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1. 发明授权

US6054617A Nitro compound-reducing process 失效
标题翻译：硝基化合物还原过程
公开(公告)号：US6054617A
公开(公告)日：2000-04-25
申请号：US11677
申请日：1998-05-22
申请人： Helmut Bahrmann , Boy Cornils , Andreas Dierdorf , Steffen Haber
发明人： Helmut Bahrmann , Boy Cornils , Andreas Dierdorf , Steffen Haber
IPC分类号： B01J31/24 , C07B61/00 , C07C209/36 , C07C211/45 , C07C211/46 , C07C211/52 , C07C213/02 , C07C215/76 , C07C217/84 , C07C209/32
CPC分类号： C07C209/36 , C07C209/365 , C07C213/02
摘要： The invention concerns a process for the reduction of nitro groups to amino groups, characterized that a nitro compound is reacted with hydrogen in the presence of an aqueous solution of a water-soluble metal catalyst of the formula M (L).sub.n (Y).sub.m wherein M is ruthenium, rhodium, nickel, or palladium; L, is a water soluble ligand; Y is a further ligand or an alkaline earth ion; n is 1, 2, 3, or 4; and m is 0, 1, or 2.
摘要翻译： PCT No.PCT / EP96 / 03415 Sec。 371日期1998年5月23日 102（e）日期1998年5月23日PCT提交1996年8月2日PCT公布。出版物WO97 / 07087 日期：1997年2月27日本发明涉及将硝基还原成氨基的方法，其特征在于硝基化合物与式（M）的水溶性金属催化剂水溶液的存在下，与氢反应， n（Y）m其中M为钌，铑，镍或钯; L，是水溶性配体; Y是另一种配体或碱土金属离子; n为1,2,3或4; m为0,1或2。

2. 发明授权

US5091350A Process for hydroformylation with rhodium catalysts and the separation of rhodium therefrom 失效
标题翻译：用氢氧化镁催化剂进行氢化处理和其分离
公开(公告)号：US5091350A
公开(公告)日：1992-02-25
申请号：US605939
申请日：1990-10-29
申请人： Boy Cornils , Werner Konkol , Helmut Bahrmann , Hanswilhelm Bach , Ernest Wiebus , Wolfgang Lipps
发明人： Boy Cornils , Werner Konkol , Helmut Bahrmann , Hanswilhelm Bach , Ernest Wiebus , Wolfgang Lipps
IPC分类号： B01J23/96 , B01J31/40 , C01G55/00 , C07C45/50 , C07C45/80 , C07C45/85 , C22B3/38 , C22B7/00 , B01J38/68 , C22B11/04
CPC分类号： C22B11/048 , B01J31/2404 , B01J31/4046 , C01G55/001 , C07C45/50 , C07C45/80 , C07C45/85 , C22B3/0051 , C22B7/009 , B01J2231/321 , B01J23/464 , B01J2531/822 , Y02P10/214 , Y02P10/234 , Y02P20/584
摘要： A process for separating rhodium from mixtures thereof, comprising extracting said rhodium with an aqueous solution of a rhodium complexing agent and a solubilizer. A process for preparing aldehydes in the presence of both the complexing agent and the solubilizer is also set forth. The solubilizer is generally selected from salts of carboxylic acids having 8-20 carbon atoms, alkyl sulfonates, alkyl aryl sulfonates, amines and quaternary ammonium compounds of Formula II ##STR1## wherein A is alkyl, alkoxy, hydroxyalkyl, aryl having 6-25 carbon atoms, or R.sup.7 CONHCH.sub.2 CH.sub.2 CH.sub.2 --wherein R.sup.7 is alkyl having 5-11 carbon atoms; B is an alkyl having 1-25 carbon atoms, an aryl having 6-25 carbon atoms, or an .omega.-hydroxy alkyl having 1-4 carbon atoms; C and D are each independently an alkyl or .omega.-hydroxy alkyl having 1-4 carbon atoms or form, together with each other and the bridging N, a 5 or 6 membered heterocyclic ring; E is a halide, sulfate, borate, sulfonate, lactate or citrate; and p is the number of charges on E. The rhodium complexing agent is preferably a triaryl phosphine carboxylate or sulfonate.
摘要翻译：一种从其混合物中分离铑的方法，包括用铑络合剂和增溶剂的水溶液萃取所述铑。还阐述了在络合剂和增溶剂存在下制备醛的方法。增溶剂通常选自具有8-20个碳原子的羧酸盐，烷基磺酸盐，烷基芳基磺酸盐，胺和季铵化合物，其中A是烷基，烷氧基，羟基烷基，具有6-25个碳原子或R7CONHCH2CH2CH2-，其中R7是具有5-11个碳原子的烷基; B是具有1-25个碳原子的烷基，具有6-25个碳原子的芳基，或具有1-4个碳原子的ω-羟基烷基; C和D各自独立地为具有1-4个碳原子的烷基或ω-羟基烷基，或彼此形成桥连N和5或6元杂环; E是卤化物，硫酸盐，硼酸盐，磺酸盐，乳酸盐或柠檬酸盐; 并且p是E上的电荷数。铑络合剂优选为三芳基膦羧酸盐或磺酸盐。

3. 发明授权

US4673535A Quaternary ammonium salts of sulfonated triarylphosphines and process for the production thereof 失效
标题翻译：磺化三芳基膦的季铵盐及其制备方法
公开(公告)号：US4673535A
公开(公告)日：1987-06-16
申请号：US738868
申请日：1985-05-29
申请人： Helmut Bahrmann , Boy Cornils , Wolfgang Lipps , Peter Lappe , Helmut Springer
发明人： Helmut Bahrmann , Boy Cornils , Wolfgang Lipps , Peter Lappe , Helmut Springer
IPC分类号： B01J31/24 , C07F9/50 , C07C87/30
CPC分类号： C07F9/5022
摘要： The invention relates to new quaternary ammonium salts of di and trisulfonated triarylphosphines as well as a process for their preparation. The salts are of Formula I ##STR1## wherein Ar.sub.1, Ar.sub.2, and Ar.sub.3 are each independently an aryl; X.sup.1, X.sup.2, and X.sup.3 are each independently a sulfo group; y.sup.1, y.sup.2, and y.sup.3 are each independently 0 or 1, provided that their sum is at least 1; A is an alkyl, hydroxyalkyl, aralkyl, or aryl having 6-25 carbon atoms; B, C, and D are straight chain or branched alkyl having 1-4 carbons; and n is a whole number of 1-3.
摘要翻译：本发明涉及二和三磺化三芳基膦的新季铵盐及其制备方法。该盐具有式I的化合物，其中Ar 1，Ar 2和Ar 3各自独立地为芳基; X 1，X 2和X 3各自独立地为磺基; y1，y2和y3各自独立地为0或1，条件是它们的和为至少1; A是具有6-25个碳原子的烷基，羟基烷基，芳烷基或芳基; B，C和D是具有1-4个碳的直链或支链烷基; n为1-3的整数。

4. 发明授权

US4623490A Process for the purification of sulfonated aryl phosphines 失效
标题翻译：磺化芳基膦的纯化方法
公开(公告)号：US4623490A
公开(公告)日：1986-11-18
申请号：US770303
申请日：1985-08-27
申请人： Ludger Bexten , Boy Cornils , Dieter Kupies
发明人： Ludger Bexten , Boy Cornils , Dieter Kupies
IPC分类号： B01J38/00 , C07F9/50 , C07F15/00 , C07C143/24
CPC分类号： C07F9/5095 , C07F9/5054
摘要： A process for the purification of salts of at least one member of the group consisting of diphenylphosphine-phenyl-m-sulfonic acid, phenylphosphine-di-(m-phenylsulfonic acid) and triphenylphosphine-tri-(m-sulfonic acid) from aqueous solutions thereof comprising adding at least a molar equivalent amount of at least one member of the group consisting of di-(n-pentyl)-amine, di-(n-hexyl)-amine and water-soluble salts of said amines to an aqueous solution containing at least one member of the group consisting diphenylphosphine-phenyl-m-sulfonic acid, phenylphosphine-di-(m-phenylsulfonic acid), triphenylphosphine-tri(m-sulfonic acid) and salts thereof to adjust the pH value to .ltoreq.7, recovering the precipitate, washing the precipitate and dissolving the same in an aqueous basic solution.
摘要翻译：从水溶液中纯化二苯基膦 - 苯基间磺酸，苯基膦 - 二 - （间苯磺酸）和三苯基膦 - 三 - （间 - 磺酸）中的至少一种成员的盐的方法其包括将至少一种摩尔当量的所述胺的二（正戊基） - 胺，二 - （正己基） - 胺和水溶性盐组成的组中的至少一种添加到水溶液中含有二苯基膦 - 苯基 - 间磺酸，苯基膦 - 二 - （间苯磺酸），三苯基膦 - 三（m-磺酸）及其盐中的至少一个成员以将pH值调节至< 7，回收沉淀物，洗涤沉淀物并将其溶于碱性水溶液中。

5. 发明授权

US4551328A Selectively absorbent layer for solar collectors, and method of making it 失效
标题翻译：用于太阳能集热器的选择性吸收层及其制造方法
公开(公告)号：US4551328A
公开(公告)日：1985-11-05
申请号：US496383
申请日：1983-05-20
申请人： Edwin Erben , August Muhlratzer , Roland Bertinger , Boy Cornils , Bela Tihanyi , Werner DeWin
发明人： Edwin Erben , August Muhlratzer , Roland Bertinger , Boy Cornils , Bela Tihanyi , Werner DeWin
IPC分类号： C01G37/02 , F24J2/48 , C23C11/08
CPC分类号： C01G37/02 , F24J2/487 , C01P2004/62 , C01P2004/80 , C01P2006/60 , Y02E10/40
摘要： A selectively absorbent layer for solar collectors, comprising a mixture of chromium oxides resulting from thermal decomposition of chromium hexacarbonyl or substituted chromium carbonyl. The absorbent layer is deposited from a process gas containing the carbonyl gaseous phase, oxygen, and inert carrier gas. An intermediate reflective layer is provided between the absorbent layer and the substrate.
摘要翻译：一种用于太阳能收集器的选择性吸收层，包括由六羰基铬或取代的铬羰基的热分解产生的铬氧化物的混合物。吸收层由含有羰基气相，氧气和惰性载气的工艺气体沉积。在吸收层和基底之间设置中间反射层。

6. 发明授权

US4504588A Process for the recovery of water-soluble hydroformylation catalysts containing rhodium 失效
标题翻译：用于回收含有铑的水溶性加氢甲酰化催化剂的方法
公开(公告)号：US4504588A
公开(公告)日：1985-03-12
申请号：US534088
申请日：1983-09-20
申请人： Roderich Gartner , Boy Cornils , Ludger Bexten , Dieter Kupies
发明人： Roderich Gartner , Boy Cornils , Ludger Bexten , Dieter Kupies
IPC分类号： B01J23/96 , B01J23/90 , B01J31/40 , B01J38/00 , C07C45/00 , C07C45/50 , C07C67/00
CPC分类号： B01J31/2404 , B01J31/26 , B01J31/4046 , B01J2231/321 , B01J2531/822 , B01J2531/96 , B01J31/0235
摘要： To recover a hydroformylation catalyst system containing rhodium and phosphine, the aqueous solution containing the catalyst system is mixed with acid and then extracted with an amine which is dissolved in an organic solvent. The organic phase is separated and treated with the aqueous solution of an inorganic base, thereby recovering the catalyst in essentially pure form as an aqueous solution.
摘要翻译：为了回收含有铑和膦的加氢甲酰化催化剂体系，将含有催化剂体系的水溶液与酸混合，然后用溶解在有机溶剂中的胺萃取。将有机相分离并用无机碱的水溶液处理，从而以基本上纯的形式作为水溶液回收催化剂。

7. 发明授权

US4483802A Process for the preparation of sulfonated aryl phosphine 失效
标题翻译：磺化芳基膦的制备方法
公开(公告)号：US4483802A
公开(公告)日：1984-11-20
申请号：US534089
申请日：1983-09-20
申请人： Roderich Gartner , Boy Cornils , Helmut Springer , Peter Lappe
发明人： Roderich Gartner , Boy Cornils , Helmut Springer , Peter Lappe
IPC分类号： C07F9/50 , C07C143/24
CPC分类号： C07F9/5054 , C07F9/5095
摘要： A process for the preparation of mono, di or trisulfonated aryl phosphines whereby triaryl phosphine is sulfonated with oleum at 0.degree. to 40.degree. C. After dilution of the reaction product with water, the sulfonated triaryl phosphine is extracted with an amine dissolved in an organic solvent; both the amine and organic solvent being insoluble in water. From the organic phase the sulfonated phosphine is transferred to the aqueous phase by treatment with an aqueous solution of a base.
摘要翻译：一种制备单，二或三磺化芳基膦的方法，其中三芳基膦在0-40℃下用发烟硫酸磺化。在用水稀释反应产物后，将磺化的三芳基膦用溶解在有机物中的胺萃取溶剂; 胺和有机溶剂都不溶于水。从有机相中，通过用碱的水溶液处理将磺化膦转移到水相中。

8. 发明授权

US4404410A Process for preparing 2,3-dimethyl-2,3-butanediol 失效
标题翻译：制备2,3-二甲基-2,3-丁二醇的方法
公开(公告)号：US4404410A
公开(公告)日：1983-09-13
申请号：US272229
申请日：1981-06-10
申请人： Boy Cornils , Jurgen Weber , Wolfgang Bernhagen , Helmut Springer
发明人： Boy Cornils , Jurgen Weber , Wolfgang Bernhagen , Helmut Springer
IPC分类号： B01J31/00 , C07B61/00 , C07C27/00 , C07C29/03 , C07C31/20 , C07C67/00
CPC分类号： C07C29/03 , A24F2700/03
摘要： An improved process for the preparation of 2,3-dimethyl-2,3-butanediol is disclosed wherein hydrogen peroxide and 2,3-dimethylbutene are reacted with formic acid at 50.degree. to 70.degree. C. while stirring, the 2,3-dimethylbutene and hydrogen peroxide being introduced into the formic acid simultaneously but separately. The diol can be obtained by hydrolysis of the pinacol monoformate formed.
摘要翻译：公开了一种制备2,3-二甲基-2,3-丁二醇的改进方法，其中过氧化氢和2,3-二甲基丁烯在50℃至70℃下与甲酸反应同时搅拌，二甲基丁烯和过氧化氢同时引入甲酸，但分开。二醇可以通过水解形成的频哪醇单甲酸酯来获得。

9. 发明授权

US4289913A Process for preparing 3-(4)-formyltricyclo-[5,2,1,0.sup.2,6 ]-decene-8 失效
标题翻译：制备3-（4） - 甲酰基三环[5,2,1,02,6] - 癸烯-8的方法
公开(公告)号：US4289913A
公开(公告)日：1981-09-15
申请号：US099121
申请日：1979-11-30
申请人： Helmut Bahrmann , Jurgen Weber , Boy Cornils
发明人： Helmut Bahrmann , Jurgen Weber , Boy Cornils
IPC分类号： C07C47/445 , B01J31/00 , C07B61/00 , C07C45/00 , C07C45/50 , C07C67/00
CPC分类号： C07C45/50
摘要： A process for preparing 3- or 4-formyltricyclo-[5,2,1,0.sup.2,6 ]-decene-8 which comprises contacting dicyclopentadiene with carbon monoxide and hydrogen in the presence of a rhodium catalyst at 110.degree. to 150.degree. C. and 50 to 400 atmospheres, said catalyst being present in an amount of 1 to 30 ppm of rhodium, based upon the amount of dicyclopentadiene employed, said rhodium being present in the form of an organic phosphine-carbon monoxide containing complex.
摘要翻译：制备3-或4-甲酰基三环[5,2,1,02,6] - 十一烯-8的方法，其包括在铑催化剂存在下，在110-150℃下使二环戊二烯与一氧化碳和氢气接触。和50至400个大气压，所述催化剂以1至30ppm的铑的量存在，基于所用的二环戊二烯的量，所述铑以有机膦 - 一氧化碳的络合物的形式存在。

10. 发明授权

US4172091A Process for the manufacture of .beta.-(dimethylamino)-propionitrile 失效
标题翻译：制备{62 - （二甲基氨基） - 丙腈的方法
公开(公告)号：US4172091A
公开(公告)日：1979-10-23
申请号：US883757
申请日：1978-03-06
申请人： Jurgen Weber , Helmut Springer , Boy Cornils , Hans Feichtinger , Wolfgang Payer
发明人： Jurgen Weber , Helmut Springer , Boy Cornils , Hans Feichtinger , Wolfgang Payer
IPC分类号： C07C255/24 , C07C20060101 , C07C67/00 , C07C253/00 , C08F20060101 , C11D20060101 , C07C120/00 , C07C121/43
CPC分类号： C07C253/30
摘要： An improvement in a process for the manufacture of .beta.-(dimethylamino)-propionitrile by contacting acrylonitrile with dimethylamine, the improvement residing in passing the reactants in countercurrent with respect to one another in a bubble column reactor and reacting them therein at a temperature between 25.degree. and 80.degree. C., preferably 40.degree. to 60.degree. C.
摘要翻译：通过使丙烯腈与二甲胺接触制备β-（二甲基氨基） - 丙腈的方法的改进，其改进在气泡塔型反应器中使反应物相对于彼此逆流通过，并使其在25℃ DEG和80℃，优选40℃至60℃。

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