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    • 6. 发明申请
    • ELECTRODE MATERIALS AND PROCESS FOR PRODUCING THEM
    • 电极材料及其生产工艺
    • US20120205594A1
    • 2012-08-16
    • US13396112
    • 2012-02-14
    • Robert BAYERBastian EWALDJordan Keith LAMPERTSimon SCHRÖEDLE
    • Robert BAYERBastian EWALDJordan Keith LAMPERTSimon SCHRÖEDLE
    • H01B1/18B82Y30/00
    • B82Y30/00H01B1/18
    • Process for producing electrode materials, wherein (a) (A) at least one iron compound in which Fe is present in the oxidation state +2 or +3, (B) at least one phosphorus compound, (C) at least one lithium compound, (D) at least one carbon source which can be a separate carbon source or at the same time at least one iron compound (A) or phosphorus compound (B) or lithium compound (C), (E) optionally at least one reducing agent, (F) optionally at least one further metal compound which has a metal other than iron, (G) optionally water or at least one organic solvent, are mixed with one another, (b) spray dried together by means of at least one apparatus which employs at least one spray nozzle for spraying and (c) thermally treated at temperatures in the range from 350 to 1200° C.
    • 制备电极材料的方法,其中(a)(A)至少一种Fe以氧化态+2或+3存在的铁化合物,(B)至少一种磷化合物,(C)至少一种锂化合物 ,(D)至少一个碳源,其可以是单独的碳源,或同时至少一种铁化合物(A)或磷化合物(B)或锂化合物(C),(E),任选地至少一种还原 试剂,(F)任选地至少一种另外的金属化合物,其具有除铁以外的金属,(G)任选的水或至少一种有机溶剂,彼此混合,(b)通过至少一种 使用至少一个用于喷射的喷嘴的设备,(c)在350-1200℃的温度下进行热处理。
    • 8. 发明申请
    • PROCESS FOR PRODUCING A CATALYST AND CATALYST
    • 生产催化剂和催化剂的方法
    • US20110195347A1
    • 2011-08-11
    • US13021242
    • 2011-02-04
    • Claudia QuernerEkkehard SchwabBastian Ewald
    • Claudia QuernerEkkehard SchwabBastian Ewald
    • H01M4/96B01J27/22
    • H01M4/8846H01M4/8657H01M4/8885H01M4/92H01M4/921H01M4/926
    • The invention relates to a process for producing a catalyst, where the catalyst comprises a catalytically active material and a carbon-comprising support, in which the carbon-comprising support is impregnated with a metal salt solution in a first step, the carbon-comprising support impregnated with the metal salt solution is subsequently heated to a temperature of at least 1500° C. in an inert atmosphere to form a metal carbide layer and the catalytically active material is finally applied to the carbon-comprising support provided with the metal carbide layer. The invention further provides a catalyst which has been produced by the process and comprises a carbon-comprising support and a catalytically active material, with the carbon-comprising support having a metal carbide layer and the catalytically active material having been applied to the carbon-comprising support provided with the metal carbide layer.
    • 本发明涉及一种生产催化剂的方法,其中催化剂包含催化活性材料和含碳载体,其中在第一步骤中用金属盐溶液浸渍含碳载体,含碳载体 随后将金属盐溶液浸渍的金属盐溶液在惰性气氛中加热到至少1500℃的温度以形成金属碳化物层,并且最终将催化活性材料施加到设置有金属碳化物层的含碳载体上。 本发明还提供了一种已经通过该方法生产并包含含碳载体和催化活性材料的催化剂,其中含碳载体具有金属碳化物层,催化活性材料已被应用于含碳的载体 支撑体设有金属碳化物层。
    • 10. 发明申请
    • USE OF EXPANDED GRAPHITE IN LITHIUM/SULPHUR BATTERIES
    • 在锂/硫电池中使用膨胀石墨
    • US20130164635A1
    • 2013-06-27
    • US13700696
    • 2011-05-26
    • Ruediger SchmidtAlexander PanchenkoBastian EwaldPhilip HanefeldSorin IvanoviciHelmut MoehwaldIgor P. Kovalev
    • Ruediger SchmidtAlexander PanchenkoBastian EwaldPhilip HanefeldSorin IvanoviciHelmut MoehwaldIgor P. Kovalev
    • H01M4/133
    • H01M4/133H01M4/0485H01M4/136H01M4/1397H01M4/38H01M4/621H01M4/625H01M10/052Y02E60/122
    • The present invention relates to a solid composite for use in the cathode of a lithium- sulphur electric current producing cell wherein the solid composite comprises 1 to 75 wt.-% of expanded graphite, 25 to 99 wt.-% of sulphur, 0 to 50 wt.-% of one or more further conductive agents other than expanded graphite, and 0 to 50 wt.-% one or more binder, based on the total amount of the solid composite, a lithium-sulphur electric current producing cell comprising (i) a cathode comprising the solid composite, (ii) an anode and (iii) an electrolyte interposed between said cathode and said anode, and a process for preparing the solid composite comprising the steps (I) preparing a slurry comprising sulphur, expanded graphite, and optionally further components in a liquid medium by dispersing the sulphur, the expanded graphite, and optionally the further components in the liquid medium; (H) casting the slurry provided in step (I) on a substrate or placing the slurry provided in step (I) into a mold; and (III) removing some or all of the liquid medium from the slurry cast in step (II) to form a solid composite.
    • 本发明涉及一种用于锂硫电流电池的阴极的固体复合材料,其中固体复合材料包含1至75重量%的膨胀石墨,25至99重量%的硫,0至 50重量%的膨胀石墨以外的一种或多种其它导电剂和0至50重量%的一种或多种粘合剂,基于固体复合材料的总量,锂 - 硫电流产生电池包含( i)包含固体复合材料的阴极,(ii)阳极和(iii)介于所述阴极和所述阳极之间的电解质,以及制备所述固体复合材料的方法,包括步骤(I)制备包含硫,膨胀石墨 ,以及任选地通过将硫,膨胀石墨和任选的其它组分分散在液体介质中的液体介质中的其它组分; (H)将步骤(I)中提供的浆料浇铸在基材上或将步骤(I)中提供的浆料放入模具中; 和(III)从步骤(II)中浇铸的浆料中除去一些或全部液体介质以形成固体复合材料。