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    • 1. 发明申请
    • POLYMER PARTICLES AND RELATED ARTICLES
    • 聚合物颗粒及相关物品
    • WO2008030697A2
    • 2008-03-13
    • PCT/US2007/076295
    • 2007-08-20
    • NOVA CHEMICALS INC.BLEIJENBERG, Karel, CornelisBERGHMANS, Michel, Florentine, JozefBERGHMANS, Hugo, A.A.
    • BLEIJENBERG, Karel, CornelisBERGHMANS, Michel, Florentine, JozefBERGHMANS, Hugo, A.A.
    • C08J9/18
    • C08J9/125C08J9/18C08J9/232C08J2203/06
    • Process for preparing polymer, e.g., polystyrene, particles that may not or may contain a water-retaining agent and that require only a one-step process for incorporating the water-retaining agent. The polymer particles may be prepared via an extrusion process, or a bulk polymerization process wherein a water-retaining agent is blended into the polymer melt. Water is incorporated into the particles by soaking them in hot or cold water or treating the particles with steam for a predetermined time depending on the desired water content in the particles. The water-retaining agent may be starch, zeolite, silica dioxide or poly (N-isopropyl acrylamide) ranging from 0.1% to 10.0% by weight. The particles can be expanded via appropriate means to form pre-expanded or expanded particles in a conventional manner. These polymer particles may be used via conventional means to produce an article and the article may be soaked in hot or cold water or steam can be applied to the article to introduce a desired amount of water into the particles in the article and than expanded via hot air, steam, etc. to form a foamed polymer article.
    • 用于制备聚合物(例如聚苯乙烯)的方法,所述聚合物可能不含或可能含有保水剂并且仅需要一步法用于掺入保水剂。 聚合物颗粒可以通过挤出法或其中将保水剂共混入聚合物熔体中的本体聚合法来制备。 通过将水浸泡在热水或冷水中或通过蒸汽处理颗粒预定的时间而将水结合到颗粒中,这取决于颗粒中所需的水含量。 保水剂可以是按重量计0.1%至10.0%的淀粉,沸石,二氧化硅或聚(N-异丙基丙烯酰胺)。 颗粒可以通过适当的方式膨胀以常规方式形成预膨胀或膨胀颗粒。 这些聚合物颗粒可以通过常规方式用于制造制品,并且可以将制品浸泡在热水或冷水中,或者可以将蒸汽施加到制品上以将期望量的水引入制品中的颗粒中并且通过热 空气,蒸汽等形成发泡聚合物制品。
    • 6. 发明申请
    • EXPANDABLE RESINS
    • 可膨胀树脂
    • WO2006122185A2
    • 2006-11-16
    • PCT/US2006/018075
    • 2006-05-10
    • NOVA CHEMICALS INC.PETELA, GrazynaBERGHMANS, Michel Florentine, JozefBLEIJENBERG, Karel, Cornelis
    • PETELA, GrazynaBERGHMANS, Michel Florentine, JozefBLEIJENBERG, Karel, Cornelis
    • C08J9/16
    • C08J9/18C08J9/0061C08J2353/00C08J2425/00Y10T428/2982
    • Resin beads having an average particle size of from 0.001 mm to 10 mm and containing a continuous phase and a particulate dispersed phase are described. The continuous phase includes elastomeric polymers; the dispersed phase includes homopolymers and/or copolymers containing repeat units resulting from the polymerization of one or more aryl polymerizable monomers. The unexpanded polymer resin beads can be prepared by dispersing an organic phase containing elastomeric polymers and one or more monomers, into droplets and polymerizing the monomers in the organic droplets in a low shear flow pattern. The beads can be impregnated with blowing agents, expanded and can be used to make molded articles. Resin beads having a continuous phase comprising a nitrile rubber, and a dispersed phase comprising one or more homopolymers and/or copolymers containing repeat units resulting form the polymerization of one or more aryl polymerizable show prolonged retention of blowing agents in unexpanded form.
    • 描述平均粒度为0.001mm至10mm并且包含连续相和颗粒分散相的树脂珠。 连续相包括弹性聚合物; 分散相包括由一种或多种芳基可聚合单体聚合得到的含有重复单元的均聚物和/或共聚物。 未膨胀的聚合物树脂珠可以通过将含有弹性体聚合物和一种或多种单体的有机相分散在液滴中并以低剪切流动模式将有机相聚合在有机液滴中来制备。 珠可以用发泡剂浸渍,膨胀并可用于制造模制品。 具有包含丁腈橡胶的连续相的树脂珠粒和包含一种或多种含有形成聚合一个或多个芳基可聚合的重复单元的均聚物和/或共聚物的分散相显示出未发泡形式的发泡剂的延长保留。