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    • 3. 发明授权
    • Nontoxic chemical process for in situ permeability enhancement and
accelerated decontamination of fine-grain subsurface sediments
    • 无毒化学工艺,用于原位渗透率增强和加速细颗粒地下沉积物的去污
    • US5593248A
    • 1997-01-14
    • US495294
    • 1995-06-27
    • Edward J. KansaAnanda M. WijesingheBrian E. Viani
    • Edward J. KansaAnanda M. WijesingheBrian E. Viani
    • B09C1/00B09C1/02E02D3/10E21B43/40B09C1/08
    • B09C1/02B09C1/00E02D3/10E21B43/40B09C2101/00
    • The remediation of heterogeneous subsurfaces is extremely time consuming and expensive with current and developing technologies. Although such technologies can adequately remove contaminants in the high hydraulic conductivity, coarse-grained sediments, they cannot access the contaminated low hydraulic conductivity fine-grained sediments. The slow bleed of contaminants from the fine-grained sediments is the primary reason why subsurface remediation is so time-consuming and expensive. This invention addresses the problem of remediating contaminated fine-grained sediments. It is intended that, in the future, a heterogeneous site be treated by a hybrid process that first remediates the high hydraulic conductivity, coarse-grained sediments, to be followed by the process, described in this invention, to treat the contaminated low hydraulic conductivity fine-grained sediments. The invention uses cationic flocculents and organic solvents to collapse the swelling negative double layer surrounding water saturated clay particles, causing a flocculated, cracked clay structure. The modification of the clay fabric in fine-grained sediments dramatically increases the hydraulic conductivity of previously very tight clays many orders of magnitude.
    • 异构亚表面的修复对于当前和开发的技术来说非常耗时且昂贵。 虽然这些技术可以充分去除高水力传导性的污染物,但是粗粒沉积物,它们不能进入被污染的低水力传导性细粒沉积物。 来自细粒沉积物的污染物的缓慢渗出是地下修复如此耗时和昂贵的主要原因。 本发明解决了污染细粒沉积物的补救问题。 目的在于,将来通过混合过程来处理异质场地,该混合过程首先弥补本发明所述的方法所遵循的高水力传导性,粗粒沉积物,以处理污染的低水力传导性 细粒沉积物。 本发明使用阳离子絮凝剂和有机溶剂使周围水饱和粘土颗粒的膨胀负双层塌陷,引起絮凝,破裂的粘土结构。 细粒沉积物中粘土织物的改性显着提高了以前非常紧密粘土的水力传导性,其数量级很多。