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1. 发明申请

WO1991019042A1 PROCESS FOR THE PREPARATION OF AN AQUEOUS SOLUTION OF SODIUM COMPOUNDS 审中-公开
标题翻译：用于制备钠化合物的水溶液的方法
公开(公告)号：WO1991019042A1
公开(公告)日：1991-12-12
申请号：PCT/SE1991000383
申请日：1991-05-31
申请人： CHEMREC AKTIEBOLAG , STIGSSON, Lars , BERNHARD, Nils
发明人： CHEMREC AKTIEBOLAG
IPC分类号： D21C11/12
CPC分类号： F28C3/06 , D21C11/063 , D21C11/066 , D21C11/122 , D21C11/125 , F28D2021/0075 , Y02P40/44 , Y10S423/03
摘要： The present invention relates to a process for the preparation of a solution of sodium compounds formed together with a gas containing carbon monoxide, carbon dioxide and hydrogen gas, at partial combustion of cellulose spent liquors, the gas with its content of sodium compounds being brought into contact with at least one dissolving liquid in a device consisting of a vessel, containing a solving liquid and a vertically arranged downcoming tube (3), the upper part of which being connected to a gas generator (1) and the lower part of which debouching below the resting surface (14) of the solving liquid, whereby the gas and sodium compounds pass down through the downcoming tube (3), into which tube a dissolving liquid is added, and then pass between the downcoming tube (3) and an upcoming tube (6), the upper end of which debouches above the resting surface (14) of the dissolving liquid, and the lower end of which debouches therebelow, and which upcoming tube (6) wholly or partly surrounds the downcoming tube (3), whereby gas, sodium compounds and dissolving liquid being carried with the gas are brought into contact, whereby the sodium compounds are separated off and are dissolved in the dissolving liquid, which is drafted for the preparation of a digestion liquid.

2. 发明申请

WO2007030078A2 METHOD FOR ARRANGING A CHEMICAL BARRIER IN A GASIFYING REACTOR FOR BLACK LIQUOR, A CHEMICAL GASIFYING REACTOR, A BARRIER LAYER OF A REACTOR AND A METHOD FOR MANUFACTURING A BUILDING BLOCK FOR SUCH A BARRIER LAYER 审中-公开
标题翻译：用于在黑液体气化反应器，化学气化反应器，反应器的障碍层中安装化学阻挡物的方法和用于制造用于这种隔离层的建筑物块的方法
公开(公告)号：WO2007030078A2
公开(公告)日：2007-03-15
申请号：PCT/SE2006/050316
申请日：2006-09-06
申请人： CHEMREC AKTIEBOLAG , TEGMAN, Ragnar
发明人： TEGMAN, Ragnar
IPC分类号： C04B35/10 , D21C11/12 , F27D1/00
CPC分类号： D21C11/122 , C04B35/113 , C04B35/44 , C04B35/443 , C04B35/657 , C04B35/66 , C04B2235/3201 , C04B2235/3206 , C04B2235/3208 , C04B2235/3218 , C04B2235/3222 , C04B2235/3241 , C04B2235/77 , C04B2235/80 , C04B2235/9669 , C10J3/74 , C10J2200/09 , F27D1/0006
摘要： A chemical reactor and a method for arranging a ceramic barrier in a gasifying reactor, which reactor is arranged to convert high energy organic waste of black liquor type with a large amount of organic or inorganic alkali metal compounds, by high temperature oxidation with air or oxygen, whereby the organic waste is converted to a hot reducing gas containing a considerable amount of water vapour and the inorganic compounds form an alkali-containing salt melt at a temperature of 750-1150 °C, and which reactor is arranged to comprise an outer shell (14) with associated inlet and outlet devices for reactants and products, the method comprising the arranging of a lining (16, 18) comprising one or more layers of ceramic barriers (16, 18) on the inside of the shell (14), the innermost ceramic barrier (16) of the reactor being composed of a lining material that primarily contains compounds of aluminium oxide (Al 2 O 3 ) and at least one of alkali metal oxides (Me2 (I) O) and alkaline earth metal oxides (Me (II) 0), forming compounds of the type Me2 (I) O Al2O3 and Me (II) 0- Al 2 O 3 .
摘要翻译：一种化学反应器和在气化反应器中布置陶瓷阻挡层的方法，该反应器被布置成通过用空气或氧气高温氧化将大量有机或无机碱金属化合物转化成黑液型高能有机废物，由此将有机废物转化为含有相当量水蒸气的热还原气体，并且无机化合物在750-1150℃的温度下形成含碱盐的熔体，并且该反应器设置成包含外壳（14），其具有用于反应物和产品的相关联的入口和出口装置，所述方法包括在壳体（14）的内侧上布置包括一层或多层陶瓷阻挡层（16,18）的衬里（16,18）反应器的最内层的陶瓷阻挡层（16）由主要包含氧化铝（Al 2 O 3 3）的化合物和碱金属的至少一种的衬里材料组成氧化物（Me2（I））（O）和碱土金属氧化物（Me（O）O）），形成Me 2（I）O Al 2 O 3和Me（II）的化合物）0-A1 2 O 3 3。

3. 发明申请

WO1994010085A1 PROCESS ASSOCIATED WITH THE GASIFICATION OF CELLULOSE SPENT LIQUORS 审中-公开
标题翻译：与生产纤维素气泡液相关的方法
公开(公告)号：WO1994010085A1
公开(公告)日：1994-05-11
申请号：PCT/SE1993000778
申请日：1993-09-29
申请人： CHEMREC AKTIEBOLAG , BACKLUNG, Åke , STIGSSON, Lars , WALLERGÅRD, Ove
发明人： CHEMREC AKTIEBOLAG
IPC分类号： C01B15/01
CPC分类号： D21C11/125 , C01B3/22 , C01B15/023
摘要： The present invention relates to a process for producing hydrogen peroxide, preferably intended for use in the bleaching of pulp, in which the hydrogen gas necessary for producing the hydrogen peroxide is generated wholly or partly by the gasification or partial combustion of cellulose spent liquors.
摘要翻译：本发明涉及一种优选用于漂白纸浆的过氧化氢的方法，其中生产过氧化氢所需的氢气全部或部分地由纤维素废液的气化或部分燃烧产生。

4. 发明申请

WO1994020677A1 A METHOD OF SEPARATING SULPHUR COMPOUNDS 审中-公开
标题翻译：一种分离硫化合物的方法
公开(公告)号：WO1994020677A1
公开(公告)日：1994-09-15
申请号：PCT/SE1994000184
申请日：1994-03-04
申请人： CHEMREC AKTIEBOLAG , STIGSSON, Lars
发明人： CHEMREC AKTIEBOLAG
IPC分类号： D21C11/12
CPC分类号： D21C11/0071 , B01D53/1462 , B01D53/52 , C01B17/167 , C01B17/168 , D21C11/06 , Y02P20/152 , Y02P70/24
摘要： A method of separating sulphur compounds out of a gas containing carbon dioxide and hydrogen sulphide, in a gas washing system, said gas being obtained by gasification of spent cellulose liquor. According to the invention the gas washing system has a gas-liquid contact zone (5) operating at a pressure exceeding atmospheric pressure as well as a regeneration zone (8) operating at a pressure substantially less than the pressure in the gas-liquid contact zone (5). The carbon dioxide partial pressure in the gas prior to entering the gas-liquid contact zone exceeds 0.2 atm. Furthermore the gas comes into contact with an alkaline absorption liquid in the gas-liquid contact zone, and alkaline liquid containing alkali hydrogen sulphide is withdrawn from the gas-liquid contact zone and transferred to the regeneration zone, in which zone hydrogen sulphide is expelled from said liquid containing alkali hydrogen sulphide and withdrawn in the form of a gas.
摘要翻译：一种在气体洗涤系统中从包含二氧化碳和硫化氢的气体中分离出硫化合物的方法，所述气体是通过将废纤维素液体气化获得的。根据本发明，气体清洗系统具有在超过大气压力的压力下操作的气液接触区（5）以及在基本上小于气液接触区中的压力的压力下操作的再生区（8）（5）。进入气液接触区之前气体中的二氧化碳分压超过0.2atm。此外，气体与气 - 液接触区中的碱性吸收液体接触，并且含有碱金属硫化氢的碱性液体从气 - 液接触区域中排出并转移到再生区，在该再生区中，硫化氢被排出所述液体含有碱金属硫化氢并以气体形式排出。

5. 发明申请

WO1994017240A1 METHOD FOR THE RECOVERY OF CELLULOSE SPENT LIQUORS 审中-公开
标题翻译：纤维素液体回收方法
公开(公告)号：WO1994017240A1
公开(公告)日：1994-08-04
申请号：PCT/SE1994000028
申请日：1994-01-18
申请人： CHEMREC AKTIEBOLAG , STIGSSON, Lars , BACKLUND, Åke
发明人： CHEMREC AKTIEBOLAG
IPC分类号： D21C11/12
CPC分类号： D21C11/125 , D21C11/04 , D21C11/063 , Y02P70/24
摘要： The present invention relates to a method for producing pulp cooked under alkaline conditions, in which method cellulose-containing material is brought into contact, in a digester, with an alkaline cooking liquor containing dissolved potassium and sodium compounds, with used spent cooking liquor being separated off from the cellulose-containing material and withdrawn for the recovery of energy and chemicals, wherein: a) the molar ratio, calculated as K/K + Na, between potassium and sodium in a withdrawn spent cooking liquor exceeds 0.25; b) the withdrawn spent cooking liquor is concentrated with respect to its content of solid material and is subjected to partial oxidation in a reactor, resulting in the formation of a combustible gas which is withdrawn from the reactor; c) oxygen-containing gas is supplied to the reactor in order to support the partial oxidation; d) the operating temperature in the reactor is adjusted to between 400-1200 DEG C; e) the combustible gas, which is obtained in association with the partial oxidation and which contains entrained solid and/or liquid alkali metal compounds, is separated from the major part of its content of alkali and used for the production of useful energy; f) the alkali metal compounds which have been separated off from the process gas are dissolved in liquid, which liquid is used either wholly or in part for preparing cooking liquor.
摘要翻译：本发明涉及一种生产在碱性条件下煮熟的纸浆的方法，其中使用含有溶解的钾和钠化合物的碱性蒸煮液在消化器中与含纤维素材料接触的方法，将分离出的废蒸煮液分离从所述含纤维素材料中取出并取出以回收能量和化学品，其中：a）在抽出的废蒸煮液中钾和钠之间的K / K + Na计算的摩尔比超过0.25; b）将取出的废蒸煮液相对于其固体物质的含量进行浓缩，并在反应器中进行部分氧化，形成从反应器中排出的可燃气体; c）向反应器供应含氧气体以支持部分氧化; d）将反应器中的操作温度调节至400-1200℃; e）与部分氧化相关并且含有夹带的固体和/或液体碱金属化合物获得的可燃气体与其碱的主要部分分离并用于生产有用能量; f）从工艺气体中分离的碱金属化合物溶于液体，该液体全部或部分用于制备蒸煮液。

6. 发明申请

WO1993012288A1 A METHOD OF PREPARING DIGESTING LIQUOR 审中-公开
标题翻译：一种制备消泡液的方法
公开(公告)号：WO1993012288A1
公开(公告)日：1993-06-24
申请号：PCT/SE1992000855
申请日：1992-12-11
申请人： CHEMREC AKTIEBOLAG , NILSSON, Bengt
发明人： CHEMREC AKTIEBOLAG
IPC分类号： D21C11/12
CPC分类号： D21C11/125 , D21C11/04 , Y02P40/44
摘要： A method of preparing digesting liquor having high sulphidity from a spent liquor obtained from digesting cellulosic fiber material, preferably without a conventional causticizing step is described, said method comprising thermal decomposition of the spent liquor under reducing conditions in a reactor at a pressure of from atmospheric pressure up to about 150 bar and at a temperature of about 500 to 1600 DEG C so that a combustible gas phase containing hydrogen sulphide is formed in the reactor and extracted therefrom, and a phase of solid or molten material comprising substantially sodium sulphide which is dissolved in aqueous liquid to produce said digesting liquor. According to the invention hydrogen sulphide is recovered from the gas phase and is returned to the reactor to be present during the thermal decomposition of the spent liquor.
摘要翻译：描述了从消耗纤维素纤维材料获得的废液中制备具有高硫化物的消化液的方法，优选不经常规苛化步骤，所述方法包括在还原条件下在反应器中在大气压力下热分解废液压力高达约150巴，温度为约500至1600℃，从而在反应器中形成含有硫化氢的可燃气相，并从其中提取，并将基本上溶解硫化钠的固体或熔融材料的相在水性液体中以产生所述消化液。根据本发明，从气相回收硫化氢，并且在废液的热分解期间将其返回到反应器中以存在。

7. 发明申请

WO1993002249A1 METHOD FOR RECOVERY OF CHEMICALS AND ENERGY FROM SPENT LIQUOR 审中-公开
标题翻译：化学品的回收方法和饮料中的能量的方法
公开(公告)号：WO1993002249A1
公开(公告)日：1993-02-04
申请号：PCT/SE1992000477
申请日：1992-06-29
申请人： CHEMREC AKTIEBOLAG , KIGNELL, Jan-Erik
发明人： CHEMREC AKTIEBOLAG
IPC分类号： D21C11/12
CPC分类号： D21C11/125 , D21C11/066 , Y02E20/12
摘要： The present invention relates to a process for the extraction of chemicals and energy from cellulose spent liquors, preferably black liquor obtained in the sulphate cellulose process, wherein the spent liquor is introduced into a gasification reactor (1) for pyrolysis and partial incineration, wherein an energy-rich gas is formed containing particles of inorganic chemical melt, the said gas mixture is conveyed out of the reactor (1) and concomitantly cooled by injection of a finely-divided cooling medium, preferably water, in connection with the departure from the reactor (1), the said mixture of gas and non-adhesive chemical particles is led from a cooling chamber (2) arranged in connection with the gasification reactor (1) to a separating arrangement (3), preferably a cyclone, where the non-adhesive chemical particles are separated from the gas, the gas stream, essentially cleaned of chemical particles, is taken out via an upper connection on the separating arrangement (3) while the chemical particles are taken out via a lower connection on the separating arrangement (3), wherein the melt particles leaving the reactor in the gas mixture are cooled to a temperature where they have at least partially solidified and been converted to solid phase, so that the particles included in the gas mixture are non-adhesive, and that a subsequent heat exchange of the separated gas is carried out from an essentially preserved temperature level.
摘要翻译：本发明涉及从纤维素废液中提取化学品和能量的方法，优选在硫酸纤维素方法中获得的黑液，其中将废液引入用于热解和部分焚化的气化反应器（1）中，其中形成含有无机化学熔体颗粒的能量丰富的气体，所述气体混合物从反应器（1）输送出来，并伴随着与离开反应器的注入相分离的冷却介质（优选为水）冷却介质（1）中，所述气体和非粘合剂化学颗粒的混合物从与气化反应器（1）连接的冷却室（2）引入分离装置（3），优选旋风分离器，粘合剂化学颗粒与气体分离，基本上清洁的化学颗粒的气流通过分离装置（3）上的上部连接被取出，而化学颗粒通过分离装置（3）上的较低连接件被取出，其中离开气体混合物中的反应器的熔体颗粒被冷却到其至少部分固化并被转化成固相的温度，使得包含在气体混合物中的颗粒是非粘合剂的，并且分离的气体的后续热交换从基本保持的温度水平进行。

8. 发明申请

WO1991019041A1 PROCESS FOR THE PARTIAL COMBUSTION OF CELLULOSE SPENT LIQUOR II 审中-公开
标题翻译：二，细胞培养液二部分燃烧过程
公开(公告)号：WO1991019041A1
公开(公告)日：1991-12-12
申请号：PCT/SE1991000346
申请日：1991-05-16
申请人： CHEMREC AKTIEBOLAG , STIGSSON, Lars
发明人： CHEMREC AKTIEBOLAG
IPC分类号： D21C11/12
CPC分类号： D21C11/125 , C10J3/506 , C10J2200/152 , C10J2300/1223 , F23D11/104 , F23D11/106
摘要： The present invention relates to a process for partial combustion of cellulose spent liquors using a burner equipped with a liquor lance and an atomizing nozzle, which burner is connected to a reactor operating at pressures in the range of 1.1 to 150 bars while supplying an oxygen containing gas, whereby the weight ratio between the oxygen containing gas supplied through the burner and the spent liquor solids supplied through the burner is less than 2:1, and that at least half of the non-fuel bound oxygen required for the partial combustion is discharged into the reactor through the atomizing nozzle.
摘要翻译：本发明涉及使用装备有液体喷枪和雾化喷嘴的燃烧器将纤维素废液部分燃烧的方法，该燃烧器连接到在1.1至150巴的压力下操作的反应器，同时提供含氧的气体，由此通过燃烧器供应的含氧气体与通过燃烧器供应的废液固体之间的重量比小于2:1，并且部分燃烧所需的非燃料结合氧的至少一半被排出通过雾化喷嘴进入反应器。

9. 发明申请

WO2004051167A1 DEVICE FOR THE GASIFICATION OR OXIDIZATION OF AN ENERGY CONTAINING FUEL 审中-公开
标题翻译：用于含燃料燃料的气化或氧化的装置
公开(公告)号：WO2004051167A1
公开(公告)日：2004-06-17
申请号：PCT/SE2003/001877
申请日：2003-12-04
申请人： CHEMREC AKTIEBOLAG , NILSSON, Bengt , ABDULLAH, Zia , GOROG, Peter, J.
发明人： NILSSON, Bengt , ABDULLAH, Zia , GOROG, Peter, J.
IPC分类号： F27D1/00
CPC分类号： C10J3/74 , C10J2300/1223 , F23M5/00
摘要： Device for the gasification or oxidizing of an energy containing fuel, which device comprises a reactor volume (10), which is provided with a burner (12), a reactor shell (14) and a ceramic lining (16, 18), an intermediate space (20, 42) being provided between said reactor shell and said ceramic lining. According to the invention, said intermediate space (20, 42) constitutes an expansion room which holds a thermal bridge member (22, 25, 30), which thermal bridge member has the ability to transfer thermal energy from the ceramic lining (16, 18) to the reactor shell (14) and the ability to absorb or counteract defined expansion forces from the ceramic lining, during a controlled temperature drop through the ceramic lining and the reactor shell.
摘要翻译：用于气化或氧化含能燃料的装置，该装置包括具有燃烧器（12），反应器壳体（14）和陶瓷衬里（16,18）的反应器容积（10），中间体空间（20,42）设置在所述反应器壳体和所述陶瓷衬垫之间。根据本发明，所述中间空间（20,42）构成保持热桥构件（22,25,30）的膨胀室，该热桥构件具有从陶瓷衬里（16,18）传递热能的能力）到反应器壳体（14）以及在通过陶瓷衬里和反应器壳体的受控温度下降期间吸收或抵消来自陶瓷衬里的限定的膨胀力的能力。

10. 发明申请

WO1993024703A1 A PROCESS FOR RECOVERING ENERGY FROM A COMBUSTIBLE GAS 审中-公开
标题翻译：从可燃气体回收能源的过程
公开(公告)号：WO1993024703A1
公开(公告)日：1993-12-09
申请号：PCT/SE1992000363
申请日：1992-05-29
申请人： CHEMREC AKTIEBOLAG , STIGSSON, Lars
发明人： CHEMREC AKTIEBOLAG
IPC分类号： D21C11/12
CPC分类号： D21C11/12 , D21C11/125 , F01K21/047 , F01K23/067 , F02C1/04 , F02C3/28 , Y02E20/16 , Y02E20/18 , Y02P70/24
摘要： A process for recovering energy from a combustible gas generated by partial oxidation of cellulose waste liquor in a gas generator (A) operating in a temperature range of 600-1300 DEG C and a pressure in the range of 1-100 bar, cooling and cleaning said combustible gas and using the gas as fuel in a recuperated gas turbine cycle (C, E), wherein water and/or steam is injected to humidify compressed air and/or combustible gas, increasing turbine motive fluid massflow and power output.
摘要翻译：从在600-1300℃的温度范围和1-100巴的压力范围内运行的气体发生器（A）中的纤维素废液的部分氧化产生的可燃气体中回收能量的方法，冷却和清洗所述可燃气体并且在再生燃气轮机循环（C，E）中使用气体作为燃料，其中注入水和/或蒸汽以加湿压缩空气和/或可燃气体，增加涡轮机动力流体质量流量和功率输出。

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