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    • 9. 发明申请
    • DITHIENOPHTHALIMIDE SEMICONDUCTOR POLYMERS
    • 二苯基二胺半导体聚合物
    • WO2013004730A1
    • 2013-01-10
    • PCT/EP2012/062996
    • 2012-07-04
    • BASF SENOGUCHI, HiroyoshiDÖTZ, FlorianMISHRA, Ashok, KumarVAIDYANATHAN, SubramanianMINH-TIEN, Mai
    • NOGUCHI, HiroyoshiDÖTZ, FlorianMISHRA, Ashok, KumarVAIDYANATHAN, SubramanianMINH-TIEN, Mai
    • C08G61/12C09K11/00H01B1/00H01L51/00
    • H01L51/0036C08G61/126C08G2261/124C08G2261/1412C08G2261/3223C08G2261/3327C08G2261/344C08G2261/364C08G2261/92H01L51/0043H01L51/0558Y02E10/549
    • The invention concerns apolymer of the formula (I): wherein: M1 is an optionally substituted dithienophthalimide formula (II): wherein: X is N or C-R, wherein R is H or a C 1 -C 40 alkyl group, R 1 , at each occurrence, is independently selected from H, a C 1-40 alkyl group, a C 2-40 alkenyl group, a C 1-40 haloalkyl group, and a monocyclicor polycyclic moiety, wherein: each of the C 1-40 alkyl group, the C 2-40 alkenyl group, and the C 1-40 haloalkyl group can be optionally substituted with 1-10 substituents independently selected from a halogen, CN, -NO 2 , OH, NH 2 , -NH(C 1-20 alkyl), N(C 1-20 alkyl) 2 , -S(O) 2 OH, -CHO, -C(O)-C 1-20 alkyl, -C(O)OH, -C(O)-OC 1-20 alkyl, -C(O)NH 2 , -C(O)NH-C 1-20 alkyl, -C(O)N(C 1-20 alkyl) 2 , -OC 1-20 alkyl, -SiH 3 , -SiH(C 1-20 alkyl) 2 , -SiH 2 (C 1-20 alkyl), and -Si(C 1-20 alkyl) 3 ; and the monocyclic or polycyclic moiety can be covalently bonded to the imide nitrogen via an optional linker, and can be optionally substituted with 1-5 substituentsindependently selected from a halogen, oxo, -CN, -NO 2 , OH, =C(CN) 2 , -NH 2 , -NH(C 1-20 alkyl), N(C 1-20 alkyl) 2 , -S(O) 2 OH,-CHO, -C(O)OH, -C(O)-C 1-20 alkyl, -C(O)-OC 1-20 alkyl, -C(O)NH 2 , -C(O)NH-C 1-20 alkyl, -C(O)N(C 1-20 alkyl) 2 , -SiH 3 , -SiH(C 1-20 alkyl) 2 , -SiH 2 (C 1-20 alkyl), -Si(C 1-20 alkyl) 3 ,-O-C 1-20 alkyl, -O-C 1-20 alkenyl, -O-C 1-20 haloalkyl, C 1-20 alkyl, C 1-20 alkenyl, C 1-20 haloalkyl, C 7-20 arylalkyl, C 6-20 aryloxy and C 7-20 arylcarbonyl. M 2 is a repeating unit comprising one or more cyclic moieties; and n is an integer between 2 and 5,000.
    • 本发明涉及式(I)的聚合物:其中:M1是任选取代的二噻吩邻苯二甲酰亚胺式(II):其中:X是N或CR,其中R是H或C 1 -C 40烷基, 独立地选自H,C 1-4烷基,C 2-40链烯基,C 1-40卤代烷基和单环多环部分,其中:C 1-4烷基,C 2-40链烯基 ,C 1-4卤代烷基可以任选地被1-10个独立地选自卤素,CN,-NO 2,OH,NH 2,-NH(C 1-20烷基),N(C 1-20烷基) -S(O)2 OH,-CHO,-C(O)-C 1-20烷基,-C(O)OH,-C(O)-OC 1-20烷基,-C(O)NH 2,-C )NH-C 1-20烷基,-C(O)N(C 1-20烷基)2,-OC 1-20烷基,-SiH 3,-SiH(C 1-20烷基)2,-SiH 2(C 1-20烷基) 和-Si(C 1-20烷基)3; 并且单环或多环部分可以经由任选的接头共价键合到酰亚胺氮上,并且可以任选被1-5个取代基取代,所述取代基独立地选自卤素,氧代,-CN,-NO 2,OH,= C(CN)2 ,-NH 2,-NH(C 1-20烷基),N(C 1-20烷基)2,-S(O)2 OH,-CHO,-C(O)OH,-C(O) -C(O)-OC 1-20烷基,-C(O)NH 2,-C(O)NH-C 1-20烷基,-C(O)N(C 1-20烷基)2,-SiH 3,-SiH C 1-20烷基)2,-SiH 2(C 1-20烷基),-Si(C 1-20烷基)3,-O-C 1-20烷基,-O-C 1-20烯基,-O-C 1-20卤代烷基, C 1-20烷基,C 1-20烯基,C 1-20卤代烷基,C 7-20芳基烷基,C 6-20芳氧基和C 7-20芳基羰基。 M2是包含一个或多个环状部分的重复单元; n为2〜5,000的整数。