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1. 发明申请

WO2003002652A1 ADDITIVE FUNCTIONALIZED ORGANOPHILIC NANO-SCALED FILLERS 审中-公开
标题翻译：添加官能化有机纳米填料填料
公开(公告)号：WO2003002652A1
公开(公告)日：2003-01-09
申请号：PCT/EP2002/006848
申请日：2002-06-20
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , CAMENZIND, Hugo , HERBST, Heinz , WUNDERLICH, Wiebke
发明人： CAMENZIND, Hugo , HERBST, Heinz , WUNDERLICH, Wiebke
IPC分类号： C08K13/02
CPC分类号： B82Y30/00 , C08K5/005 , C08K5/14 , C08K9/04 , C08K2201/011
摘要： The present invention discloses a product obtainable by reacting a nano-scaled filler with a compound of the formula (I): AD-L-RG, wherein AD is an additive selected from the group of radical scavengers, hydroperoxide decomposers, UV-absorbers, light stabilizers, flame retardants or photoinitiators, L is a spacer, RG is a reactive group, and the nano-scaled filler can be of unmodified or organophilically modified character. These products are for example useful as stabilizers and/or compatibilizers in organic materials, or as photoinitiators in pre-polymeric or pre-crosslinking formulations.
摘要翻译：本发明公开了一种通过使纳米级填料与式（I）化合物反应得到的产物：AD-L-RG，其中AD是选自自由基清除剂，氢过氧化物分解剂，UV吸收剂，光稳定剂，阻燃剂或光引发剂，L是间隔基，RG是反应性基团，纳米级填料可以是未改性的或有机改性的。这些产品例如可用作有机材料中的稳定剂和/或增容剂，或作为预聚物或预交联配方中的光引发剂。

2. 发明申请

WO2003095512A1 POLYMERS PRODUCED BY ATOM TRANSFER RADICAL POLYMERISATION TECHNIQUE WITH STRUCTURALLY MODIFIED TERMINAL GROUPS 审中-公开
标题翻译：具有结构改性终端组的原子转移辐射聚合技术生产的聚合物
公开(公告)号：WO2003095512A1
公开(公告)日：2003-11-20
申请号：PCT/EP2003/004449
申请日：2003-04-29
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , CAMENZIND, Hugo , DUBS, Paul , HÄNGGI, Peter , MARTIN, Roger , MÜHLEBACH, Andreas , RIME, François
发明人： CAMENZIND, Hugo , DUBS, Paul , HÄNGGI, Peter , MARTIN, Roger , MÜHLEBACH, Andreas , RIME, François
IPC分类号： C08F293/00
CPC分类号： C08F293/005 , C08F8/26 , C08F8/30 , C08F8/34 , C08F8/40 , C08F2438/01 , C08K5/005 , C08F120/18
摘要： The present invention relates to a block copolymer prepared by ATRP, wherein the polymer chain terminal group is structurally modified with the functionally effective group of a lubricant or polymer additive selected from the group consisting of antioxidants, metal deactivators, antiwear and extreme pressure additives and corrosion inhibitors. The invention also relates to a composition comprising the structurally modified block copolymer and a composition of matter subject to oxidative, thermal or light induced degradation, such as lubricants or polymers.
摘要翻译：本发明涉及由ATRP制备的嵌段共聚物，其中聚合物链末端基团用功能有效的润滑剂或聚合物添加剂基团进行结构改性，所述润滑剂或聚合物添加剂选自抗氧化剂，金属钝化剂，抗磨和极压添加剂以及腐蚀抑制剂。本发明还涉及包含结构改性的嵌段共聚物和经受氧化，热或光诱导降解的物质组合物如润滑剂或聚合物的组合物。

3. 发明申请

WO2004050671A8 LIQUID PHENOLIC SULPHUR-CONTAINING ANTIOXIDANTS 审中-公开
标题翻译：液体酚类含硫抗氧化剂
公开(公告)号：WO2004050671A8
公开(公告)日：2004-09-16
申请号：PCT/EP0350876
申请日：2003-11-24
申请人： CIBA SC HOLDING AG , CAMENZIND HUGO , DUBS PAUL , MARTIN ROGER , CHASAN DAVID ELIEZER , DEMME GUNNAR , ROBBINS JAMES
发明人： CAMENZIND HUGO , DUBS PAUL , MARTIN ROGER , CHASAN DAVID ELIEZER , DEMME GUNNAR , ROBBINS JAMES
IPC分类号： C07G99/00 , C07C323/12 , C10M135/26 , C10M159/12 , C07G17/00
CPC分类号： C10M159/12 , C07C323/12 , C10M135/26 , C10M2205/0285 , C10M2207/021 , C10M2207/281 , C10M2207/289 , C10M2215/064 , C10M2215/223 , C10M2219/084 , C10M2219/085 , C10N2230/04 , C10N2230/10 , C10N2240/10 , C10N2240/102 , C10N2240/104
摘要： The invention relates to liquid sulphur-containing antioxidants obtainable by reacting at least compound of formula (I) with at least one compound of formula (II) and at least one compound of formula (III) where the variables are as defined in the claims. The invention further relates to compositions comprising them. The novel lubricant compositions comprise the reaction product of a selected group of 5-tert-butyl-4-hydroxy-3-methyl(or tert-butyl)phenyl substituted carboxylic acid esters with thiodiethylene glycol and a mono-hydroxy alcohol with a chain length higher than 4 C-atoms. The novel lubricant compositions are highly resistant to oxidative degradation and are capable of reducing negative effects of deposits, such as black sludge, in motor combustion engines, particularly spark ignition internal combustion engines.
摘要翻译：本发明涉及通过使式（I）化合物与至少一种式（II）化合物和至少一种式（III）化合物反应而得到的液体含硫抗氧化剂，其中变量如权利要求中所定义。本发明还涉及包含它们的组合物。新型润滑剂组合物包含5-选择的5-叔丁基-4-羟基-3-甲基（或叔丁基）苯基取代的羧酸酯与硫代二甘醇和链长的单羟基醇的反应产物高于4个C原子。新型润滑剂组合物对氧化降解具有高度抗性，并且能够减少马达内燃机，特别是火花点火内燃机中的沉积物（例如黑色污泥）的负面影响。

4. 发明申请

WO2004026811A2 SUCCINIC ACID SEMI-AMIDES AS ANTI-CORROSIVES AGENTS 审中-公开
标题翻译：琥珀酸半酰胺作为抗腐蚀剂
公开(公告)号：WO2004026811A2
公开(公告)日：2004-04-01
申请号：PCT/EP2003/010115
申请日：2003-09-11
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , CAMENZIND, Hugo , HÄNGGI, Peter
发明人： CAMENZIND, Hugo , HÄNGGI, Peter
IPC分类号： C07C235/74
CPC分类号： C10M133/16 , C10M133/24 , C10M133/38 , C10M2215/08 , C10M2215/12 , C10M2215/16 , C10M2215/22 , C10M2215/226 , C10N2230/12 , C10N2240/04 , C10N2240/08 , C10N2240/10 , C10N2240/40 , C10N2270/00
摘要： The invention relates to improved compositions based on lubricants and comprising succinic acid semi-amides and to the use of those lubricant compositions in improving the use properties of lubricants, such as hydraulic or metal-working fluids, greases, gear oils or engine oils.
摘要翻译：本发明涉及基于润滑剂并包含琥珀酸半酰胺的改进组合物，并涉及这些润滑剂组合物在改善润滑剂如液压或金属加工流体，润滑脂的使用性能中的用途，齿轮油或发动机油。

5. 发明申请

WO03095512A8 POLYMERS PRODUCED BY ATOM TRANSFER RADICAL POLYMERISATION TECHNIQUE WITH STRUCTURALLY MODIFIED TERMINAL GROUPS 审中-公开
标题翻译：具有结构改性终端组的原子转移辐射聚合技术生产的聚合物
公开(公告)号：WO03095512A8
公开(公告)日：2004-10-21
申请号：PCT/EP0304449
申请日：2003-04-29
申请人： CIBA SC HOLDING AG , CAMENZIND HUGO , DUBS PAUL , HAENGGI PETER , MARTIN ROGER , MUEHLEBACH ANDREAS , RIME FRANCOIS
发明人： CAMENZIND HUGO , DUBS PAUL , HAENGGI PETER , MARTIN ROGER , MUEHLEBACH ANDREAS , RIME FRANCOIS
IPC分类号： C08F2/38 , C08F8/00 , C08F293/00 , C08K5/00
CPC分类号： C08F293/005 , C08F8/26 , C08F8/30 , C08F8/34 , C08F8/40 , C08F2438/01 , C08K5/005 , C08F120/18
摘要： The present invention relates to a block copolymer prepared by ATRP, wherein the polymer chain terminal group is structurally modified with the functionally effective group of a lubricant or polymer additive selected from the group consisting of antioxidants, metal deactivators, antiwear and extreme pressure additives and corrosion inhibitors. The invention also relates to a composition comprising the structurally modified block copolymer and a composition of matter subject to oxidative, thermal or light induced degradation, such as lubricants or polymers.
摘要翻译：本发明涉及通过ATRP制备的嵌段共聚物，其中聚合物链端基在结构上用功能有效的润滑剂或聚合物添加剂基团进行改性，所述润滑剂或聚合物添加剂选自抗氧化剂，金属钝化剂，抗磨和极压添加剂和腐蚀抑制剂。本发明还涉及包含结构改性的嵌段共聚物和经受氧化，热或光诱导降解的物质组合物如润滑剂或聚合物的组合物。

6. 发明申请

WO2004050671A1 LIQUID PHENOLIC SULPHUR-CONTAINING ANTIOXIDANTS 审中-公开
标题翻译：液体酚类含硫抗氧化剂
公开(公告)号：WO2004050671A1
公开(公告)日：2004-06-17
申请号：PCT/EP2003/050876
申请日：2003-11-24
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , CAMENZIND, Hugo , DUBS, Paul , MARTIN, Roger , CHASAN, David, Eliezer , DEMME, Gunnar , ROBBINS, James
发明人： CAMENZIND, Hugo , DUBS, Paul , MARTIN, Roger , CHASAN, David, Eliezer , DEMME, Gunnar , ROBBINS, James
IPC分类号： C07G17/00
CPC分类号： C10M159/12 , C07C323/12 , C10M135/26 , C10M2205/0285 , C10M2207/021 , C10M2207/281 , C10M2207/289 , C10M2215/064 , C10M2215/223 , C10M2219/084 , C10M2219/085 , C10N2230/04 , C10N2230/10 , C10N2240/10 , C10N2240/102 , C10N2240/104
摘要： The invention relates to liquid sulphur-containing antioxidants and to compositions comprising them. The novel lubricant comprise the reaction product of a selected group of 5-tert-butyl-4-hydroxy-3-methyl(or tert-butyl)phenyl substituted carboxylic acid esters with thiodiethylene glycol and a mono-hydroxy alcohol with a carbon chain length higher than 4 C-atoms. The novel lubricant compositions are highly resistant to oxidative degradation and are capable of reducing the negative effects of deposits, such as black sludge, in motor combustion engines, particularly spark ignition internal combustion engines.
摘要翻译：本发明涉及液体含硫抗氧化剂及其组合物。新型润滑剂包括选择的5-叔丁基-4-羟基-3-甲基（或叔丁基）苯基取代的羧酸酯与硫代二乙二醇和具有碳链长度的单羟基醇的反应产物高于4个C原子。新型润滑剂组合物对氧化降解具有高度抗性，并且能够减少马达内燃机，特别是火花点火内燃机中的沉积物如黑色污泥的负面影响。

7. 发明申请

WO2004026811A3 SUCCINIC ACID SEMI-AMIDES AS ANTI-CORROSIVES AGENTS 审中-公开
标题翻译：作为抗腐蚀剂的半胱氨酸半胱氨酸
公开(公告)号：WO2004026811A3
公开(公告)日：2004-06-17
申请号：PCT/EP0310115
申请日：2003-09-11
申请人： CIBA SC HOLDING AG , CAMENZIND HUGO , HAENGGI PETER
发明人： CAMENZIND HUGO , HAENGGI PETER
IPC分类号： C07D295/18 , C07C233/47 , C10M133/16 , C10M133/24 , C10M133/38 , C10M133/40 , C10M133/50 , C10M169/04 , C10N10/02 , C10N10/04 , C10N30/12 , C10N40/04 , C10N40/08 , C10N40/20 , C10N40/25 , C10N50/10 , C07C235/74 , C07C237/22 , C07C255/29 , C10M141/06
CPC分类号： C10M133/16 , C10M133/24 , C10M133/38 , C10M2215/08 , C10M2215/12 , C10M2215/16 , C10M2215/22 , C10M2215/226 , C10N2230/12 , C10N2240/04 , C10N2240/08 , C10N2240/10 , C10N2240/40 , C10N2270/00
摘要： The invention relates to improved compositions based on lubricants and comprising succinic acid semi-amides and to the use of those lubricant compositions in improving the use properties of lubricants, such as hydraulic or metal-working fluids, greases, gear oils or engine oils.
摘要翻译：本发明涉及基于润滑剂并且包含琥珀酸半酰胺的改进的组合物以及这些润滑剂组合物在改善润滑剂如液压或金属加工流体，润滑脂，齿轮油或发动机油中的使用性能中的用途。

8. 发明专利

CA1317596C AMINOMETHYL DERIVATIVES OF MONOTHIOCARBAMATES AND DITHIOCARBAMATES AS ADDITIVES FOR LUBRICANTS 未知
公开(公告)号：CA1317596C
公开(公告)日：1993-05-11
申请号：CA577428
申请日：1988-09-15
申请人： CAMENZIND HUGO
发明人： CAMENZIND HUGO
IPC分类号： C07D263/16 , C07D277/16 , C07D279/06 , C10M135/32 , C10M135/36 , C10N30/06 , C10N40/08 , C10N40/25
摘要： Aminomethyl derivatives of monothiocarbamates and dithiocarbamates as additives for lubricants Composition containing one or more lubricants or hydraulic oils based on mineral oil, synthetic oils or mixtures thereof and at least one compound of the formulae I, II or III, I II III in which R1, R2, R3, R4, R5 and R6 independently of one another are C1-C24alkyl or C1-C24alkyl which can be substituted by oxo or thio groups, or C3-C24alkyl which can be interrupted by , -O-, -S- and/or -N(R8)- in which R8 is hydrogen or C1-C12-alkyl and which can be substituted by oxo or thionogroups, or C2-C24alkenyl or phenyl or naphthyl which is unsubstituted or substituted by one or two C1-C12alkyl, C1-C4alkoxy, C2-C24carboalkoxy or nitro groups; or are C7-C10phenylalkyl, and R1, R2, R3 and R4 additonally are hydrogen, or R1 and R2, or R1 and R3 in the event that n is zero, together with the C atoms to which they are attached, form a 5-membered or 6-membered aliphatic ring which can be interrupted by -N(R8)- in which R8 is as defined above, -O- or -S- and/or can be substituted by oxo or thiono groups; or in which R4 and R5, together with the N atom to which they are attached, form a 5-membered or 6-membered aliphatic-heterocyclic ring which, additionally to the N atom, can contain further heteroatoms ¢N(R8), O or S! and/or can be substituted by oxo or thiono groups, and in which R7 is also C2-C12alkylene which can be interrupted by -N(R8)-, -O- and/or -S- and/or can contain oxo or thiono groups, C6-C15cyclo-alkylene, C6-C15arylene, carbonyl or thiocarbonyl, or the group -N(R4)-R7-N(R4)- is a piperazine-1,4-diyl radical which can be substituted by one or more methyl groups, and X is also oxygen or sulfur and n is the numbers zero or 1, and also the compounds themselves, provided that they are novel.

9. 发明专利

CA1304737C THIADIAZOLE DERIVATIVES AS LUBRICANT ADDITIVES 未知
公开(公告)号：CA1304737C
公开(公告)日：1992-07-07
申请号：CA586545
申请日：1988-12-21
申请人： CAMENZIND HUGO
发明人： CAMENZIND HUGO
IPC分类号： C07D285/12 , C07D285/125 , C10M135/36 , C10N30/06 , C10N30/10 , C10N30/12 , C10N40/08 , C07D417/00
摘要： A-16835/+ Thiadiazole derivatives as lubricant additives A lubricant composition or hydraulic oil composition containing at least one lubricant or one hydraulic oil and at least one 2,5-di-mercapto-1,3,4-thiadiazole of general formula I wherein R1, R2, R3 and R4, which are identical or different, are alkyl having 1 to 24 C atoms, alkenyl having 3 to 12 C atoms or phenyl (C1-C4)-alkyl which is unsubstituted or substituted in the phenyl radical by C1-C4-alkyl, or R1 and R2 and/or R3 and R4, with the N atom to which they are bonded, are a morpholine, piperidine, pyrrolidine, piperazine, methylpiperazine or perhydroazepine radical which is unsubstituted or substituted by C1-C4-alkyl, and X and X1, which are identical or different, are H, alkyl having 1 to 23 C atoms, phenyl, phenyl-(C1-C4)-alkyl or phenyl substituted by C1-C12-alkyl, C1-C12-alkoxy, hydroxyl, di(C1-C4-alkyl)amino, halogen and/or nitro.

10. 发明专利

CA1277308C ADDITIVES FOR LUBRICANT COMPOSITIONS 未知
公开(公告)号：CA1277308C
公开(公告)日：1990-12-04
申请号：CA514740
申请日：1986-07-28
申请人： CAMENZIND HUGO
发明人： CAMENZIND HUGO , DUBS PAUL
IPC分类号： C10M135/34 , C10M135/36 , C10N30/06 , C10N30/08 , C10N30/12 , C10N40/00 , C10N40/25 , C07D331/02
摘要： Additives for lubricant compositions The invention relates to lubricant compositions comprising at least one compound of the general formula I (I) wherein R1 and R2 are each independently selected from C1-C24alkyl, C1-C24alkyl which is interrupted by one or more identical or different members selected from -O-, -S- and/or -?- ant/or which contains one or more oxo and/or thiono groups; or C3-C24alkenyl, C2-C4hydroxyalkyl, C5-C8cycloalkyl, phenyl or phenyl which is substituted by one or two C1-C12alkyl, C1-C4alkoxy, C2-C2-alkoxy-carbonyl and/or nitro groups; or naphthyl, C7-C10aralkyl, furan-2-ylmethyl or tetrahydrofuran-2-ylmethyl, or R1 and R2, together with the nitrogen atom to which they are attached, form a 5- or 6-membered mononuclear aliphatic heterocyclic ring which, in addition to the N atom, may contain one or two additional N, O and/or S atoms as ring members and/or one or two oxo and/or thiono groups as substituents, or form an indolinyl, 1,2,3,4-tetrahydro-quinolinyl or 1,2,3,4-tetrahydroisoquinolinyl radical which radicals are unsubstituted or substituted by 1 to 3 methyl groups, and R3 is hydrogen or C1-C8alkyl. The N,N-disubstituted S-thiiranylmethylcarbamothioates of formula I are particularly suitable for use as antiwear additives and extreme pressure additives for mineral and synthetic lubricants.

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