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    • 4. 发明申请
    • Method for producing bi-continuous and high internal phase nanostructures
    • 生产双连续和高内相纳米结构的方法
    • US20080001116A1
    • 2008-01-03
    • US11810895
    • 2007-06-07
    • Glenn FredricksonEdward KramerBumjoon KimCraig Hawker
    • Glenn FredricksonEdward KramerBumjoon KimCraig Hawker
    • H01L29/12
    • C08J3/005C08K5/0008C08K9/08
    • A process for producing bi-continuous morphologies in polymer melts and solids, wherein two distinct domains or phases percolate and macroscopically connect throughout the composition. The process proceeds by simply mixing the components in a common solvent and casting a film by slow removal of the solvent. Bulk materials can be produced by mixing the components in an extruder, compounder, or other specialized equipment for processing molten polymers, and forming into a pellet, fiber, film, sheet, or molded part. The invention allows the production of materials with unique or unusual combinations of transparency, high electronic or ionic conductivity, high vapor transport rates, and/or high absorption rates of moisture or vapors . Particles used in the present invention are 5-10 nm to yield a scale of the bi-continuous structures of 10-50 nm. The materials can be produced in bulk form, or in films 1-100 microns thick.
    • 在聚合物熔体和固体中生产双连续形态的方法,其中两个不同的结构域或相渗透并且宏观地连接整个组合物。 该方法通过简单地将组分混合在普通溶剂中并通过缓慢除去溶剂来浇铸膜来进行。 散装材料可以通过在挤出机,混炼机或其他用于加工熔融聚合物的专用设备中混合组分并形成颗粒,纤维,薄膜,片材或模制件来制备。 本发明允许生产具有透明度,高电子或离子电导率,高蒸气传输速率和/或高吸收率的水分或蒸汽的独特或不寻常的组合的材料。 在本发明中使用的颗粒为5-10nm,以产生10-50nm双连续结构的尺度。 这些材料可以以块状形式或1-100微米厚的薄膜生产。