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1. 发明申请

WO1998028338A1 METHOD FOR THE EPOXIDATION OF UNSATURATED POLYMERS 审中-公开
标题翻译：环氧化不饱和聚合物的方法
公开(公告)号：WO1998028338A1
公开(公告)日：1998-07-02
申请号：PCT/EP1997007284
申请日：1997-12-22
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , CESKA, Gary, W. , FAN, Mingxin , HORGAN, James
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
IPC分类号： C08C19/06
CPC分类号： C08C19/06
摘要： A process for epoxidizing unsaturated polymers comprising reacting an unsaturated polymer with hydrogen peroxide in the presence of (a) tungstic acid or a metal salt thereof or molybdic acid or a molybdenum oxide, (b) phosphoric acid or a metal salt, and (c) at least one phase transfer catalyst.
摘要翻译：一种使不饱和聚合物环氧化的方法，包括在（a）钨酸或其金属盐或钼酸或氧化钼存在下使不饱和聚合物与过氧化氢反应，（b）磷酸或金属盐，和（c）至少一种相转移催化剂。

2. 发明申请

WO1990008166A1 THERMOPLASTIC ELASTOMER COMPOSED OF MACROMOLECULAR MONOMERS AND ALKOXYALKYL ACRYLATE MONOMERS 审中-公开
标题翻译：大分子单体和烷基丙烯酸酯单体组成的热塑性弹性体
公开(公告)号：WO1990008166A1
公开(公告)日：1990-07-26
申请号：PCT/US1990000206
申请日：1990-01-17
申请人： CESKA, Gary, W. , COSTIN, C., Richard , HAZELL, Thomas, W. , LECLERC, Robert, G.
IPC分类号： C08F257/02
CPC分类号： C08F290/044 , C08F8/00 , C08F12/00
摘要： Thermoplastic elastomers made by copolymerizing macromolecular monomers with alkoxyalkyl acrylates serve as binders for solid propellants which binders have high burn rates and increased insensitivity over conventional binders. The preferred alkoxyalkyl acrylate is methoxyethyl acrylate.

3. 发明申请

WO1998028307A1 FREE RADICALLY POLYMERIZABLE SILANE MONOMERS AND OLIGOMERS AND THE METHOD FOR MAKING THEM 审中-公开
标题翻译：自由可聚合的硅烷单体和低聚物及其制备方法
公开(公告)号：WO1998028307A1
公开(公告)日：1998-07-02
申请号：PCT/EP1997007285
申请日：1997-12-22
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , CESKA, Gary, W. , FAN, Mingxin , HORGAN, James
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
IPC分类号： C07F07/18
CPC分类号： C07F7/1896 , C07F7/081 , C07F7/1804
摘要： Compounds of formula (I), wherein R is H or CH3; n is 1 to 6; A is a bivalent to heptavalent linking group; X is O, S, NH; R is H or a C1-C20 organic group; R is a divalent linking group; and each of Y Y Y , which may be the same or different, represents alkoxyl, carboxy, alkoxy ether, alkyl, aryl. A process of making compounds of formula (I) comprises reacting a multifunctional (meth)acrylate of formula (II), with a silane of formula (III). Compounds (I) are shown to be useful as coupling agents or adhesion promotors in free radically, radiation curable compositions where the odor of allyl methacrylate is undesirable. The associated methods, curable compositions, coatings, adhesives and coated articles are also disclosed.
摘要翻译：式（I）化合物，其中R 1是H或CH 3; n为1至6; A是二价至七价连接基团; X是O，S，NH; R 2是H或C 1 -C 20有机基团; R 3是二价连接基团; Y Y Y Y 3中的每一个可以相同或不同，表示烷氧基，羧基，烷氧基醚，烷基，芳基。制备式（I）化合物的方法包括使式（II）的多官能（甲基）丙烯酸酯与式（III）的硅烷反应。化合物（I）被证明可用作自由基可辐射固化组合物中的偶联剂或粘合促进剂，其中甲基丙烯酸烯丙酯的气味是不期望的。还公开了相关方法，可固化组合物，涂料，粘合剂和涂覆制品。

4. 发明申请

WO2004081132A1 REVERSIBLY CROSSLINKED RESIN COMPOSITIONS AND METHODS 审中-公开
标题翻译：反向交联树脂组合物和方法
公开(公告)号：WO2004081132A1
公开(公告)日：2004-09-23
申请号：PCT/IB2004/050243
申请日：2004-03-12
申请人： SARTOMER TECHNOLOGY CO., INC. , CRAY VALLEY S.A. , BAILEY, Michael, A. , COSTIN, Richard, C. , CESKA, Gary, W.
发明人： BAILEY, Michael, A. , COSTIN, Richard, C. , CESKA, Gary, W.
IPC分类号： C09J4/00
CPC分类号： C09J133/08 , C08F230/04 , C09J7/38 , C09J7/385 , C09J133/10 , C09J2201/606 , Y10T428/31525
摘要： The present invention relates to a resin composition which exhibits reversible crosslinking behavior prepared by copolymerizing an alpha-beta ethylenically unsaturated monomer with an oil soluble metal salt prepared by reacting (A) a metal compound with (B) an acid functional compound which is a reaction product of a reactive mixture comprising (1) an alphabeta ethylenically unsaturated hydroxy compound and (2) a carboxylic polyacid or anhydride, sulfur oxide, or phosphorus oxide. The invention does also concern a process of heating the resin so as to cause reversible crosslinking.
摘要翻译：本发明涉及一种树脂组合物，其具有通过使α-β-烯键式不饱和单体与（A）金属化合物与（B）作为反应的酸官能化合物反应制备的油溶性金属盐共聚制备的可逆交联性能反应性混合物的产物，其包含（1）字母表烯键不饱和羟基化合物和（2）羧酸多酸或酸酐，硫氧化物或氧化磷。本发明还涉及加热树脂以引起可逆交联的方法。

5. 发明申请

WO1998028308A1 SILICON-CONTAINING ALKOXYLATED (METH)ACRYLATE MONOMERS 审中-公开
标题翻译：含硅烷氧基（甲基）丙烯酸酯单体
公开(公告)号：WO1998028308A1
公开(公告)日：1998-07-02
申请号：PCT/EP1997007287
申请日：1997-12-22
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , FAN, Mingxin , CESKA, Gary, W. , HORGAN, James , HAZELL, Thomas, W.
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
IPC分类号： C07F07/18
CPC分类号： C08F30/08 , C07F7/081 , C07F7/12 , C07F7/1804 , C09D4/00 , Y10T428/31663 , C08F230/08
摘要： Compounds of formula (I), wherein R = H, -CH3; each of the Y, which may be the same or different when n is higher than 1, represents an alkylene oxide unit of formula (Ia) or (Ib), wherein R is H, -CH3, -CH2CH3 or -CH2CH2CH3; n = 1-10; X = halogen, (C1-C6) alkyl, (C1-C6) alkoxy, or aromatic radical, wherein each of the three X substituents can be the same or different, are shown to be useful as coupling agents or adhesion promotors in free radically curable compositions such as radiation (UV or EB) curable and/or peroxide curable (meth)acrylate-based coating compositions. The associated methods, curable compositions, coatings, adhesives and coated articles are also disclosed.
摘要翻译：式（I）化合物，其中R 1 = H，-CH 3; 当n高于1时，每个Y可以相同或不同，表示式（Ia）或（Ib）的烯化氧单元，其中R 2是H，-CH 3，-CH 2 CH 3或-CH 2 CH 2 CH 3 ; n = 1-10; X =卤素，（C 1 -C 6）烷基，（C 1 -C 6）烷氧基或芳族基团，其中三个X取代基中的每一个可以相同或不同，被证明可用作自由基中的偶联剂或粘附促进剂可固化组合物如辐射（UV或EB）可固化和/或过氧化物可固化（甲基）丙烯酸酯基涂料组合物。还公开了相关方法，可固化组合物，涂料，粘合剂和涂覆制品。

6. 发明申请

WO1998028287A1 ALKOXYLATED GLYCIDYL (METH)ACRYLATES AND METHOD OF PREPARATION 审中-公开
标题翻译：烷基甘氨酸（甲基）丙烯酸酯及其制备方法
公开(公告)号：WO1998028287A1
公开(公告)日：1998-07-02
申请号：PCT/EP1997007283
申请日：1997-12-22
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , FAN, Mingxin , CESKA, Gary, W. , HORGAN, James , HAZELL, Thomas, W.
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
IPC分类号： C07D303/16
CPC分类号： C08G65/14 , C07D303/16 , C08F20/32 , C08L71/02 , C08L2666/04
摘要： The present invention relates to compounds of formula (I) (R = H, CH3; each of the Y, which may be the same or different when x is higher than 1, represents an alkylene oxide unit of formula (a) or (b), wherein R is hydrogen or (C1-C6) alkyl; and x = 1-20, with the proviso that x is higher than 10 when all the alkylene oxide units Y are ethylene oxide units); and to a process for preparing compounds (I) which comprises reacting an alkoxylated allyl acrylate or methacrylate of formula (II) wherein R ans Y are as defined above and x = 1-20, with hydrogen peroxide in the presence of (a) tungstic acid or a metal salt thereof or molybdic acid or a molybdenum oxide; (b) phosphoric acid or a metal salt thereof; and (c) at least one phase transfer catalyst.
摘要翻译：本发明涉及式（I）化合物（R 1 = H，CH 3;当x高于1时Y可各自相同或不同，表示式（a）的烯化氧单元）或（b），其中R 2为氢或（C 1 -C 6）烷基; x = 1-20，条件是当所有环氧烷单元Y为环氧乙烷单元时x高于10）; 以及制备化合物（I）的方法，其包括使式（II）的烷氧基化烯丙基丙烯酸酯或甲基丙烯酸酯（其中R 1和Y如上定义）和x = 1-20与过氧化氢在（ a）钨酸或其金属盐或钼酸或氧化钼; （b）磷酸或其金属盐; 和（c）至少一种相转移催化剂。

7. 发明申请

WO1998028286A2 UNSATURATED (METH)ACRYLATE ESTERS CONTAINING EPOXIDIZED CYCLIC GROUPS AND PROCESS FOR PREPARING 审中-公开
标题翻译：含有环氧化环状团的不饱和（METH）丙烯酸酯和制备方法
公开(公告)号：WO1998028286A2
公开(公告)日：1998-07-02
申请号：PCT/EP1997007286
申请日：1997-12-22
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , CESKA, Gary, W. , FAN, Mingxin , HORGAN, James
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
IPC分类号： C07D303/00
CPC分类号： C07D303/40 , C07D301/12 , C07D303/16 , C07D303/24 , C08G59/24
摘要： A process of making compounds of formula (I), wherein Z is an unsubstituted or substituted n-valent cyclic moiety bearing at least one endocyclic oxirane group; Y is O, S, NH, (Ia) or (Ib); R is a divalent linking group; X is O, S or NH; R is H or (C1-C6) alkyl; and n is an integer from 1 to 6, Z being mono- to hexavalent respectively, it being possible for -Y-R to represent a single bond, comprises reacting a compound of formula (II), wherein Z is a cyclic moiety bearing at least one endocyclic C=C group; and Y, R , X, R and n are as defined above with hydrogen peroxide in the presence of (a) tungstic acid or tungsten oxide or molybdic acid or a molybdenum oxide; (b) phosphoric acid or a salt thereof; and (c) at least one phase transfer catalyst.
摘要翻译：制备式（I）化合物的方法，其中Z是具有至少一个环内环氧基团的未取代或取代的n价环状部分; Y是O，S，NH，（Ia）或（Ib）; R 2是二价连接基团; X是O，S或NH; R 1是H或（C 1 -C 6）烷基; n为1〜6的整数，Z分别为1〜6价，-YR 2可以表示单键，包括使式（II）化合物（其中Z 1为具有至少一个环内C = C基团的环状部分; 在（a）钨酸或钨氧化物或钼酸或氧化钼的存在下，Y，R 2，X，R 1和n如上定义，与过氧化氢反应; （b）磷酸或其盐; 和（c）至少一种相转移催化剂。

8. 发明申请

WO2005068506A1 POLY(ETHYLENE-BUTYLENE) (METH)ACRYLATES AND RELATED COMPOSITIONS 审中-公开
标题翻译：聚（乙烯 - 丁烯）（甲基）丙烯酸酯和相关组合物
公开(公告)号：WO2005068506A1
公开(公告)日：2005-07-28
申请号：PCT/EP2005/000160
申请日：2005-01-11
申请人： SARTOMER TECHNOLOGY Co., inc. , CRAY VALLEY SA , FAN, Mingxin , KLANG, Jeffrey, A. , CESKA, Gary, W. , HORGAN, James, P.
发明人： FAN, Mingxin , KLANG, Jeffrey, A. , CESKA, Gary, W. , HORGAN, James, P.
IPC分类号： C08C19/00
CPC分类号： C08C19/38 , B33Y70/00 , C08G18/69 , C08L15/00 , C08L19/006
摘要： A polymer and a composition comprising the said polymer, which is a (meth)acrylated polymer resulting from alkoxylated derivatives of hydrogenated hydroxyl-terminated polybutadienes, with an average degree of alkoxylation n per reactive hydroxyl group, ranging from about 1 to 100 and a number of (meth)acrylic ester groups per molecule from about 1 to 15, more particularly a polymer according to Structure 1 wherein R is H, Me, Et or C 6 H 5 ; R' is H or Me ; n is a number from 1 to 100 ; and Z is a number from 1 to 3 ; f is a number from 1 to 5, with f = 1 if B is nothing ; A is residue of a hydrogenated polybutadiene backbone ; B is nothing or it is a difunctional organic linking group as disclosed. The composition can be cured and used in a wide range of articles such as a photopolymer printing plate, sealant, caulk, encapsulent, road marking paint, photoresist, binder, impact modifier, polymer modifier, oxygen or water vapor barrier coating, conformal coating, solder mask, pigment dispersion, stereolithography, laminating resin, grafted copolymer, composite, optical fiber coating, paper coating, metal coating, glass coating, plastic coating, wood coating, waterproofing material, electrical insulating material, automotive belt or hose, tire, engine mount, gasket, golf ball core, and rubber roll.
摘要翻译：聚合物和组合物，其包含所述聚合物，其是由氢化羟基封端的聚丁二烯的烷氧基化衍生物得到的（甲基）丙烯酸酯化的聚合物，每个反应性羟基的平均烷氧基化度n为约1至100，数量为的（甲基）丙烯酸酯基团，每分子约1至15个，更特别是根据结构1的聚合物，其中R是H，Me，Et或C 6 H 5; R'是H或Me; n是从1到100的数字; Z为1〜3的数; f是从1到5的数字，如果B没有，f = 1; A是氢化聚丁二烯骨架的残基; B是没有的，或者是如所公开的双官能有机连接基团。该组合物可以固化并用于宽范围的制品如光聚合物印刷版，密封剂，填隙料，包封剂，道路标线漆，光致抗蚀剂，粘合剂，抗冲改性剂，聚合物改性剂，氧气或水蒸气阻隔涂料，保形涂层，焊料掩模，颜料分散体，立体光刻，层压树脂，接枝共聚物，复合材料，光纤涂层，纸涂层，金属涂层，玻璃涂层，塑料涂层，木器涂料，防水材料，电绝缘材料，汽车皮带或软管，轮胎，发动机安装，垫圈，高尔夫球芯和橡胶辊。

9. 发明申请

WO2005023887A1 POLYBUTADIENE (METH)ACRYLATE COMPOSITION AND METHOD 审中-公开
标题翻译：聚丙烯（甲基）丙烯酸酯组合物和方法
公开(公告)号：WO2005023887A1
公开(公告)日：2005-03-17
申请号：PCT/IB2004/051726
申请日：2004-09-09
申请人： SARTOMER TECHNOLOGY CO., Inc. , CRAY VALLEY S.A. , CESKA, Gary W. , HORGAN, James P. , KLANG, Jeffrey A. , HE, Yuhong
发明人： CESKA, Gary W. , HORGAN, James P. , KLANG, Jeffrey A. , HE, Yuhong
IPC分类号： C08F290/04
CPC分类号： C08C19/38 , B33Y70/00 , C08L15/00 , C08L19/006 , Y10S430/106 , Y10S430/111
摘要： A composition comprising a polymer according to Structure (1), wherein R is H, Me, Et or C6H5 ; R' is H or Me ; n is an integer from 1 to 100 ; and Z is from 1 to 3 is disclosed. The composition can be cured and used in a wide range of articles such as a photopolymer printing plate, sealant, caulk, encapsulent, road marking paint, photoresist, binder, impact modifier, polymer modifier, oxygen or water vapor barrier coating, conformal coating, solder mask, pigment dispersion, stereolithography, laminating resin, grafted co -polymer, composite, optical fiber coating, paper coating, metal coating, glass coating, plastic coating, wood coating, waterproofing material, electrical insulating material, automotive belt or hose, tire, engine mount, gasket, golf ball core, and rubber roll.
摘要翻译：一种组合物，其包含根据结构（1）的聚合物，其中R为H，Me，Et或C 6 H 5; R'是H或Me; n为1〜100的整数， Z为1〜3。该组合物可以固化并用于宽范围的制品中，例如光聚合物印刷版，密封剂，填缝剂，密封剂，道路标线漆，光致抗蚀剂，粘合剂，抗冲改性剂，聚合物改性剂，氧气或水蒸气阻隔涂料，保形涂层，焊料掩模，颜料分散体，立体光刻，层压树脂，接枝共聚物，复合材料，光纤涂层，纸张涂层，金属涂层，玻璃涂层，塑料涂层，木器涂料，防水材料，电绝缘材料，汽车皮带或软管，轮胎发动机支架，垫片，高尔夫球芯和橡胶辊。

10. 发明申请

WO9828286A3 UNSATURATED (METH)ACRYLATE ESTERS CONTAINING EPOXIDIZED CYCLIC GROUP AND PROCESS FOR PREPARING THEM 审中-公开
标题翻译：含有环氧化环状基团的不饱和（甲基）丙烯酸酯及其制备方法
公开(公告)号：WO9828286A3
公开(公告)日：1998-08-13
申请号：PCT/EP9707286
申请日：1997-12-22
申请人： SARTOMER CO INC , CRAY VALLEY SA , CESKA GARY W , FAN MINGXIN , HORGAN JAMES
发明人： CESKA GARY W , FAN MINGXIN , HORGAN JAMES
IPC分类号： B01J31/24 , B01J31/34 , C07D301/12 , C07D303/16 , C07D303/24 , C07D303/40 , C08F20/32 , C08G59/24
CPC分类号： C07D303/40 , C07D301/12 , C07D303/16 , C07D303/24 , C08G59/24
摘要： Process of making compounds of the formula wherein R1=(C1-C6) alkyl; X=O, S, NH; R2=divalent saturated organic group; Y=O, S, NH, ester; R3=cyclic moiety containing oxirane group; comprising reacting a compound of the formula wherein R4 is a cyclic moiety containing C=C group with hydrogen peroxide in the presence of (a) tungstic acid, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst; polymers of compounds of formula I; and compounds of formula I except for compounds wherein R4 is a dicyclopentenyl epoxide, Y is O, R2 is -CH2CH2-, X is O, and R1 is H or methyl.
摘要翻译：制备下式化合物的方法其中R1 =（C1-C6）烷基; X = O，S，NH; R2 =二价饱和有机基团; Y = O，S，NH，酯; R3 =含环氧乙烷基团的环状部分; 包括在（a）钨酸，（b）磷酸或其金属盐存在下使下式化合物其中R 4是含有C = C基团的环状部分与过氧化氢反应，和（c）至少一种相转移催化剂; 式I化合物的聚合物; 和式I化合物，除了其中R 4是二环戊烯基环氧化物，Y是O，R 2是-CH 2 CH 2 - ，X是O，且R 1是H或甲基的化合物。

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