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1. 发明专利

JP2001145919A SOLVENTLESS PROCESSING OF POLYMER CONTAINING HIGH ACRYLONITROLE 失效
公开(公告)号：JP2001145919A
公开(公告)日：2001-05-29
申请号：JP2000311440
申请日：2000-10-12
申请人： BASHIR ZAHIR
发明人： BASHIR ZAHIR
IPC分类号： C08J5/00 , B29B13/02 , B29C47/00 , B29C67/24
摘要： PROBLEM TO BE SOLVED: To provide a method, different from a conventional processing method, which can continuously extrude a polymer containing a PAN homopolymer and a high nitrile (acrylonitrile content of 96-100 wt.%) at a temperature considerably lower than 320 deg.C, which is the thermodynamical melting point of the polymer, without using a solvent or a plasticizer into a molding. SOLUTION: Acrylonitrile homopolymer or a copolymer containing a high acrylonitrile content (95-100%) can be extruded into moldings without using a solvent or a plasticizer. The moldings include thick-walled moldings such as bars and tubes (profile extrusion) which have been impossible to be extrusion- molded from the polymers of an acrylonitrile by other methods. The extruded molding keeps orientation formed in an extrusion process.

2. 发明公开

EP1223023A1 Method of solventless processing PAN homopolymers or high acrylonitrile content PAN copolymers 审中-公开
标题翻译：用于处理PAN PAN均聚物或共聚物与丙烯腈的含量高的无溶剂法
公开(公告)号：EP1223023A1
公开(公告)日：2002-07-17
申请号：EP01300363.7
申请日：2001-01-16
申请人： Bashir, Zahir
发明人： Bashir, Zahir
IPC分类号： B29C47/54 , B29C47/00 , B29C55/00
CPC分类号： B29C55/005 , B29C47/0004 , B29C47/0014 , B29C47/0019 , B29C47/0023 , B29C47/0071 , B29C47/54 , B29C55/30 , B29K2033/20
摘要： Articles from acrylonitrile homopolymer and copolymers with an acrylonitrile content from over 95% to 100% are shaped by extrusion methods, without the aid of solvents or plasticisers. This allows the production of thick sections such as rods, tubes, by profile extrusion, and other objects that cannot be produced from high acrylonitrile-based polymers by any other method. The extruded articles can retain the orientation imparted during extrusion.
摘要翻译：与来自超过95％至100％的丙烯腈含量从丙烯腈聚物和共聚物制品是通过挤出法成形，没有溶剂或增塑剂的帮助。这允许生产厚的切片的：如棒，管，通过型材挤出，和其它的目的也无法从高丙烯腈系聚合物通过任何其它方法生产。该挤出制品可以保持挤压过程中所施加的方向。

3. 发明专利

GB2356830A A method for the solventless processing of high acrylonitrile- content polymers 未知
公开(公告)号：GB2356830A
公开(公告)日：2001-06-06
申请号：GB0023402
申请日：2000-09-25
申请人： BASHIR ZAHIR
发明人： BASHIR ZAHIR
IPC分类号： C08J5/00 , B29B13/02 , B29C47/00 , B29C67/24 , B29C43/00 , B29C43/24 , B29C45/00 , B29C55/00 , D01F6/18
摘要： A method for the solventless processing of high acrylonitrile- content polymers containing more than 95% and up to 100% by weight of acrylonitrile, comprises the step of heating the dry polymer under pressure at a temperature above its glass transition but below its melting point. It is then continuously or discontinuously extruded through a die, or deformed to form a uniaxially or biaxially oriented article. The deformation may achieved by injection moulding, blow moulding, calendering, compression moulding, die drawing, pultrusion or hot drawing.

4. 发明专利

GB0023402D0 Solventless processing of high-acrylonitrile polymers 未知
公开(公告)号：GB0023402D0
公开(公告)日：2000-11-08
申请号：GB0023402
申请日：2000-09-25
申请人： BASHIR ZAHIR
IPC分类号： C08J5/00 , B29B13/02 , B29C47/00 , B29C67/24

5. 发明申请

WO2012041482A1 POLYESTER-BASED TAPE, PROCESS FOR PRODUCING SAID TAPE AND USE THEREOF 审中-公开
标题翻译：基于聚酯的胶带，用于生产胶带的方法及其用途
公开(公告)号：WO2012041482A1
公开(公告)日：2012-04-05
申请号：PCT/EP2011/004823
申请日：2011-09-27
申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC) , STARLINGER & Co. Gesellschaft m. b. H. , BASHIR, Zahir , FÜRST, Herbert , SCHNEIDER, Franz , KRAUS, Robert , LEEB, Christian
发明人： BASHIR, Zahir , FÜRST, Herbert , SCHNEIDER, Franz , KRAUS, Robert , LEEB, Christian
IPC分类号： B29C55/06 , C08L67/02 , C08J5/18
CPC分类号： D03D3/005 , B29C47/0004 , B29C47/0014 , B29C47/0021 , B29C55/06 , B29K2067/00 , B29K2105/0088 , B29K2423/0625 , B65H18/08 , B65H18/28 , C08L67/02 , D03D1/04 , D03D15/00 , Y10T428/1345 , Y10T428/1397 , Y10T428/249921 , Y10T442/2861 , C08L23/0815
摘要： The invention relates to a tape comprising from (i) about 75 wt% to about 99.9 wt% of a thermoplastic polyester, (ii) from about 0.1 wt% to about 25 wt% of a linear low-density polyethylene and (iii) from 0 wt% to about 5 wt% of other components, said tape having a thickness from 5μm to 300 μm and a width from 0.5mm to 7mm. This tape shows no twinning and sticking to other tapes after slitting, has very good mechanical properties. When the tape is wound, bobbins having a regular shape can be obtained.
摘要翻译：本发明涉及包含（i）约75重量％至约99.9重量％的热塑性聚酯，（ii）约0.1重量％至约25重量％的线性低密度聚乙烯和（iii）从 0重量％至约5重量％的其它组分，所述带的厚度为5μm至300μm，宽度为0.5mm至7mm。这种胶带在分切后没有显示出孪晶和粘附到其他胶带，具有非常好的机械性能。当磁带被缠绕时，可以获得具有规则形状的线轴。

6. 发明申请

WO2010105787A8 PROCESS FOR MAKING THERMOPLASTIC POLYESTERS 审中-公开
标题翻译：制造热塑性聚酯的工艺
公开(公告)号：WO2010105787A8
公开(公告)日：2011-10-20
申请号：PCT/EP2010001618
申请日：2010-03-15
申请人： SAUDI BASIC IND CORP , BASHIR ZAHIR , SABIC PETROCHEMICALS BV
发明人： BASHIR ZAHIR
IPC分类号： C08G63/85
CPC分类号： C08G63/85
摘要： The invention relates to a process for making a thermoplastic polyester, which comprises contacting at least one carboxylic acid-based compound and at least one alcohol-based compound in esterification and subsequent polycondensation reactions, in the presence of certain exfoliated inorganic nano-layered titanates acting as a catalyst.
摘要翻译：本发明涉及一种制备热塑性聚酯的方法，其包括在酯化和随后的缩聚反应中使至少一种羧酸基化合物和至少一种醇基化合物在某些剥离的无机纳米层状钛酸盐作为催化剂。

7. 发明专利

GB9923977D0 Solventless processing of high-acrylonitrile polymers 未知
公开(公告)号：GB9923977D0
公开(公告)日：1999-12-15
申请号：GB9923977
申请日：1999-10-12
申请人： BASHIR ZAHIR
IPC分类号： C08J5/00 , B29B13/02 , B29C47/00 , B29C67/24

8. 发明申请

WO2010105787A1 PROCESS FOR MAKING THERMOPLASTIC POLYESTERS 审中-公开
标题翻译：制造热塑性聚酯的工艺
公开(公告)号：WO2010105787A1
公开(公告)日：2010-09-23
申请号：PCT/EP2010/001618
申请日：2010-03-15
申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC) , BASHIR, Zahir , SABIC PETROCHEMICALS B.V.
发明人： BASHIR, Zahir
IPC分类号： C08G63/85
CPC分类号： C08G63/85
摘要： The invention relates to a process for making a thermoplastic polyester, which comprises contacting at least one carboxylic acid-based compound and at least one alcohol-based compound in esterification and subsequent polycondensation reactions, in the presence of certain exfoliated inorganic nano-layered titanates acting as a catalyst.
摘要翻译：本发明涉及一种制备热塑性聚酯的方法，其包括在酯化和随后的缩聚反应中使至少一种羧酸基化合物和至少一种醇基化合物在某些剥离的无机纳米层状钛酸盐作为催化剂。

9. 发明申请

WO2009130033A1 PROCESS FOR MAKING OPAQUE POLYESTER FILM 审中-公开
标题翻译：制作OPAQUE聚酯薄膜的方法
公开(公告)号：WO2009130033A1
公开(公告)日：2009-10-29
申请号：PCT/EP2009/002986
申请日：2009-04-20
申请人： SAUDI BASIC INDUSTRIES CORPORATION , BASHIR, Zahir , WARD, Ian, Macmillan , THOMPSON, Glen, Peter , UNWIN, Anthony, Paul
发明人： BASHIR, Zahir , WARD, Ian, Macmillan , THOMPSON, Glen, Peter , UNWIN, Anthony, Paul
IPC分类号： C08J5/18 , C08L67/00 , B65D88/16 , D01D5/42
CPC分类号： D01F6/62 , B29C47/0004 , B29C47/0021 , B29C47/0057 , B29C47/043 , B29C47/88 , B29C47/8805 , B29C47/8815 , B29C47/884 , B29C47/8845 , B29C47/92 , B29C55/06 , B29C55/12 , B29C55/14 , B29C55/143 , B29C71/02 , B29C2071/022 , B29C2947/92742 , B29C2947/92752 , B29C2947/9278 , B29K2067/00 , B29K2067/003 , C08J5/18 , C08J2367/02 , D01D5/426 , Y10T428/1345 , Y10T442/30
摘要： The invention relates to a process for making an opaque and glossy film from a thermoplastic polyester composition, comprising the steps of a) extruding the polyester composition through a slot die, and quenching to form a substantially amorphous film having a crystallinity of at most 5%; b) rapidly heating the amorphous film to a drawing temperature in the range from T g to (T g + 50) °C while applying a draw ratio in the range of from λ initiation to λ max . in longitudinal direction, and a drawing rate of at least 1 m/min to form an oriented film showing stress-whitening, wherein λ initiation is the draw ratio at which a transfer from a transparent product to a stress-whitened product occurs and λ max . is the draw ratio at which failure of the stress whitened film occurs; and c) heat-setting the oriented stress-whitened film; the thermoplastic polyester composition substantially consisting of at least one crystallisable polyester derived from at least one aliphatic diol and at least one aromatic dicarboxylic acid. With this process it is possible to make a unitary, glossy, opaque film from a polyester composition that does not contain void-forming additives like high amounts of fine pigment particles or dispersed non-miscible polymer particles. The film obtained also has very good mechanical properties. It is a further advantage that the process can be performed continuously on conventional extrusion and stretching equipment used for making transparent film from polyesters. The invention also relates to an opaque polyester film obtainable by said process.
摘要翻译：本发明涉及一种由热塑性聚酯组合物制造不透明和光泽的薄膜的方法，包括以下步骤：a）通过槽模挤出聚酯组合物，并淬火以形成结晶度至多为5％的基本上无定形的薄膜， ; b）在Tg至（Tg + 50）℃的范围内将非晶膜快速加热到拉伸温度，同时施加拉伸比在开始了？最大。并且拉伸速度为至少1m / min，以形成显示应力增白的取向膜，其中，起始是从透明产品转移到应力白化产品的拉伸比，λmax。是发生应力增白膜失效的拉伸比; 和c）热定形应力增白膜; 所述热塑性聚酯组合物基本上由至少一种衍生自至少一种脂族二醇和至少一种芳族二羧酸的可结晶聚酯组成。通过该方法，可以由不含空隙形成添加剂如大量细颜料颗粒或分散的不可混溶聚合物颗粒的聚酯组合物制成单一的，有光泽的不透明膜。获得的膜也具有非常好的机械性能。进一步的优点是可以在用于从聚酯制造透明膜的常规挤出和拉伸设备上连续进行。本发明还涉及通过所述方法可获得的不透明聚酯膜。

10. 发明申请

WO2009130032A1 FLEXIBLE INTERMEDIATE BULK CONTAINER 审中-公开
标题翻译：柔性中间大容量容器
公开(公告)号：WO2009130032A1
公开(公告)日：2009-10-29
申请号：PCT/EP2009/002985
申请日：2009-04-20
申请人： SAUDI BASIC INDUSTRIES CORPORATION , BASHIR, Zahir , WARD, Ian, Macmillan , THOMPSON, Glen, Peter , UNWIN, Anthony, Paul
发明人： BASHIR, Zahir , WARD, Ian, Macmillan , THOMPSON, Glen, Peter , UNWIN, Anthony, Paul
IPC分类号： D01D5/42 , D01F6/62 , B29C55/06 , B65D88/16
CPC分类号： D01D5/426 , B29C55/06 , B29K2067/00 , B65D88/1612 , D01F6/62 , Y10T428/1362
摘要： The invention relates to a Flexible Intermediate Bulk Container (FIBC) having a body made of flexible woven fabric, and integral handling devices, wherein the fabric is woven from opaque oriented polyethylene terephthalate (PET) strips having a density of from 500 to 1300 kg/m 3 and a tensile strength of at least 250 MPa. Advantages of said FIBC include directly printability with the usual type of inks, giving excellent contrast and good adhesion, without pre-treatment like a corona- or flame-treatment. The FIBC based on the PET fabric also shows higher gloss; better UV resistance; better mechanical properties, like high tensile strength and creep resistance; favourable abrasion resistance; and higher temperature resistance than a conventional big bag based on polypropylene strips. The invention further relates to such a FIBC based on stress-whitened PET tapes obtained by a special drawing process.
摘要翻译：本发明涉及一种具有由柔性织物制成的主体的柔性中间散装容器（FIBC）和一体式处理装置，其中织物由密度为500至1300kg / m 2的不透明取向的聚对苯二甲酸乙二醇酯（PET） m3，拉伸强度至少为250MPa。所述FIBC的优点包括使用通常类型的油墨直接印刷，具有优异的对比度和良好的附着力，无需进行电晕或火焰处理的预处理。基于PET织物的FIBC也具有较高的光泽度; 更好的抗紫外线; 更好的机械性能，如高抗拉强度和抗蠕变性; 耐磨性好; 耐高温性比传统的基于聚丙烯条的大袋子。本发明还涉及通过特殊拉伸工艺获得的基于应力增白PET带的这种FIBC。

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