream through the tapered outlet.
摘要翻译：提供了一种用于使固体颗粒流化的系统，其中流化床系统包括流化床容器，流化床部分，分离部分，再循环管线和锥形出口。还提供了通过提供如上所述的系统来使固体流化的方法，使包含固体颗粒的床流化，并且通过锥形出口除去再循环流。

7. 发明申请

WO2008042182A1 METHOD FOR PREVENTING CATALYST AGGLOMERATION BASED ON PRODUCTION RATE CHANGES 审中-公开
标题翻译：基于生产率变化预防催化剂组合的方法
公开(公告)号：WO2008042182A1
公开(公告)日：2008-04-10
申请号：PCT/US2007/020762
申请日：2007-09-26
申请人： UNIVATION TECHNOLOGIES, LLC , SAVATSKY, Bruce, J. , DAVIS, Mark, B. , TERRY, Kersten, A. , BLOOD, Mark, W. , OSKAM, John, H. , LYNN, Timothy, R.
发明人： TERRY, Kersten, A. , BLOOD, Mark, W. , OSKAM, John, H. , LYNN, Timothy, R.
IPC分类号： C08F2/01
CPC分类号： C10G50/00 , B01J4/002 , B01J8/1809 , B01J8/1827 , B01J2208/00274 , C08F10/00 , C08F2400/02 , C10G2300/1088 , C10G2300/1096 , C10G2400/22 , C10G2400/30 , Y10S526/919 , C08F2/00 , C08F2/01
摘要： A system and method for olefin polymerization is provided. The method includes polymerizing one or more olefins within a reactor having one or more injection tubes in fluid communication therewith, at least one of the one or more injection tubes having two or more concentric flow paths; flowing a catalyst through a first flow concentric path of the injection tube into the reactor; flowing one or more monomers through a second concentric flow path of the injection tube into the reactor; measuring rate of heat removal within the reactor; and adjusting the one or more monomers flow through the injection tube in response to the rate of heat removal in the reactor.
摘要翻译：提供了一种用于烯烃聚合的体系和方法。该方法包括在反应器内聚合一种或多种烯烃，所述反应器具有与其流体连通的一个或多个注射管，所述一个或多个注射管中的至少一个具有两个或更多个同心的流动路径; 将催化剂流经注射管的第一流动同心径流入反应器; 使一种或多种单体通过注入管的第二同心流动路径流入反应器; 测量反应器内的热量去除率; 以及响应于反应器中的除热速率，调节一个或多个单体流过注射管。

8. 发明申请

WO2008042078A1 EFFERVESCENT NOZZLE FOR CATALYST INJECTION 审中-公开
标题翻译：用于催化剂注射的高效喷嘴
公开(公告)号：WO2008042078A1
公开(公告)日：2008-04-10
申请号：PCT/US2007/019642
申请日：2007-09-10
申请人： UNIVATION TECHNOLOGIES, LLC , TERRY, Kersten, A. , BLOOD, Mark, W. , OSKAM, John, H. , LYNN, Timothy, R. , SAVATSKY, Bruce, J. , DAVIS, Mark, B. , ZILKER, Daniel, P. , LIPP, Charles, W.
发明人： TERRY, Kersten, A. , BLOOD, Mark, W. , OSKAM, John, H. , LYNN, Timothy, R. , SAVATSKY, Bruce, J. , DAVIS, Mark, B. , ZILKER, Daniel, P. , LIPP, Charles, W.
IPC分类号： C08F2/01
CPC分类号： B01J8/1827 , B01J4/002 , B01J8/004 , B01J8/20 , B01J8/22 , B01J19/26 , B01J2208/00371 , B01J2208/00752 , B01J2208/00769 , C08F10/00 , C08F2/01
摘要： A nozzle for catalyst injection for olefin polymerization is provided. In one or more embodiments the nozzle includes a first conduit including a body, a tapered section, and an injection tip. The nozzle also includes a second conduit having an inner surface and an outer surface. The first conduit is disposed about the second conduit defining a first annulus therebetween. The nozzle further includes a support member at least partially disposed about the outer surface of the first conduit defining a second annulus therebetween. The support member has a converging outer surface at a first end thereof.
摘要翻译：提供了用于烯烃聚合的催化剂注入用喷嘴。在一个或多个实施例中，喷嘴包括包括主体，锥形部分和注射尖端的第一导管。喷嘴还包括具有内表面和外表面的第二导管。第一导管设置在第二导管周围，在第二导管之间限定第一环。所述喷嘴还包括至少部分地设置在所述第一管道的外表面周围在其间限定第二环形空间的支撑构件。支撑构件在其第一端具有会聚的外表面。

9. 发明申请

WO2005118127A2 AN ANGULAR FLOW DISTRIBUTION BOTTOM HEAD 审中-公开
标题翻译：直角流分布底部头
公开(公告)号：WO2005118127A2
公开(公告)日：2005-12-15
申请号：PCT/US2005/010402
申请日：2005-03-29
申请人： UNIVATION TECHNOLOGIES, LLC , DAVIS, Mark, B. , PERRY, Wesley, J.
发明人： DAVIS, Mark, B. , PERRY, Wesley, J.
IPC分类号： B01J8/18
CPC分类号： B01J8/1827
摘要： An improved angled annular deflector for angular flow distribution in a fluidized bed polymerization reactor. The angled annular deflector has an outer surface with a conical shape and an inner cavity along a central axis, said cavity open at both ends. The angled annular deflector being adapted to associate with a cone-shaped bottom portion of a fluidized bed polymerization reactor vessel and when in said association the outer surface of said angled annular deflector is at an angle to be substantially parallel to an inner wall of the cone-shaped bottom portion. This combination leads to increased optimization of fluid flow.
摘要翻译：一种用于流化床聚合反应器中角流分布的改进的角度环形偏转器。成角度的环形偏转器具有圆锥形的外表面和沿着中心轴线的内腔，所述空腔在两端敞开。成角度的环形偏转器适于与流化床聚合反应器容器的锥形底部相关联，并且当处于所述缔合时，所述成角度的环形偏转器的外表面的角度基本上平行于锥体的内壁形底部。这种组合导致流体流动优化的增加。

10. 发明申请

WO2005061561A1 POLYETHYLENE FILMS 审中-公开
标题翻译：聚乙烯薄膜
公开(公告)号：WO2005061561A1
公开(公告)日：2005-07-07
申请号：PCT/US2004/009807
申请日：2004-03-31
申请人： UNIVATION TECHNOLOGIES, LLC , SHANNON, Porter, C. , KUMAR, Rakesh , SHIRODKAR, Pradeep, P. , EHRMAN, Fred, D. , DAVIS, Mark, B. , TRAPP, Keith, W. , DONGMING, Li
发明人： SHANNON, Porter, C. , KUMAR, Rakesh , SHIRODKAR, Pradeep, P. , EHRMAN, Fred, D. , DAVIS, Mark, B. , TRAPP, Keith, W. , DONGMING, Li
IPC分类号： C08F10/02
CPC分类号： C08L23/0815 , C08F210/16 , C08L2205/02 , C08L2205/025 , C08L2666/06 , C08F210/08 , C08F2500/12 , C08F2500/02 , C08F2500/01 , C08F2500/05 , C08F2500/26
摘要： A film comprising a polyethylene composition, the polyethylene composition in one embodiment comprising a high molecular weight component having a weight average molecular weight of greater than 50,000 amu and a low molecular weight component having a weight average molecular weight of less than 50,000 amu; the polyethylene composition possessing a density of between 0.940 and 0.970 g/cm 3 , and an I 21 value of less than 20 dg/min; characterized in that the polyethylene composition extrudes at an advantageously high specific throughput at an advantageously low melt temperature, and wherein the film has a gel count of less than 100.
摘要翻译：一种包含聚乙烯组合物的膜，一个实施方案中的聚乙烯组合物包含重均分子量大于50,000amu的高分子量组分和重均分子量小于50,000amu的低分子量组分; 聚乙烯组合物的密度为0.940〜0.970g / cm 3，I21值小于20dg / min; 其特征在于，所述聚乙烯组合物在有利的低熔融温度下以有利的高比生产量挤出，并且其中所述膜的凝胶计数小于100。

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