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    • 4. 发明申请
    • Composition of acryl-silicone complex, preparing method and use thereof
    • 丙烯酸 - 硅氧烷配合物的组成,其制备方法和用途
    • US20070100073A1
    • 2007-05-03
    • US11549214
    • 2006-10-13
    • Kwang-jin LEEJeong-heon AHNHye-kyong LEEBoo-ho SEOJi-min LEE
    • Kwang-jin LEEJeong-heon AHNHye-kyong LEEBoo-ho SEOJi-min LEE
    • C08F30/08C08G77/20
    • C08F265/04C08F257/02C08F265/06C08F283/00C08F283/12C08F285/00C08G77/442C08L51/04C08L51/08Y10S525/902Y10S525/903C08L2666/04C08L2666/02
    • The present invention relates to an acryl-silicon rubber complex polymer and a method for the preparation and use of the same. More precisely, the present invention relates to an acryl-silicon rubber complex polymer which has a seed-core-shell structure wherein the vinyl monomer and hydrophilic monomer are cross-linked on the seed; the acryl-silicon complex IPN core having an IPN (interpenetrating network) structure in which silicon rubber particles are dispersed by being cross-linked to acryl rubber, in a continuous phase, is formed on the seed; and a shell prepared by graft-polymerization of C1˜C4 alkyl methacrylate to the acryl-silicon complex IPN core is formed on the core, and a method of preparation and use of the same. The acryl-silicon rubber complex polymer of the present invention has excellent impact resistance, weatherability and gloss, so that it can be effectively used as an impact modifier for vinyl chloride resin. The acryl-silicon complex IPN core has an IPN (interpenetrating network) structure formed by radical polymerization of acryl monomer and hydrosilyation of silicon rubber.
    • 本发明涉及丙烯酸硅橡胶复合聚合物及其制备和使用方法。 更准确地说,本发明涉及一种具有种核 - 壳结构的丙烯酰硅橡胶复合聚合物,其中乙烯基单体和亲水单体在种子上交联; 在种子上形成具有IPN(互穿网络)结构的丙烯酸 - 硅复合物IPN芯,其中硅橡胶颗粒通过与丙烯酸橡胶交联而分散在其中; 并且在芯上形成通过将C1-C4烷基甲基丙烯酸酯接枝到丙烯酸 - 硅复合物IPN芯上而制备的壳及其制备和使用方法。 本发明的丙烯酸 - 硅橡胶复合聚合物具有优异的耐冲击性,耐候性和光泽,因此可有效地用作氯乙烯树脂的抗冲击改性剂。 丙烯酸 - 硅复合物IPN芯具有通过丙烯酸单体的自由基聚合和硅橡胶的氢化作用形成的IPN(互穿网络)结构。