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    • 6. 发明授权
    • Method of growing nitride crystal of group III element
    • 生长III族元素氮化物晶体的方法
    • US06284042B1
    • 2001-09-04
    • US09605742
    • 2000-06-29
    • Chiaki Sasaoka
    • Chiaki Sasaoka
    • C30B2502
    • C30B25/02C23C16/303C30B29/403C30B29/406
    • A MOVPE method is provided that makes it possible to grow a high-quality nitride crystal of a group III element. The method comprises the steps (a) to (d). In the step (a), an organometallic compound in a gas phase is supplied to a reaction chamber as a group III component material by a carrier gas. In the step (b), a nitrogen compound in a gas phase is supplied to the chamber as a group V component material by the carrier gas. In the step (c), a hydrocarbon in a gas phase is supplied to the chamber by the carrier gas. In the step (d), the organometallic compound and the nitrogen compound are reacted with each other in a atmosphere containing the hydrocarbon in the chamber to grow a nitride crystal of a group III element on a crystalline substrate. As the hydrocarbon, any hydrocarbon containing at least one carbon-to-carbon (i.e., C—C) bond in its molecule (i.e., alkanes) may be used. Preferably, any hydrocarbon containing at least one double or triple carbon-to-carbon bond (i.e., C═C or C≡C) in its molecule (i.e., alkens or alkynes) is additionally supplied to the chamber. A step of supplying a p- or n-type dopant material to the chamber may be added, in which the nitride crystal exhibits the p- or n-type conductivity.
    • 提供了一种MOVPE方法,其可以生长III族元素的高质量氮化物晶体。 该方法包括步骤(a)至(d)。 在步骤(a)中,气相中的有机金属化合物作为III族组分材料通过载气供给到反应室。 在步骤(b)中,气相中的氮化合物作为V族组分材料通过载气供给到室。 在步骤(c)中,通过载气将气相中的烃供给室。 在步骤(d)中,有机金属化合物和氮化合物在室内含有烃的气氛中相互反应,以在晶体衬底上生长III族元素的氮化物晶体。 作为烃,可以使用在其分子中含有至少一个碳 - 碳(即C-C)键的任何烃(即烷烃)。 优选地,在其分子中含有至少一个双重或三重碳 - 碳键(即C = C或C = C)的烃(即,烯烃或炔烃)另外提供给该室。 可以添加向腔室供给p型或n型掺杂剂材料的步骤,其中氮化物晶体呈现p型或n型导电性。