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    • 4. 发明授权
    • Fire resistant styrene polymer foams with reduced brominated fire retardant
    • 耐火苯乙烯聚合物泡沫与减少溴化阻燃剂
    • US06579911B1
    • 2003-06-17
    • US09744005
    • 2001-06-04
    • Chau Van VoSylvie Boukami
    • Chau Van VoSylvie Boukami
    • C08J900
    • C08J9/0038C08J2205/052C08J2325/02C08K5/0066C08K5/01C08K5/523C08L25/02
    • Extruded, substantially closed-polystyrene foams that exhibit improved fire resistance yet contain lower levels of brominated fire retardant are disclosed. Methods of preparing the foams, comprising extruding the polystyrene with a novel fire retardant formulation comprising a mixture of a) a phosphate compound, preferably TPP; b) less than about 2.5 percent HBCD based on 100 percent polystyrene; and optionally c) a flow promoter such as dimethyldiphenylbutane, the extrusion process using a blowing agent which is preferably selected from carbon dioxide, mixtures of two or more of carbon dioxide, water, alcohol, ether and hydrocarbons, or a mixture of hydrofluorocarbons, alcohols, and hydrocarbons, are also disclosed. Use of the phosphate compound in the fire retardant formulation allows a reduction in the amount of brominated compound required and a reduction in the foaming temperature, resulting in lower density foams.
    • 公开了具有改进的耐火性但含有较低含量的溴化阻燃剂的挤出的基本封闭的聚苯乙烯泡沫。 制备泡沫的方法,包括用新的阻燃剂制品挤出聚苯乙烯,该阻燃剂包含a)磷酸酯化合物,优选TPP; b)基于100%聚苯乙烯小于约2.5%的六溴环十二烷; 和任选地c)流动促进剂如二甲基二苯基丁烷,使用优选选自二氧化碳的发泡剂的挤出方法,二氧化碳,水,醇,醚和烃中的两种或更多种的混合物,或氢氟烃,醇的混合物 ,和烃类。 在阻燃剂配方中使用磷酸盐化合物可以减少所需的溴化化合物的量和发泡温度的降低,导致较低密度的泡沫。