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    • 1. 发明授权
    • Alkaline soluble maleimide-containing polymers
    • 含碱性可溶性马来酰亚胺的聚合物
    • US06586560B1
    • 2003-07-01
    • US09954888
    • 2001-09-18
    • Cindy X. ChenRodney Hurditch
    • Cindy X. ChenRodney Hurditch
    • C08G6908
    • C08F222/40C08G73/12
    • An alkaline soluble maleimide tetrapolymer of Formulae I or II prepared by the free radical polymerization of the monomers maleimide, N-alkyl maleimide, (methyl)methacrylate and either (meth)acrylic acid or (meth)acrylate: wherein R is an alkyl having I to 4 carbon atoms; each R1, R2 and R3 is individually selected from hydrogen or methyl; each m is the mole fraction of maleimide and has a value of 5 to 20%, each n is a mole fraction of N-alkyl maleimide and has a value of about 50 to 70%, each x is the mole fraction of methyl(meth)acrylate and has a value of about 15 15 to 30%, y is the mole fraction of (meth)acrylic acid and has a value 3 to 12%, and z is the mole fraction of (meth)acrylamide and has a value of about 4 to 15%, wherein the values of m, n, x, y in Formula I and m, n, x and z in Formula II are such that the total nitrogen content of the maleimide tetrapolymer is at least about 6.5% by weight of the polymer.
    • 通过单体马来酰亚胺,N-烷基马来酰亚胺,(甲基)甲基丙烯酸酯和(甲基)丙烯酸或(甲基)丙烯酸酯的自由基聚合制备的式I或II的碱性可溶性马来酰亚胺四元共聚物:其中R是具有I 至4个碳原子; 每个R 1,R 2和R 3分别选自氢或甲基; 每个m是马来酰亚胺的摩尔分数,其值为5〜20%,n为N-烷基马来酰亚胺的摩尔分数,为约50〜70%,各为x(甲基) )丙烯酸酯,并且具有约15 15至30%的值,y是(甲基)丙烯酸的摩尔分数,并且具有3至12%的值,z是(甲基)丙烯酰胺的摩尔分数,并且具有 约4至15%,其中式I中的m,n,x,y和式II中的m,n,x和z的值使得马来酰亚胺四元共聚物的总氮含量为至少约6.5重量% 的聚合物。