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1. 发明授权

EP0785966B1 POLYCARBONATE-CONTAINING POLYMERS FLAME RETARDED WITH OLIGOMERIC PHOSPHATE ESTERS 失效
标题翻译： BY低聚物磷STAR隔爆PLOYCARBONAT含氯聚合物
公开(公告)号：EP0785966B1
公开(公告)日：2006-03-01
申请号：EP95936257.5
申请日：1995-10-12
申请人： Akzo Nobel N.V. , Moy, Paul Y. , Bright, Danielle A.
发明人： MOY, Paul, Y. , BRIGHT, Danielle, A.
IPC分类号： C08K5/523 , C08K5/521 , C08K5/52 , C08G64/00
CPC分类号： C08K5/523 , C08L69/00
摘要： Polycarbonate-containing compositions are flame retarded with a mixture which comprises an arylene-bridged oligomeric polyphosphate ester and an effective amount of an alkylene-bridged diphosphate compound for increased flame retardancy efficacy and improved processing characteristics.

2. 发明公开

EP0785966A4 POLYCARBONATE-CONTAINING POLYMERS FLAME RETARDED WITH OLIGOMERIC PHOSPHATE ESTERS 失效
标题翻译： BY低聚物磷STAR隔爆PLOYCARBONAT含氯聚合物
公开(公告)号：EP0785966A4
公开(公告)日：2002-01-09
申请号：EP95936257
申请日：1995-10-12
申请人： AKZO NOBEL NV , MOY PAUL Y , BRIGHT DANIELLE A
发明人： MOY PAUL Y , BRIGHT DANIELLE A
IPC分类号： C08K5/523 , C08L69/00 , C08G64/00 , C08K5/52 , C08K5/521
CPC分类号： C08K5/523 , C08L69/00
摘要： Polycarbonate-containing compositions are flame retarded with a mixture which comprises an arylene-bridged oligomeric polyphosphate ester and an effective amount of an alkylene-bridged diphosphate compound for increased flame retardancy efficacy and improved processing characteristics.

3. 发明公开

EP0785966A1 POLYCARBONATE-CONTAINING POLYMERS FLAME RETARDED WITH OLIGOMERIC PHOSPHATE ESTERS 失效
标题翻译： BY低聚物磷STAR隔爆PLOYCARBONAT含氯聚合物
公开(公告)号：EP0785966A1
公开(公告)日：1997-07-30
申请号：EP95936257.0
申请日：1995-10-12
申请人： AKZO NOBEL N.V. , Moy, Paul Y. , Bright, Danielle A.
发明人： MOY, Paul, Y. , BRIGHT, Danielle, A.
IPC分类号： C08K5 , C08L69
CPC分类号： C08K5/523 , C08L69/00
摘要： Polycarbonate-containing compositions are flame retarded with a mixture which comprises an arylene-bridged oligomeric polyphosphate ester and an effective amount of an alkylene-bridged diphosphate compound for increased flame retardancy efficacy and improved processing characteristics.

4. 发明公开

EP0796265A4 PROCESS FOR MAKING HYDROXY-TERMINATED AROMATIC OLIGOMERIC PHOSPHATES 失效
标题翻译： PROCESS生产芳族低聚磷酸酯的羟基封端
公开(公告)号：EP0796265A4
公开(公告)日：1998-05-06
申请号：EP95941523
申请日：1995-12-05
申请人： AKZO NOBEL NV , BRIGHT DANIELLE A , PIRRELLI RONALD L
发明人： BRIGHT DANIELLE A , PIRRELLI RONALD L
IPC分类号： B65H45/09 , C07F9/09 , B41F13/58 , B65H45/22 , C07F9/12
CPC分类号： B41F13/58 , C07F9/12
摘要： The present invention is a process for forming hydroxy-terminated aromatic oligomeric phosphates by the initial reaction of a monoaryl dihalophosphate, such as monophenyl dichlorophosphate, with an aromatic diol, such as resorcinol, to form a halo-terminated aromatic oligomeric phosphate and the subsequent reaction of that halo-terminated phosphate with aromatic diol to form the hydroxy-terminated aromatic oligomeric phosphate. The initial and subsequent reactions preferably employ a Lewis acid catalyst, such as magnesium dichloride.
摘要翻译：本发明是用于通过单芳dihalophosphate ,:如单苯基二氯的初始反应形成羟基封端的芳族低聚磷酸酯，与芳族二醇的方法：如间苯二酚，以形成卤代封端的芳族低聚磷酸酯和随后的反应的那样卤端基磷酸盐与芳族二醇以形成羟基封端的芳族低聚磷酸酯。初始和随后的反应优选使用路易斯酸催化剂：如二氯化镁。

5. 发明公开

EP0789703A1 PROCESS FOR THE FORMATION OF HYDROCARBYL BIS(HYDROCARBYL PHOSPHATE) 失效
标题翻译： METHOD FOR REPRESENTING烃基BIS（烃基磷酸酯）
公开(公告)号：EP0789703A1
公开(公告)日：1997-08-20
申请号：EP95937516.0
申请日：1995-10-20
申请人： AKZO NOBEL N.V. , Bright, Danielle A. , Pirrelli, Ronald L.
发明人： BRIGHT, Danielle, A. , PIRRELLI, Ronald, L.
IPC分类号： C07F9
CPC分类号： C07F9/093 , C07F9/12
摘要： A process for the synthesis of a hydrocarbyl bis(dihydrocarbyl phosphate), such as a hydrocarbyl bis(diaryl phosphate), comprises the reaction of an unstable hydrocarbyl-containing diol, such as an aromatic group-containing diol, with a dihydrocarbyl halophosphate, such as diphenyl chlorophosphate, in the presence of a Lewis acid catalyst, such as magnesium dichloride, in the additional presence of an effective amount (e.g., up to about 100 % by weight of diol and halophosphate) of a liquid hydrocarbon, such as an aliphatic hydrocarbon, like heptane, or an aromatic hydrocarbon, such as toluene, to enhance the removal of hydrogen halide by-product and thereby increase the yield of hydrocarbyl bis(dihydrocarbyl phosphate).

6. 发明授权

EP0796265B1 PROCESS FOR MAKING HYDROXY-TERMINATED AROMATIC OLIGOMERIC PHOSPHATES 失效
标题翻译： PROCESS生产芳族低聚磷酸酯的羟基封端
公开(公告)号：EP0796265B1
公开(公告)日：2003-04-09
申请号：EP95941523.3
申请日：1995-12-05
申请人： Akzo Nobel N.V. , Bright, Danielle A. , Pirrelli, Ronald L.
发明人： BRIGHT, Danielle, A. , PIRRELLI, Ronald, L.
IPC分类号： C07F9/12
CPC分类号： B41F13/58 , C07F9/12
摘要： The present invention is a process for forming hydroxy-terminated aromatic oligomeric phosphates by the initial reaction of a monoaryl dihalophosphate, such as monophenyl dichlorophosphate, with an aromatic diol, such as resorcinol, to form a halo-terminated aromatic oligomeric phosphate and the subsequent reaction of that halo-terminated phosphate with aromatic diol to form the hydroxy-terminated aromatic oligomeric phosphate. The initial and subsequent reactions preferably employ a Lewis acid catalyst, such as magnesium dichloride.

7. 发明公开

EP0796265A1 PROCESS FOR MAKING HYDROXY-TERMINATED AROMATIC OLIGOMERIC PHOSPHATES 失效
标题翻译： PROCESS生产芳族低聚磷酸酯的羟基封端
公开(公告)号：EP0796265A1
公开(公告)日：1997-09-24
申请号：EP95941523.0
申请日：1995-12-05
申请人： Akzo Nobel N.V. , Bright, Danielle A. , Pirrelli, Ronald L.
发明人： BRIGHT, Danielle, A. , PIRRELLI, Ronald, L.
IPC分类号： B65H45 , C07F9 , B41F13
CPC分类号： B41F13/58 , C07F9/12
摘要： The present invention is a process for forming hydroxy-terminated aromatic oligomeric phosphates by the initial reaction of a monoaryl dihalophosphate, such as monophenyl dichlorophosphate, with an aromatic diol, such as resorcinol, to form a halo-terminated aromatic oligomeric phosphate and the subsequent reaction of that halo-terminated phosphate with aromatic diol to form the hydroxy-terminated aromatic oligomeric phosphate. The initial and subsequent reactions preferably employ a Lewis acid catalyst, such as magnesium dichloride.

8. 发明公开

EP0796293A4 HYDROXY-TERMINATED AROMATIC OLIGOMERIC PHOSPHATE AS ADDITIVE FLAME RETARDANT IN POLYCARBONATE RESIN COMPOSITION 失效
标题翻译：低聚的，芳族磷酸酯羟基比在阻燃添加剂的聚碳酸酯树脂组合物
公开(公告)号：EP0796293A4
公开(公告)日：1999-03-31
申请号：EP95942594
申请日：1995-12-06
申请人： AKZO NOBEL NV , BRIGHT DANIELLE A , MOY PAUL Y
发明人： BRIGHT DANIELLE A , MOY PAUL Y
IPC分类号： C08K5/521 , C08K5/523 , C08L55/02 , C08L69/00 , C08K5/52
CPC分类号： C08K5/523 , C08L69/00
摘要： The present application relates to a flame retarded polycarbonate resin composition which comprises a polycarbonate resin substrate containing an effective amount (e.g., preferably from about 5 % to about 15 %, by weight of the resin substrate) for flame retardancy of a hydroxy-terminated aromatic oligomeric phosphate composition of formula (I), where R is a hydrocarbyl group derived from an aliphatic or aromatic diol, Ar is an alkyl-substituted or unsubstituted phenyl group, n is from about 0 to about 10, and the phosphate composition contains a predominant amount of phosphate where n ranges from 0 to 1.

9. 发明公开

EP0789703A4 PROCESS FOR THE FORMATION OF HYDROCARBYL BIS(HYDROCARBYL PHOSPHATE) 失效
标题翻译： VERFAHREN ZUR DARSTELLUNG VON HYDROCARBYL-BIS-（HYDROCARBYLPHOSPHAT）
公开(公告)号：EP0789703A4
公开(公告)日：1998-02-25
申请号：EP95937516
申请日：1995-10-20
申请人： AKZO NOBEL NV , BRIGHT DANIELLE A , PIRRELLI RONALD L
发明人： BRIGHT DANIELLE A , PIRRELLI RONALD L
IPC分类号： C07F9/09 , C07F9/12
CPC分类号： C07F9/093 , C07F9/12
摘要： A process for the synthesis of a hydrocarbyl bis(dihydrocarbyl phosphate), such as a hydrocarbyl bis(diaryl phosphate), comprises the reaction of an unstable hydrocarbyl-containing diol, such as an aromatic group-containing diol, with a dihydrocarbyl halophosphate, such as diphenyl chlorophosphate, in the presence of a Lewis acid catalyst, such as magnesium dichloride, in the additional presence of an effective amount (e.g., up to about 100 % by weight of diol and halophosphate) of a liquid hydrocarbon, such as an aliphatic hydrocarbon, like heptane, or an aromatic hydrocarbon, such as toluene, to enhance the removal of hydrogen halide by-product and thereby increase the yield of hydrocarbyl bis(dihydrocarbyl phosphate).
摘要翻译：合成烃基双（二烃基磷酸酯）例如烃基双（二芳基磷酸酯）的方法包括使不稳定的含烃基二醇如含芳族基团的二醇与卤代磷酸二烃基酯反应，例如作为氯代磷酸二苯酯，在路易斯酸催化剂例如二氯化镁的存在下，在另外存在有效量（例如至多约100重量％的二醇和卤代磷酸盐）的液态烃例如脂族烃如庚烷或芳烃如甲苯，以增强卤化氢副产物的除去，从而提高烃基双（二烃基磷酸酯）的产率。

10. 发明公开

EP0796293A1 HYDROXY-TERMINATED AROMATIC OLIGOMERIC PHOSPHATE AS ADDITIVE FLAME RETARDANT IN POLYCARBONATE RESIN COMPOSITION 失效
标题翻译：低聚的，芳族磷酸酯羟基比在阻燃添加剂的聚碳酸酯树脂组合物
公开(公告)号：EP0796293A1
公开(公告)日：1997-09-24
申请号：EP95942594.0
申请日：1995-12-06
申请人： Akzo Nobel N.V. , Bright, Danielle A. , Moy, Paul Y.
发明人： BRIGHT, Danielle, A. , MOY, Paul, Y.
IPC分类号： C08K5 , C08L55 , C08L69
CPC分类号： C08K5/523 , C08L69/00
摘要： The present application relates to a flame retarded polycarbonate resin composition which comprises a polycarbonate resin substrate containing an effective amount (e.g., preferably from about 5 % to about 15 %, by weight of the resin substrate) for flame retardancy of a hydroxy-terminated aromatic oligomeric phosphate composition of formula (I), where R is a hydrocarbyl group derived from an aliphatic or aromatic diol, Ar is an alkyl-substituted or unsubstituted phenyl group, n is from about 0 to about 10, and the phosphate composition contains a predominant amount of phosphate where n ranges from 0 to 1.

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