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1. 发明授权

US07137423B2 Tire with component comprised of amine functionalized styrene/diene copolymer elastomer, silanol functionalized carbon black and coupling agent 失效
标题翻译：具有胺官能化苯乙烯/二烯共聚物弹性体，硅烷醇官能化炭黑和偶联剂的组分的轮胎
公开(公告)号：US07137423B2
公开(公告)日：2006-11-21
申请号：US10457084
申请日：2003-06-06
申请人： Paul Harry Sandstrom , John Joseph Andre Verthe , Raymond Robert DiRossi , Bill Bud Gross
发明人： Paul Harry Sandstrom , John Joseph Andre Verthe , Raymond Robert DiRossi , Bill Bud Gross
IPC分类号： B60C11/00
CPC分类号： C08L19/006 , B60C1/0016 , C08C19/22 , C08K9/02 , C08L9/06 , C08L21/00 , C08L2666/08
摘要： The invention relates to a tire having at least one component (e.g. tread) of a rubber composition comprised of an amine functionalized styrene/conjugated diene copolymer elastomer (e.g. styrene/butadiene and/or styrene/isoprene/butadiene copolymer elastomer) which contains reinforcement comprised of silanol functionalized particulate carbon black having silica domains covering a fraction of the carbon black surface together with an alkoxysilane polysulfide coupling agent. The silica domains on the carbon black surface contain hydroxyl groups (e.g. silanol groups) on their surfaces which are reactive with the alkoxysilane moiety of the coupling agent. The amine functionalized styrene/butadiene elastomer is an organic solution polymerization prepared elastomer which contains pendant and/or terminal amine groups as one or more of primary amine, secondary amine, tertiary amine, and/or heterocyclic amine groups. The amine functionalized elastomer may be tin coupled.
摘要翻译：本发明涉及一种轮胎，该轮胎具有由胺官能化苯乙烯/共轭二烯共聚物弹性体（例如苯乙烯/丁二烯和/或苯乙烯/异戊二烯/丁二烯共聚物弹性体）组成的橡胶组合物的至少一种组分（例如胎面）的硅烷醇官能化颗粒炭黑，其具有覆盖碳黑表面的一部分的二氧化硅域和烷氧基硅烷多硫偶联剂。碳黑表面上的二氧化硅结构域在其表面上含有与偶联剂的烷氧基硅烷部分反应的羟基（例如硅烷醇基）。胺官能化苯乙烯/丁二烯弹性体是含有作为伯胺，仲胺，叔胺和/或杂环胺基团中的一个或多个的侧基和/或末端胺基团的有机溶液聚合制备的弹性体。胺官能化的弹性体可以是锡偶合的。

2. 发明授权

US06720033B1 Method for coating uncured tires 有权
标题翻译：未固化轮胎涂层方法
公开(公告)号：US06720033B1
公开(公告)日：2004-04-13
申请号：US10299448
申请日：2002-11-19
申请人： Paul Harry Sandstrom , Bill Bud Gross , Douglas Andrew Till
发明人： Paul Harry Sandstrom , Bill Bud Gross , Douglas Andrew Till
IPC分类号： B05D302
CPC分类号： B29D30/0662 , B05D3/0254 , B05D7/02 , B29C37/0025 , B29C37/0067
摘要： A method of coating a tire, comprising the steps of applying to an outer surface of a green tire: a precure paint essentially free of curatives, the precure paint comprising 100 parts by weight of elastomer, and from about 2000 to about 4000 parts by weight of an organic solvent.
摘要翻译：一种涂覆轮胎的方法，包括以下步骤：施加到生轮胎的外表面：基本上不含固化剂的预固化涂料，所述预固化涂料包含100重量份的弹性体和约2000至约4000重量份的有机溶剂。

3. 发明授权

US5679751A Solution polymerization process for synthesis of styrene-butadiene or styrene-isoprene rubber 失效
标题翻译：用于合成苯乙烯 - 丁二烯或苯乙烯 - 异戊二烯橡胶的溶液聚合方法
公开(公告)号：US5679751A
公开(公告)日：1997-10-21
申请号：US599542
申请日：1996-02-12
申请人： Adel Farhan Halasa , Laurie Elizabeth Austin , Wen-Liang Hsu , Bill Bud Gross
发明人： Adel Farhan Halasa , Laurie Elizabeth Austin , Wen-Liang Hsu , Bill Bud Gross
IPC分类号： B60C1/00 , C08F4/46 , C08F4/48 , C08F236/10
CPC分类号： B60C1/0016 , C08F236/10
摘要： The subject invention relates to a technique for synthesizing rubbery copolymers of styrene and butadiene and/or isoprene. These rubbers exhibit an excellent combination of properties for utilization in high performance tire tread rubber compounds. The subject invention specifically discloses a process for preparing a styrene-butadiene rubber (SBR) which comprises: copolymerizing from about 30 weight percent to about 55 weight percent styrene and from about 45 weight percent to about 70 weight percent 1,3-butadiene in an alkane solvent, such as hexane, at a temperature which is within the range of about -10.degree. C. to about 150.degree. C. in the presence of (a) an alkali metal alkoxide, and (b) an organolithium compound, wherein the molar ratio of the alkali metal alkoxide to the organolithium compound is within the range of about 0.01:1 to about 1:1. The subject invention further discloses a process for preparing a rubbery copolymer of styrene and isoprene having an excellent combination of properties for use in making tire treads by a solution polymerization process which comprises: copolymerizing from about 30 weight percent to about 55 weight percent styrene and from about 45 weight percent to about 70 weight percent isoprene in an alkane solvent at a temperature which is within the range of about -10.degree. C. to about 150.degree. C. in the presence of (a) an alkali metal alkoxide, and (b) an organolithium compound, wherein the molar ratio of the alkali metal alkoxide to the organolithium compound is within the range of about 0.01:1 to about 1:1.
摘要翻译：本发明涉及一种合成苯乙烯和丁二烯和/或异戊二烯橡胶共聚物的技术。这些橡胶在高性能轮胎胎面橡胶化合物中表现出优异的性能组合。本发明具体公开了一种制备苯乙烯 - 丁二烯橡胶（SBR）的方法，其包括：以约30重量％至约55重量％的苯乙烯和约45重量％至约70重量％的1,3-丁二烯的共聚合烷烃溶剂如己烷，在（a）碱金属醇盐存在下，在约-10℃至约150℃的温度范围内，和（b）有机锂化合物，其中，碱金属醇盐与有机锂化合物的摩尔比在约0.01:1至约1:1的范围内。本发明进一步公开了一种制备苯乙烯和异戊二烯的橡胶共聚物的方法，其具有通过溶液聚合方法制备轮胎胎面的优异的性能组合，其包括：共聚约30重量％至约55重量％的苯乙烯和在（a）碱金属醇盐存在下，在约-10℃至约150℃的温度下，在烷烃溶剂中约45重量％至约70重量％的异戊二烯，和（b ）有机锂化合物，其中碱金属醇盐与有机锂化合物的摩尔比在约0.01:1至约1:1的范围内。

4. 发明授权

US06913329B1 Endless rubber track having guide lugs with guide lug support layer, and vehicle containing such track 失效
标题翻译：无端橡胶履带具有带引导支撑层的导向凸耳，以及包含该轨道的车辆
公开(公告)号：US06913329B1
公开(公告)日：2005-07-05
申请号：US09685372
申请日：2000-10-10
申请人： Michael Brendan Rodgers , Ram Murthy Krishnan , Ray Eugene Beery , Paul Harry Sandstrom , Bill Bud Gross , Lewis Timothy Lukich
发明人： Michael Brendan Rodgers , Ram Murthy Krishnan , Ray Eugene Beery , Paul Harry Sandstrom , Bill Bud Gross , Lewis Timothy Lukich
IPC分类号： B62D55/24 , B60D55/205
CPC分类号： B62D55/24 , B62D55/244
摘要： The invention relates to an endless vehicular rubber track. The invention particularly relates to such track having hard rubber guide lugs with a softer guide support layer. It is to be appreciated that such guide lugs may also be positively driven drive lugs. The invention further relates to a vehicle having such track.
摘要翻译：本发明涉及无端车辆橡胶履带。本发明特别涉及具有较硬导向支撑层的硬橡胶导引凸耳的这种轨道。应当理解，这种引导凸耳也可以是主动驱动的驱动凸耳。本发明还涉及具有这种轨道的车辆。

5. 发明授权

US5922153A Tire innerliner composition 失效
标题翻译：轮胎内衬组成
公开(公告)号：US5922153A
公开(公告)日：1999-07-13
申请号：US12288
申请日：1998-01-23
申请人： Roger Neil Beers , David Andrew Benko , Bill Bud Gross , Adel Farhan Halasa
发明人： Roger Neil Beers , David Andrew Benko , Bill Bud Gross , Adel Farhan Halasa
IPC分类号： B60C1/00 , C08L23/28 , C08L53/00 , B60C5/14
CPC分类号： B60C1/0008 , C08L23/283 , C08L53/00 , Y10S152/16
摘要： A halobutyl rubber is generally used in the innerliner of pneumatic tires to retard the escape of air used to inflate the tire, thereby maintaining tire pressure. Since halobutyl rubbers, such as bromobutyl rubber, are generally the most expensive elastomers used in tires, it is desirable from a standpoint of cost reduction to reduce the level of halobutyl rubbers used in tires. The present invention relates to a technique for reducing the quantity of halobutyl rubber utilized in the innerliner of tubeless pneumatic vehicle tires. The present invention more specifically relates to a tire innerliner and pneumatic tires containing the same, which are prepared from a composition comprising, based on 100 parts by weight of rubber, a blend of (1) about 50 parts to about 90 parts of a halobutyl rubber and (2) about 10 parts to about 50 parts of a styrene-isoprene-butadiene terpolymer rubber having a first glass transition temperature which is within the range of about -110.degree. C. to about -20.degree. C. and a second glass transition temperature which is within the range of about -50.degree. C. to about 0.degree. C., wherein said styrene-isoprene-butadiene terpolymer rubber contains about 20 weight percent to about 40 weight percent bound styrene.
摘要翻译：通常，在充气轮胎的内衬层中使用卤代丁基橡胶，以阻止用于使轮胎充气的空气的逸出，从而保持轮胎压力。由于卤代丁基橡胶（例如溴丁基橡胶）通常是轮胎中使用的最昂贵的弹性体，因此从成本降低的观点来看，期望降低轮胎中使用的卤代丁基橡胶的含量。本发明涉及减少无内胎气动车辆轮胎的内衬中使用的卤代丁基橡胶的量的技术。本发明更具体地涉及一种包含其的轮胎内衬和充气轮胎，其由基于100重量份橡胶的组合物制备，（1）约50重量份至约90重量份的卤代丁基橡胶和（2）约10份至约50份第一玻璃化转变温度在约-110℃至约-20℃范围内的苯乙烯 - 异戊二烯 - 丁二烯三元共聚物橡胶和第二玻璃转化温度在约-50℃至约0℃的范围内，其中所述苯乙烯 - 异戊二烯 - 丁二烯三元共聚物橡胶含有约20重量％至约40重量％的结合苯乙烯。

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