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1. 发明授权

US09309125B2 Process and system for generating synthesis gas 有权
标题翻译：生成合成气的工艺和系统
公开(公告)号：US09309125B2
公开(公告)日：2016-04-12
申请号：US14129134
申请日：2012-12-20
申请人： CCP TECHNOLOGY GMBH
发明人： Olaf Kuhl
IPC分类号： C01B3/24 , C01B31/18 , C10J3/00 , C10K3/06 , C10G2/00 , C01B31/02 , B01J19/12 , C07C1/04 , B01J19/24
CPC分类号： B01J19/0013 , B01J19/126 , B01J19/245 , B01J2219/00051 , B01J2219/0898 , B01J2219/1206 , B01J2219/24 , C01B3/24 , C01B32/05 , C01B32/40 , C01B2203/0255 , C01B2203/0272 , C01B2203/062 , C01B2203/0833 , C01B2203/0861 , C01B2203/1235 , C07C1/041 , C07C1/0485 , C10G2/32 , C10G2/34 , C10G2400/04 , C10G2400/08 , C10J3/00 , C10J2300/094 , C10J2300/0943 , C10J2300/0973 , C10J2300/1659 , C10J2300/1884 , C10K3/06
摘要： A method and an apparatus for generating synthesis gas using hydrocarbons and water are described. In further embodiments of the method and the apparatus, synthesis gases having any desired CO/hydrogen ratio and/or synthetic functionalized and/or non-functionalized hydrocarbons are generated. With this method, a hydrocarbon containing fluid may be transformed into a synthesis gas having variable hydrogen content without generating significant amounts of CO2. Further, hydrogen and different forms of carbon may be obtained as by-products.
摘要翻译：描述了使用烃和水产生合成气的方法和装置。在该方法和装置的其它实施方案中，产生具有任何所需CO /氢比的合成气和/或合成官能化和/或非官能化烃。通过这种方法，可以将含烃流体转化为具有可变氢含量的合成气，而不产生显着量的CO 2。此外，作为副产物可以获得氢气和不同形式的碳。

2. 发明专利

TW201529859A 用於處理金屬礦石的方法以及用於金屬生產的高爐审中-公开
简体标题：用于处理金属矿石的方法以及用于金属生产的高炉
公开(公告)号：TW201529859A
公开(公告)日：2015-08-01
申请号：TW103141164
申请日：2014-11-27
申请人： CCP技術有限公司 , CCP TECHNOLOGY GMBH
发明人：庫爾歐拉芙 , KUEHL, OLAF
IPC分类号： C21B5/00 , C21B5/06 , C21B7/00
CPC分类号： C21B5/06 , B01D53/62 , B01D53/84 , B01D53/8671 , B01D53/90 , B01D2251/20 , B01D2257/502 , B01D2257/504 , B01D2258/025 , C12M21/12 , C12M41/20 , C12M43/04 , C12M47/20 , C12P7/06 , C12P7/08 , C21B5/003 , C21B5/004 , C21B7/002 , C21B2005/005 , C21B2100/02 , C21B2100/22 , C21B2100/24 , C21B2100/282 , H01M8/0612 , H01M8/22 , H01M2250/10 , Y02A50/2358 , Y02B90/14 , Y02C10/02 , Y02C10/04 , Y02E50/17 , Y02P10/122 , Y02P10/128 , Y02P10/265 , Y02P10/283 , Y02P20/152 , Y02P20/59 , Y02P70/56
摘要：本發明描述一種用於處理金屬礦石的製程，其包括以下步驟：在高爐爐身中還原金屬礦石，特定而言為金屬氧化物；在高爐爐身中產生含有CO2的爐氣；自高爐爐身排放爐氣；將爐氣的至少一部分直接或間接地引導至CO2轉換器中；以及在存在化學計量過量的C的情況下，在CO2轉換器中將含於爐氣中的CO2轉換成由載氣及C粒子組成的氣溶膠；將來自CO2轉換器的氣溶膠的至少第一部分引導至高爐爐身中；以及將H2O引入至高爐爐身中。藉助於反應C+H2O→CO2+2H，在高爐中產生引起金屬礦石的快速還原的初生氫。金屬礦石的還原速度因此增加，且有可能增加高爐的輸送容量或減小高爐的大小。呈流體形式的氣溶膠可易於引入至高爐爐身中。
简体摘要：本发明描述一种用于处理金属矿石的制程，其包括以下步骤：在高炉炉身中还原金属矿石，特定而言为金属氧化物；在高炉炉身中产生含有CO2的炉气；自高炉炉身排放炉气；将炉气的至少一部分直接或间接地引导至CO2转换器中；以及在存在化学计量过量的C的情况下，在CO2转换器中将含于炉气中的CO2转换成由载气及C粒子组成的气溶胶；将来自CO2转换器的气溶胶的至少第一部分引导至高炉炉身中；以及将H2O引入至高炉炉身中。借助于反应C+H2O→CO2+2H，在高炉中产生引起金属矿石的快速还原的初生氢。金属矿石的还原速度因此增加，且有可能增加高炉的输送容量或减小高炉的大小。呈流体形式的气溶胶可易于引入至高炉炉身中。

3. 发明申请

US20180327260A1 APPARATUS AND PROCESS FOR PRODUCTION OF SYNTHESIS GAS 审中-公开
公开(公告)号：US20180327260A1
公开(公告)日：2018-11-15
申请号：US15770224
申请日：2016-10-26
申请人： CCP TECHNOLOGY GMBH
发明人： Olaf Kuhl
IPC分类号： C01B3/24 , B01J19/08
CPC分类号： C01B3/24 , B01J19/088 , B01J2219/0898 , C01B3/342 , C01B2203/0216 , C01B2203/0222 , C01B2203/0272 , C01B2203/085 , C01B2203/0861 , C01B2203/1241 , C01B2203/1614 , C01B2203/1619 , C01B2203/1628 , C01B2203/1633 , C01B2203/1676 , C01B2203/169
摘要： An apparatus for producing synthesis gas at high capacity is described, wherein particularly fast conversion and operation for a long time without interruption is obtained. The apparatus comprises a reactor (1) having a reactor chamber (2) which comprises at least one first inlet (5) connected to a source of hydrocarbon fluid and at least one outlet (15); further a plasma burner (7) having a burner part (11) which is adapted to produce a plasma; and at least one second inlet (6) connected to a source of CO2 or H2O. The reactor chamber (2) defines a flow path from the first inlet (5) to the outlet (15), wherein the burner part is located, with respect to the flow path, between the first inlet (5) for hydrocarbon fluid and the second inlet (6) for CO2 or H2O; and wherein the second inlet (6) is located with respect to the flow path such that the second inlet (6) is at a location where between 90% and 95% of the hydrocarbon fluid is thermally decomposed. Further a method for operating an apparatus for producing synthesis gas is described.

4. 发明申请

US20170057818A1 METHOD AND APPARATUS FOR PRODUCING H2-RICH SYNTHESIS GAS 有权
标题翻译：用于生产氢气合成气的方法和装置
公开(公告)号：US20170057818A1
公开(公告)日：2017-03-02
申请号：US15307898
申请日：2015-05-13
申请人： CCP Technology GmbH
发明人： Olaf Kuhl
IPC分类号： C01B3/24 , C01B3/12 , C10K3/04 , C10G2/00
CPC分类号： C01B3/24 , C01B3/12 , C01B2203/0272 , C01B2203/0283 , C01B2203/0288 , C01B2203/049 , C01B2203/061 , C01B2203/062 , C01B2203/0805 , C01B2203/0844 , C01B2203/0861 , C01B2203/0883 , C01B2203/1276 , C01B2203/141 , C01B2203/145 , C10G2/30 , C10G2/32 , C10G2/34 , C10J2300/1618 , C10J2300/1853 , C10K3/04 , Y02P20/129
摘要： A method for producing ¾-rich synthesis gas comprises the following steps: decomposing a hydrocarbon-containing fluid into an H2/C-aerosol in a first hydrocarbon converter by supplying energy which is at least partly provided in the form of heat; introducing at least a first stream of the H2/C-aerosol into a first sub-process which comprises the following steps: directing at least a part of the H2/C-aerosol from the first hydrocarbon converter into a first C-converter; introducing CO2 into the first C-converter and mixing the CO2 with the H2/C-aerosol introduced into the first C-converter; converting the mixture of H2/C-aerosol and CO2 into a synthesis gas at a temperature of 800 to 1700° C.; mixing additional H2 with the synthesis gas for the production of H2-rich synthesis gas. In a second sub-process running in parallel with the first sub-process, hydrogen H2 and carbon dioxide CO2 are produced from a hydrocarbon-containing fluid, wherein at least a portion of the CO2 produced in the second sub-process is introduced into the first C-converter; and wherein at least a portion of the H2 produced in the second sub-process is mixed with the synthesis gas from the first C-converter. The CO2 which is needed for the conversion of C in the first C-converter can thereby be provided independently of an external source, and the entire operational sequence is easily controllable.
摘要翻译：一种生产富氘合成气的方法包括以下步骤：通过提供至少部分以热的形式提供的能量将烃类流体分解成第一烃转化器中的H 2 / C-气溶胶; 将至少第一流的H2 / C-气溶胶引入到第一子过程中，其包括以下步骤：将来自第一烃转化器的H 2 / C-气溶胶的至少一部分引导到第一C转换器中; 将CO 2引入到第一C转化器中并将CO 2与引入到第一C转换器中的H 2 / C气溶胶混合; 将H 2 / C气溶胶和CO 2的混合物在800至1700℃的温度下转化为合成气; 将额外的H2与合成气混合，用于生产富H2合成气。在与第一子方法并行运行的第二子方法中，氢气H2和二氧化碳CO 2由含烃流体产生，其中在第二子方法中产生的CO 2的至少一部分被引入第一个C转换器; 并且其中在所述第二子过程中产生的所述H 2的至少一部分与来自所述第一C转换器的合成气混合。因此，可以独立于外部源来提供在第一C转换器中转换C所需的CO 2，并且整个操作顺序容易控制。

5. 发明申请

WO2017186482A1 VERFAHREN UND VORRICHTUNG ZUR HERSTELLUNG VON SYNTHESEGAS 审中-公开
标题翻译：制备合成酶的方法和装置
公开(公告)号：WO2017186482A1
公开(公告)日：2017-11-02
申请号：PCT/EP2017/058670
申请日：2017-04-11
申请人： CCP TECHNOLOGY GMBH
发明人： KUEHL, Olaf , MISSELHORN, Mark
IPC分类号： C01B3/24 , C10K3/06 , C01B32/05 , C21B7/00
CPC分类号： C01B3/24 , C10K3/026 , C10K3/06
摘要： Ein Verfahren zur Herstellung von Synthesegas mit variablem H 2 /CO-Verhältnis wird beschrieben, das folgende Schritte aufweist: Aufspalten eines Kohlenwasserstoff-Fluids, insbesondere eines ersten Gases mit der Zusammensetzung C n H m , zu Kohlenstoff und Wasserstoff in einem Reaktionsraum eines Kohlenwasserstoffkonverters unter Zuführung von Wärme, wobei der Kohlenstoff und der Wasserstoff nach der Aufspaltung eine Temperatur von wenigstens 800°C aufweist; Leiten des Kohlenstoffes und des Wasserstoffes, die aus der Aufspaltung gewonnen wurden, in einen Reaktionsraum eines CO 2 -Konverters; Mischen von CO 2 aus einer externen Quelle mit dem Kohlenstoff und dem Wasserstoff in dem CO 2 -Konverter; Umwandeln des CO 2 und des durch die Aufspaltung gewonnenen Kohlenstoffes in CO bei einer Temperatur von 800 bis 1700°C, so dass ein erstes Synthesegasgemisch entsteht; Mischen des ersten Synthesegasgemisches mit zusätzlichem Wasserstoff, so dass ein zweites Synthesegasgemisch entsteht, das einen höheren Wasserstoffanteil hat als das erste Synthesegasgemisch. Der zusätzliche Wasserstoff wird durch folgende Schritte erzeugt: Leiten eines zweiten Gases mit der Zusammensetzung C n H m in einen Reaktionsraum eines Feststoffkonverters, der ein Feststoffbett aus kohlenstoffhaltigen Granulat enthält, insbesondere ein durch den Reaktionsraum geführtes Wanderbett, wobei das Feststoffbett wenigstens lokal eine Temperatur von 800 bis 1700°C aufweist; Aufspalten des zweiten Gases mit der Zusammensetzung C n H m zu Kohlenstoff und Wasserstoff, welcher den zusätzliche Wasserstoff bildet; Trennen des durch die Aufspaltung gewonnenen Kohlenstoffes und des zusätzlichen Wasserstoffes durch Ablagern des Kohlenstoffes an dem kohlenstoffhaltigen Granulat.
摘要翻译：描述了用于生产具有可变H 2 / CO比的合成气的方法，其包括以下步骤：将烃流体，特别是第一气体与组合物C <子>名词ħ<子>米以下的W＆AUML Zuf导航用途导向烃转换器的反应空间碳和氢; RME，其中，所述分解温度后的碳和氢至少800℃; 将从分解中回收的碳和氢传递到CO 2子转换器的反应空间中; 将来自外部源的CO 2与CO 2转化器中的碳和氢混合; 在800至1700℃的温度下将CO 2和通过分解回收的碳转化为CO以形成第一合成气体混合物; 将第一合成气体混合物与另外的氢气混合，从而形成第二合成气体混合物，其具有比第一合成气体混合物更高的氢含量。社会保险机构＆AUML; USEFUL氢被通过以下步骤产生的：引导具有℃的组合物的第二气体<子>名词ħ<子>米在含有碳质粒状＆AUML的固体床的固体转换器的反应室; 特别是由反应空间引起的移动床，其中固体床至少局部地具有800至1700℃的温度; 将组成为C n的第二种气体分解成碳和氢，形成额外的氢; 通过在含碳颗粒上沉积碳来分离通过分解回收的碳和额外的氢气。

6. 发明授权

US10906806B2 Apparatus and method for producing a synthesis gas 有权
公开(公告)号：US10906806B2
公开(公告)日：2021-02-02
申请号：US15570392
申请日：2016-04-29
申请人： CCP Technology GmbH
发明人： Olaf Kuhl
IPC分类号： C01B3/24 , B01J19/08 , B01J19/26 , C10K3/04
摘要： The apparatus described herein comprises a first reaction chamber having an inlet for a hydrocarbon medium, particularly a gas having the composition CnHm, and an outlet. Means for decomposing the hydrocarbons into carbon particles and hydrogen by introducing heat are provided between the inlet and the outlet in the first reaction chamber. The apparatus also comprises a second reaction chamber having an elongated configuration and having a first inlet at one end and an outlet at the opposite end, wherein the first inlet of the second reaction chamber is connected with the outlet of the first reaction chamber, and wherein the second reaction chamber comprises a widening flow cross-section (measured perpendicular to the longitudinal dimension of the second reaction chamber) between the inlet and the outlet. In addition, at least one second inlet into the second reaction chamber is provided, wherein the second inlet can be connected to a source for CO2 and/or H2O. Preferably, the second inlet is connected with a source of CO2, and therefore CO2 is injected therewith during operation. A method for operating this apparatus is also described. The energy balance of a synthesis gas production can be improved with the apparatus and the method for operating compared with known methods.

7. 发明授权

US10526670B2 Blast furnace and method for operating a blast furnace 有权
公开(公告)号：US10526670B2
公开(公告)日：2020-01-07
申请号：US14955105
申请日：2015-12-01
申请人： CCP TECHNOLOGY GMBH
发明人： Olaf Kuhl
IPC分类号： C21B5/06 , C01B32/40 , C21B7/00 , F27B1/10 , F27D17/00
摘要： The present blast furnace and method for operating a blast furnace are able to reduce CO2 production and the amount of applied additives and heating material. The method for metal production of metal ores comprising the following steps: reducing a metal ore, particularly a metal oxide, and thereby producing furnace gas containing CO2 in a blast furnace shaft; discharging the furnace gas from the blast furnace shaft; directing at least a portion of the furnace gas into a CO2 converter and reducing the CO2 in the furnace gas into CO; directing at least a portion of the CO from the CO2 converter into the blast furnace shaft. The method produces CO as a gaseous reduction agent which may be easily introduced into the blast furnace shaft. Further, a blast furnace for metal production by reducing a metal ore designed for operating according to the method is described.

8. 发明授权

US10287643B2 Blast furnace and method for operating a blast furnace 有权
公开(公告)号：US10287643B2
公开(公告)日：2019-05-14
申请号：US15039444
申请日：2014-11-27
申请人： CCP Technology GmbH
发明人： Olaf Kuhl
IPC分类号： C21B5/06 , C21B5/00 , H01M8/22 , B01D53/84 , C12M1/02 , C12P7/08 , B01D53/90 , B01D53/86 , C21B7/00 , C12M1/00 , B01D53/62 , H01M8/0612 , C12P7/06
摘要： A process for processing metal ore includes: reducing a metal ore, particularly a metallic oxide, in a blast furnace shaft; producing furnace gas containing CO2, in the blast furnace shaft; discharging the furnace gas from the blast furnace shaft; directing at least a portion of the furnace gas directly or indirectly into a CO2-converter; and converting the CO2 contained in the furnace gas into an aerosol consisting of a carrier gas and C-particles in the CO2-converter in the presence of a stoichiometric surplus of C; directing at least a first portion of the aerosol from the CO2-converter into the blast furnace shaft; and introducing H2O into the blast furnace shaft. By virtue of the reaction C+H2O→CO2+2H, nascent hydrogen is produced in the blast furnace which causes rapid reduction of the metal ore. The speed of reduction of the metal ore is thus increased, and it is possible to increase either the throughput capacity of the blast furnace or to reduce the size of the blast furnace. An aerosol in the form of a fluid is easily introducible into the blast furnace shaft.

9. 发明申请

US20170051210A1 METHOD AND DEVICE FOR PRODUCING SYNTHETIC HYDROCARBONS 审中-公开
标题翻译：用于生产合成烃的方法和装置
公开(公告)号：US20170051210A1
公开(公告)日：2017-02-23
申请号：US15308151
申请日：2015-05-13
申请人： CCP TECHNOLOGY GMBH
发明人： Olaf Kuhl
IPC分类号： C10G2/00 , C10J3/46
CPC分类号： C10G2/32 , C01B3/24 , C01B2203/0266 , C01B2203/062 , C01B2203/0861 , C01B2203/1235 , C10G2/34 , C10J3/00 , C10J3/46 , C10J2300/0966 , C10J2300/0973 , C10J2300/1618 , C10J2300/1659 , C10J2300/1675
摘要： A method producing synthetic hydrocarbons includes producing synthesis gas. An initial step, carbon or a mixture of carbon and hydrogen is brought into contact with water at a temperature of 800-1700° C. The synthesis gas is converted into synthetic functionalised and/or non-functionalised hydrocarbons by means of a Fischer Tropsch process wherein it is brought into contact with a suitable catalyst, and wherein water in which a portion of the synthetic hydrocarbons is dissolved results as a by-product. At least a portion of the water that is produced as a by-product is supplied to the initial step. The hydrocarbons that are dissolved in the water decompose into particle-like carbon and hydrogen at the high temperature. The carbon is converted into CO in the presence of water and at a high temperature and forms a portion of the synthesis gas that is produced. In this way, a costly process for cleaning half of the water that is produced as a by-product is avoided.
摘要翻译：生产合成烃的方法包括生产合成气。初始步骤，碳或碳与氢的混合物在800-1700℃的温度下与水接触。合成气通过费 - 托法转化为合成官能化和/或非官能化烃其中其与合适的催化剂接触，并且其中部分合成烃溶解的水作为副产物产生。将作为副产物生产的水的至少一部分供给到初始步骤。溶解在水中的烃在高温下分解成颗粒状碳和氢。在水和高温存在下将碳转化为CO，并形成所生成的一部分合成气。以这种方式，避免了作为副产物生产的用于清洁一半水的昂贵的方法。

10. 发明申请

US20160089654A1 PROCESS AND SYSTEM FOR GENERATING SYNTHESIS GAS 审中-公开
标题翻译：用于产生合成气的方法和系统
公开(公告)号：US20160089654A1
公开(公告)日：2016-03-31
申请号：US14964851
申请日：2015-12-10
申请人： CCP TECHNOLOGY GMBH
发明人： Olaf Kuhl
IPC分类号： B01J19/24 , B01J19/12 , B01J19/00 , C01B3/24
摘要： A method and an apparatus for generating synthesis gas using hydrocarbons and water are described. In further embodiments of the method and the apparatus, synthesis gases having any desired CO/hydrogen ratio and/or synthetic functionalised and/or non-functionalised hydrocarbons are generated. With this method, a hydrocarbon containing fluid may be transformed into a synthesis gas having variable hydrogen content without generating significant amounts of CO2. Further, hydrogen and different forms of carbon may be obtained as by-products.
摘要翻译：描述了使用烃和水产生合成气的方法和装置。在该方法和装置的其它实施方案中，产生具有任何所需CO /氢比和/或合成官能化和/或非官能化烃的合成气。通过这种方法，可以将含烃流体转化为具有可变氢含量的合成气，而不产生显着量的CO 2。此外，作为副产物可以获得氢气和不同形式的碳。

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