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    • 5. 发明授权
    • Phase change inks containing gelator additives
    • 相变油墨含有凝胶剂添加剂
    • US06872243B2
    • 2005-03-29
    • US10235125
    • 2002-09-04
    • Marcel P. BretonDanielle C. Boils-BoissierDonald R. TitteringtonJule W. Thomas, Jr.Jeffrey H. BanningChristine E. BedfordJames D. Wuest
    • Marcel P. BretonDanielle C. Boils-BoissierDonald R. TitteringtonJule W. Thomas, Jr.Jeffrey H. BanningChristine E. BedfordJames D. Wuest
    • C09D11/00
    • C09D11/34
    • Disclosed is a phase change ink composition comprising an ink vehicle, a colorant, and a nonpolymeric organic gelator selected from the group consisting of anthracene-based compounds, steroid compounds, partially fluorinated high molecular weight alkanes, high molecular weight alkanes with exactly one hetero atom, chiral tartrate compounds, chiral butenolide-based compounds, bis-urea compounds, guanines, barbiturates, oxamide compounds, ureidopyrimidone compounds, and mixtures thereof, said organic gelator being present in the ink in an amount of no more than about 20 percent by weight of the ink, said ink having a melting point at or below which the ink is a solid, said ink having a gel point at or above which the ink is a liquid, and said ink exhibiting a gel state between the melting point and the gel point, said ink exhibiting reversible transitions between the solid state and the gel state upon heating and cooling, said ink exhibiting reversible transitions between the gel state and the liquid state upon heating and cooling, said melting point being greater than about 35° C., said gel point being greater than said melting point. Also disclosed are imaging processes employing phase change inks containing gelator additives.
    • 公开了一种相变油墨组合物,其包含油墨载体,着色剂和非聚合有机胶凝剂,其选自蒽类化合物,类固醇化合物,部分氟化的高分子量烷烃,具有正好一个杂原子的高分子量烷烃 ,手性酒石酸盐化合物,手性丁烯内酯类化合物,双脲化合物,鸟嘌呤,巴比妥类,草酰胺化合物,脲基吡啶酮化合物及其混合物,所述有机凝胶剂存在于油墨中的量不超过约20重量% 的油墨,所述油墨的熔点在或以下,油墨是固体,所述油墨具有等于或高于其上的凝胶点,油墨是液体,并且所述油墨在熔点和凝胶之间呈凝胶状态 所述油墨在加热和冷却时呈现固体状态和凝胶状态之间的可逆转变,所述油墨在凝胶状态a 在加热和冷却时记录液体状态,所述熔点大于约35℃,所述凝胶点大于所述熔点。 还公开了使用含有凝胶剂添加剂的相变油墨的成像方法。
    • 8. 发明授权
    • Processes for preparing bis(urea-urethane) compounds
    • 制备双(脲 - 氨基甲酸酯)化合物的方法
    • US07576235B2
    • 2009-08-18
    • US11097758
    • 2005-04-01
    • Rina CarliniAdela GoredemaEniko TomaChristine E. Bedford
    • Rina CarliniAdela GoredemaEniko TomaChristine E. Bedford
    • C07C261/00C07C269/00
    • C07C273/1854C07C2601/14C07C275/26
    • Processes for preparing bis(urea-urethane) compounds wherein R1 is alkyl, aryl, arylalkyl, or alkylaryl, R2 is alkylene, arylene, arylalkylene, or alkylarylene, R3 is alkylene, arylene, arylalkylene, or alkylarylene, and R4 is hydrogen or alkyl, comprising: (1) first bring to a reaction temperature of about 20-125° C. a reaction mixture comprising monoalcohol reactant R1—OH and diisocyanate reactant OCN—R2—NCO, the monoalcohol being present in an amount of about 0.8-1.2 moles monoalcohol per mole diisocyanate, the monoalcohol and diisocyanate reactants being admixed in a solvent, the reactants and solvent being present in relative amounts of at least about 1 milliliter solvent per millimole diisocyanate, the reaction temperature continuing until reaction between the monoalcohol and the diisocyanate is complete; and (2) subsequent to step (1), adding to the reaction mixture diamine without isolating the reaction product of step (1), thereby forming compound of the formula in desirably high yield and purity.
    • 制备双(脲 - 氨基甲酸酯)化合物的方法,其中R 1是烷基,芳基,芳基烷基或烷基芳基,R 2是亚烷基,亚芳基,芳基亚烷基或烷基亚芳基,R 3是亚烷基,亚芳基,芳基亚烷基或烷基亚芳基,R 4是氢或烷基 包括:(1)首先使约20-125℃的反应温度,包含一元醇反应物R1-OH和二异氰酸酯反应物OCN-R2-NCO的反应混合物,一元醇的存在量为约0.8-1.2 摩尔一元醇/摩尔二异氰酸酯,一元醇和二异氰酸酯反应物在溶剂中混合,反应物和溶剂以至少约1毫升溶剂/毫摩尔二异氰酸酯的相对量存在,直到一元醇与二异氰酸酯反应的反应温度为 完成; 和(2)在步骤(1)之后,在不分离步骤(1)的反应产物的情况下向反应混合物二胺中加入,从而以期望的高产率和纯度形成式的化合物。