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    • 3. 发明授权
    • Electrolysis apparatus
    • 电解器
    • US4056452A
    • 1977-11-01
    • US661788
    • 1976-02-26
    • Barrie C. Campbell
    • Barrie C. Campbell
    • C25B9/20C25B1/02C25B11/02
    • C25B9/206
    • Disclosed is an electrolyzer which includes a plurality of partitions, each of which are hollowed out on either side thereof, a plurality of substrates, each of which is disposed in the hollow of a different one of said partitions and each of which is corrugated on one side thereof, with the corrugated side coated with an anodic material, a plurality of solid polymer electrolyte membranes, one side of each of which is disposed in contact with the anodic material of a different one of said substrates, and a plurality of cathode plates composed of porous cathodic material, each of which is disposed in the other hollow of a different one of the partitions and is positioned in contact with the other side of a different one of the membranes. The partitions, substrates, membranes and cathode plates are secured together in a series relationship with the corrugated side of each substrate being held in contact with one side of a membrane and each cathode plate being held in contact with the other side of a corresponding membrane. Channels are formed in the corrugated side of the substrates to convey water to the grooves formed by the corrugations, and a conduit is formed to extend through the partitions to deliver water to the channels. Other channels are formed in the substrates to receive water and electrolysis products from the grooves and to deliver the water and products to a second conduit formed in the partitions. A third conduit is formed in the partitions to receive electrolysis products at the interfaces of the membranes and cathode plates. A direct current source supplies current to the substrates and cathode plates to cause an electrolytic reaction when water is supplied to the grooves of the corrugated sides of the substrates.
    • 4. 发明授权
    • Electrolyzer apparatus and electrode structure therefor
    • 电解器及其电极结构
    • US4210511A
    • 1980-07-01
    • US17681
    • 1979-03-08
    • Barrie C. CampbellHarold M. Simons
    • Barrie C. CampbellHarold M. Simons
    • C25B9/00C25B9/08C25B9/20C25B11/03C25B11/04
    • C25B9/206C25B11/03
    • Electrolysis apparatus and electrode structure comprising a solid polymer electrolyte membrane, a porous cathode plate, and a porous anode plate which is electrochemically compatible with the cathode, so that the anode plate and cathode plate are substantially immune from galvanic corrosion. The solid polymer electrolyte membrane is disposed between the anode plate and cathode plate, and means are provided for holding the anode and cathode plates in firm contact with the opposite sides, respectively, of the membrane. In an embodiment employing a plurality of sets of electrode structures means are provided for securing the anode plate, solid polymer electrolyte membranes, and cathode plate of each electrode structure in side-by-side relationship and to secure the respective electrode structures in spaced series arrangement, with a spacer plate positioned between the individual sets of spaced electrode structures. A series of grooves is provided between the anode plate and the plate in contact therewith. The grooves extend in generally parallel relationship across the interface of the anode plate and the other plate. Means are provided for supplying water to the mutually respective ends of the grooves associated with the anode plates and for withdrawing water and electrolysis products produced at the anode from the opposite ends of the grooves. A direct current source supplies current to the anode and cathode plates to cause an electrolytic reaction when water is supplied to the grooves. Water and electrolysis products are withdrawn from the cathode plates through an aligned bore extending through the electrode structures.
    • 电解装置和电极结构包括固体聚合物电解质膜,多孔阴极板和与阴极电化学相容的多孔阳极板,使得阳极板和阴极板基本上免受电镀腐蚀。 固体聚合物电解质膜设置在阳极板和阴极板之间,并且设置有用于将阳极和阴极板分别与膜的相对侧牢固接触的​​装置。 在采用多组电极结构的实施例中,提供了并排关系固定每个电极结构的阳极板,固体聚合物电解质膜和阴极板的装置,并将相应的电极结构固定成间隔开的串联布置 ,间隔板位于各组隔开的电极结构之间。 在阳极板和板之间设有一系列凹槽。 凹槽以大致平行的关系延伸穿过阳极板和另一个板的界面。 提供了用于将水供应到与阳极板相关联的槽的相应端部并且用于从槽的相对端抽出在阳极处产生的水和电解产物的装置。 当向槽提供水时,直流电源向阳极和阴极板提供电流以引起电解反应。 水和电解产物通过延伸穿过电极结构的对准的孔从阴极板中排出。
    • 6. 发明授权
    • Solid polymer electrolyte cell construction
    • 固体聚合物电解质电池结构
    • US4057479A
    • 1977-11-08
    • US661789
    • 1976-02-26
    • Barrie C. Campbell
    • Barrie C. Campbell
    • C25B1/10C25B9/08C25B11/10C25B1/02C25B9/00
    • C25B1/10C25B9/08Y02E60/366
    • A solid polymer electrolyte cell includes a solid polymer electrolyte membrane, an anode disposed on one side of and in contact with the membrane wherein the anode includes a substrate coated with lead dioxide and formed with one or more grooves therein, a cathode including a body of sintered nickel disposed on the other side of and in contact with the membrane, and a support structure corrugated on a surface portion thereof with such surface portion being in contact with the body of sintered nickel to maintain the body in contact with the membrane. With this construction, water may be supplied to the grooves in the anode to ultimately cause a reaction at the interface of the membrane and the cathode to product hydrogen gas.
    • 固体聚合物电解质电池包括固体聚合物电解质膜,设置在膜的一侧并与膜接触的阳极,其中阳极包括涂覆有二氧化铅并且在其中形成有一个或多个凹槽的基底,阴极,其包括主体 设置在膜的另一侧并与膜接触的烧结镍,以及在其表面部分上波纹状的支撑结构,其表面部分与烧结镍的主体接触以保持主体与膜接触。 通过这种结构,可以向阳极中的槽供给水,以最终在膜和阴极的界面处产生反应以产生氢气。