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    • 1. 发明申请
    • Process for catalytic deoxygenation of coal mine methane
    • 煤矿瓦斯催化脱氧工艺
    • US20120003132A1
    • 2012-01-05
    • US12737342
    • 2010-04-19
    • Shudong WangSheng WangZhongshan YuanChunxi ZhangChangjun NiDeyi Li
    • Shudong WangSheng WangZhongshan YuanChunxi ZhangChangjun NiDeyi Li
    • B01D53/46B01J29/068B01J21/16B01J23/63
    • B01J23/63B01J21/066B01J23/002B01J23/58B01J37/0242B01J2523/00C10L3/101B01J2523/3712B01J2523/48B01J2523/3737B01J2523/31
    • Deoxygenation catalyst for coal mine methane, its preparation method and application in catalytic deoxygenation of coal mine methane in oxygen-containing environment. The catalyst comprises a first composition serving as the active content and a second composition serving as the additive. The first composition consists of one or more platinum group noble metals selecting from the group consisting of Pd, Pt, Ru, Rh and Ir. The second composition consists of one or more alkaline metals or alkaline earth metals selected from the group consisting of Na2O, K2O, MgO, CaO, SrO and BaO; CeO2 and lanthanides rare earth metals such as Pr, Nd, Sm, Eu, Gd, etc.; and/or transition metals such as Y, Zr, La, etc.; and/or Al2O3 oxides complexes. Said catalyst can effectively eliminate the oscillatory behavior during catalytic combustion under oxyen-lean condition. When said catalyst is applied in the catalytic deoxygenation process of the present invention, 1 to 15% of oxygen in coal mine methane can be effectively removed and a percentage yield of methane which approximately equals to the theoretical percentage yield obtained under the assumption of complete conversion of methane and oxygen can be achieved.
    • 煤矿瓦斯脱氧催化剂及其在含氧环境中煤矿瓦斯催化脱氧的制备方法及应用。 催化剂包含作为活性成分的第一组合物和作为添加剂的第二组合物。 第一组合物由选自Pd,Pt,Ru,Rh和Ir的一种或多种铂族贵金属组成。 第二组合物由选自Na2O,K2O,MgO,CaO,SrO和BaO的一种或多种碱金属或碱土金属组成。 CeO2和镧系稀土金属如Pr,Nd,Sm,Eu,Gd等; 和/或过渡金属如Y,Zr,La等; 和/或Al 2 O 3氧化物络合物。 所述催化剂可以有效地消除贫氧条件下催化燃烧过程中的振荡行为。 当在本发明的催化脱氧方法中使用所述催化剂时,可以有效地除去煤矿甲烷中的1〜15%的氧气,甲烷的产率几乎等于在完全转化的情况下获得的理论百分比产率 的甲烷和氧气可以实现。