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1. 发明公开

EP1758850A1 PREPARATION AND APPLICATIONS OF POLYMER-SUPPORTED HALOGENATED BENZOQUINONES AS OXIDATIVE AGENTS 审中-公开
标题翻译： HERSTELLUNG UND ANWENDUNGEN VONPOLYMERGETRÄGERTENHALOGENITENTEN BENZOCHINONEN ALS OxyidationSMITTEL
公开(公告)号：EP1758850A1
公开(公告)日：2007-03-07
申请号：EP04736534.1
申请日：2004-06-10
申请人： COULADOUROS, Elias, Andrea , Strongilos, Alexandros
发明人： COULADOUROS, Elias, Andrea , Strongilos, Alexandros
IPC分类号： C07C255/46 , C07C317/44 , C07B33/00 , C07J75/00
CPC分类号： C07C255/57 , C07B2200/11 , C07C255/53 , C07C255/54 , C07C255/55 , C07C317/44 , C07C2601/16 , C07J75/00 , Y02P20/55
摘要： This invention provides a general method for the synthesis of polymer-supported benzoquinones described by the following generic structure I: wherein: •, X, R1, R2 and R3 are described in the main text. The general concept of the method consists of the use of a halogenated starting material of the general structure II (Figure 1) which by an nucleophilic substitution reaction (NSR) or a palladium mediated coupling (PMC) is either directly loaded on a resin to afford IIIa (Path A) or transformed to intermediate IIIb (Path B) which is subsequently (with or without modification) loaded on a resin to afford once again IIIa. Deprotection and/or oxidation of IIIa, if needed, afford target solid-supported oxidants I The polymer-supported benzoquinones I are used for the oxidation of hydroquinones to quinones, for the oxidation of benzylic alcohols the aldehydes, for the removal of p-methoxybenzyl and related protective groups, for the dehydrogenation of tetrahydronaphthalene derivatives and for the dehydrogenation of steroid 4-en-3-ones. The polymer-supported reagent after its use is regenerated upon treatment with an oxidative agent.
摘要翻译：本发明提供了通过以下通用结构I描述的合成聚合物负载的苯醌的一般方法：其中：。，X，R 1，R 2和R 3在正文中描述。该方法的一般概念包括使用一般结构II（图1）的卤化起始材料，其通过亲核取代反应（NSR）或钯介导的偶联（PMC）直接负载在树脂上以提供 IIIa（路径A）或转化成中间体IIIb（路径B），其随后（有或没有改性）负载在树脂上以再次提供IIIa。如果需要，IIIa的脱保护和/或氧化提供目标固体负载的氧化剂I聚合物负载的苯醌I用于将氢醌氧化成醌，用于苄基醇的氧化醛，用于除去对甲氧基苄基和相关的保护基团，用于四氢萘衍生物的脱氢和类固醇4-烯-3-酮的脱氢。使用后的聚合物负载的试剂在用氧化剂处理时再生。

2. 发明公开

EP1675835A1 METHODS OF PREPARATION OF DEHYDRO-DIKETOPIPERAZINES IN LIQUID PHASE OR OF SOLID SUPPORTED PHASE 有权
标题翻译：工艺用于液体相PRODUCING脱氢DIKETOPYPERAZINEN或通过固相合成
公开(公告)号：EP1675835A1
公开(公告)日：2006-07-05
申请号：EP03738352.8
申请日：2003-07-07
申请人： Couladouros, Elias Andrea , Magos, Alexandros , Strongilos, Alexandros
发明人： Couladouros, Elias Andrea , Magos, Alexandros , Strongilos, Alexandros
IPC分类号： C07D241/18 , C07D403/06 , A61K31/496 , A61P35/00 , C07K5/12
CPC分类号： A61K31/496 , C07D241/18 , C07D401/06 , C07D403/06 , C07D403/14 , C07D405/06 , C07D409/06 , C07D409/14 , C07D417/06 , C07D417/14 , C07D487/04 , Y02P20/55
摘要： The preparation of any compound of the generic structure (I); wherein: R1 and R2 are substituents described in the main text. Cycl- is a group represented by either of the formulae (a) and (b); wherein: R3 to R8, X and Y are substituents described in the main text. The above described compounds may be used for the treatment of cancer. The preparation method consists of coupling of the amine group of phosphynilglycinate with the carboxylic group of an aminoacid, the successively coupling of the above formed compound with the formyl-Cycl derivative, the deprotection of the aminoacid and the formation of dehydro-diketopiperazine employing mild alkaline conditions. The method is extended for the preparation of individual derivatives or libraries of derivatives related to the above described compounds of the general formula (II), employing a solid supported phosphonate of the general formula (II), wherein: Res represents any polymer support (resin) with or without a linker, Prot represents any NH- protective group, R represents alkyl or alkyloxyalkyl groups.

3. 发明授权

EP1444550B1 POLYCARBOCYCLIC DERIVATIVES FOR MODIFICATION OF RESIST, OPTICAL AND ETCH RESISTANCE PROPERTIES 有权
标题翻译：多环芳烃衍生物来改变光学性能和ÄTZBESTÄNDIGKEITSEIGNENSCHAFTEN
公开(公告)号：EP1444550B1
公开(公告)日：2005-09-21
申请号：EP02790329.3
申请日：2002-10-31
申请人： NCSR DEMOKRITOS , GOGOLIDES, Evangelos , Argitis, Panagiotis , COULADOUROS, Elias, Andrea
发明人： GOGOLIDES, Evangelos , ARGITIS, Panagiotis , COULADOUROS, Elias, Andrea Chemical Laboratories , VIDALI, Veroniki, Petrou Institute of Physical , VASILOPOULOU, Maria , CORDOYIANNIS, George
IPC分类号： G03F7/004 , C07C69/00
CPC分类号： C07C69/40 , C07C69/753 , C07C69/76 , C07C69/96 , C07C211/31 , C07C211/42 , C07C211/61 , C07C233/65 , C07C2601/14 , C07C2603/24 , C07C2603/74 , C07H13/08 , C07J7/002 , C07J41/005 , G03F7/0045 , G03F7/0392 , Y10S430/106 , Y10S430/111
摘要： Mixed carbocycle derivatives containing at least two carbocycles per molecule from the group of anthracenes, adamantanes and steroids with functionalized carbon chains are synthesized and used as modifiers of resist properties and especially etch resistance enhancement and absorption characteristics. These derivatives are characterized by formulas I-V, where A and R may be an anthryl- and/or an adamantyl- and/or a steroid moiety. Methods for the preparation of the above compounds are disclosed.

4. 发明公开

EP1444550A2 POLYCARBOCYCLIC DERIVATIVES FOR MODIFICATION OF RESIST, OPTICAL AND ETCH RESISTANCE PROPERTIES 有权
标题翻译： POLYCYCLISCHE DERIVATE ZUR VERNDNDUNG DER OPTISCHEN EIGENSCHAFTEN UNDÄTZBESTÄNDIGKEITSEIGNENSCHAFTEN
公开(公告)号：EP1444550A2
公开(公告)日：2004-08-11
申请号：EP02790329.3
申请日：2002-10-31
申请人： NCSR DEMOKRITOS , GOGOLIDES, Evangelos , ARGITIS, Panagiotis , COULADOUROS, Elias, Andrea
发明人： GOGOLIDES, Evangelos , ARGITIS, Panagiotis , COULADOUROS, Elias, AndreaChemical Laboratories , VIDALI,Veroniki P.Institute of Physical Chemistry , VASILOPOULOU, Maria , CORDOYIANNIS, George
IPC分类号： G03F7/004 , C07C69/00
CPC分类号： C07C69/40 , C07C69/753 , C07C69/76 , C07C69/96 , C07C211/31 , C07C211/42 , C07C211/61 , C07C233/65 , C07C2601/14 , C07C2603/24 , C07C2603/74 , C07H13/08 , C07J7/002 , C07J41/005 , G03F7/0045 , G03F7/0392 , Y10S430/106 , Y10S430/111
摘要： Mixed carbocycle derivatives containing at least two carbocycles per molecule from the group of anthracenes, adamantanes and steroids with functionalized carbon chains are synthesized and used as modifiers of resist properties and especially etch resistance enhancement and absorption characteristics. These derivatives are characterized by formulas I-V, where A and R may be an anthryl- and/or an adamantyl- and/or a steroid moiety. Methods for the preparation of the above compounds are disclosed.
摘要翻译：合成了具有官能化碳链的蒽，金刚烷和类固醇的每分子含有至少两个碳环的混合碳环衍生物，并用作抗蚀剂性质的改性剂，特别是耐蚀性增强和吸收特性。这些衍生物由式I-V表征，其中A和R可以是蒽基和/或金刚烷基和/或类固醇部分。公开了制备上述化合物的方法。

5. 发明申请

WO2003038523A3 POLYCARBOCYCLIC DERIVATIVES FOR MODIFICATION OF RESIST, OPTICAL AND ETCH RESISTANCE PROPERTIES 审中-公开
公开(公告)号：WO2003038523A3
公开(公告)日：2003-05-08
申请号：PCT/EP2002/012284
申请日：2002-10-31
申请人： NCSR DEMOKRITOS , GOGOLIDES, Evangelos , ARGITIS, Panagiotis , COULADOUROS, Elias, Andrea , VIDALI, Veroniki, Petrou , VASILOPOULOU, Maria , CORDOYIANNIS, George
发明人： GOGOLIDES, Evangelos , ARGITIS, Panagiotis , COULADOUROS, Elias, Andrea , VIDALI, Veroniki, Petrou , VASILOPOULOU, Maria , CORDOYIANNIS, George
IPC分类号： G03F7/004
摘要： Mixed carbocycle derivatives containing at least two carbocycles per molecule from the group of anthracenes, adamantanes and steroids with functionalized carbon chains are synthesized and used as modifiers of resist properties and especially etch resistance enhancement and absorption characteristics. These derivatives are characterized by formulas I-V, where A and R may be an anthryl- and/or an adamantyl- and/or a steroid moiety. Methods for the preparation of the above compounds are disclosed.

7. 发明申请

WO2003038523A2 POLYCARBOCYCLIC DERIVATIVES FOR MODIFICATION OF RESIST, OPTICAL AND ETCH RESISTANCE PROPERTIES 审中-公开
标题翻译：用于改变抗蚀性，光学性和蚀刻性的聚碳酸环状衍生物
公开(公告)号：WO2003038523A2
公开(公告)日：2003-05-08
申请号：PCT/EP2002/012284
申请日：2002-10-31
申请人： NCSR DEMOKRITOS , GOGOLIDES, Evangelos , ARGITIS, Panagiotis , COULADOUROS, Elias, Andrea , VIDALI, Veroniki, Petrou , VASILOPOULOU, Maria , CORDOYIANNIS, George
发明人： GOGOLIDES, Evangelos , ARGITIS, Panagiotis , COULADOUROS, Elias, Andrea , VIDALI, Veroniki, Petrou , VASILOPOULOU, Maria , CORDOYIANNIS, George
IPC分类号： G03F7/00
CPC分类号： C07C69/40 , C07C69/753 , C07C69/76 , C07C69/96 , C07C211/31 , C07C211/42 , C07C211/61 , C07C233/65 , C07C2601/14 , C07C2603/24 , C07C2603/74 , C07H13/08 , C07J7/002 , C07J41/005 , G03F7/0045 , G03F7/0392 , Y10S430/106 , Y10S430/111
摘要： Mixed carbocycle derivatives containing at least two carbocycles per molecule from the group of anthracenes, adamantanes and steroids with functionalized carbon chains are synthesized and used as modifiers of resist properties and especially etch resistance enhancement and absorption characteristics. These derivatives are characterized by formulas I-V, where A and R may be an anthryl- and/or an adamantyl- and/or a steroid moiety. Methods for the preparation of the above compounds are disclosed.
摘要翻译：合成具有官能化碳链的蒽，金刚烷和甾族化合物的每个分子中含有至少两个碳环的混合碳环衍生物，并用作抗蚀剂性能的改性剂，特别是耐蚀性增强和吸收特性。这些衍生物由式I-V表征，其中A和R可以是蒽基和/或金刚烷基和/或类固醇部分。公开了制备上述化合物的方法。

8. 发明专利

AT305145T 未知
公开(公告)号：AT305145T
公开(公告)日：2005-10-15
申请号：AT02790329
申请日：2002-10-31
申请人： NCSR DEMOKRITOS , GOGOLIDES EVANGELOS , ARGITIS PANAGIOTIS , COULADOUROS ELIAS ANDREA
发明人： GOGOLIDES EVANGELOS , ARGITIS PANAGIOTIS , COULADOUROS ELIAS ANDREA , VIDALI VERONIKI , VASILOPOULOU MARIA , CORDOYIANNIS GEORGE
IPC分类号： C07C69/00 , C07C69/96 , C07C211/31 , C07C211/42 , C07C211/61 , C07C233/65 , C07H13/08 , C07J7/00 , C07J41/00 , G03F7/004 , G03F7/039

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