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    • 1. 发明申请
    • PROCESS FOR PRODUCING OLIGOAMINES OR POLYAMINES
    • 用于生产低聚或多胺
    • WO1996011225A1
    • 1996-04-18
    • PCT/EP1995003809
    • 1995-09-26
    • BASF AKTIENGESELLSCHAFTMOHR, JürgenKNAUF, WolfgangBALZER, Wolf-DieterOPPENLÄNDER, KnutSLOTMAN, Wilhelmus
    • BASF AKTIENGESELLSCHAFT
    • C08G73/02
    • B01D17/047C07C213/04C08G65/2696C08G73/0213C10G33/04
    • Production of oxalkylates of oligoamines or polyamines in a two-stage process in which, in the first stage, a molecule of alkylene oxide per NH group is added to the oligoamine or polyamine in the presence of water, alcohols or acids or a mixture thereof in the absence of a neutral or basic catalyst and, in the second, after the removal of water and acids, a reaction is conducted with further alkylene oxide in the presence of a conventional neutral or basic catalyst. According to this method, one adds before the second stage an organic solvent or diluting agent or a mixture of such agents from the group: (a) alcohols and phenols and their alkoxylates, (b) polyalcohols based on ethylene oxide, propylene oxide, butylene oxide or a mixture thereof, (c) N-substituted carboxylic acid amides, (d) alkanol monoamines and alkanol polyamines and their alkoxylates, (e) other oxalkylates of oligo or polyamines, (f) aromatic hydrocarbons, (g) aliphatic hydrocarbons, (h) ether and (i) sulphones or sulphoxides.
    • 低聚胺或多胺的烷氧基化物通过两步骤操作制备,其中在第一阶段中,除了每NH基团在水,醇或酸或它们的混合物存在下的低聚胺或聚胺的烯化氧中的一个分子在不存在中性或碱性催化剂的其 通过之前执行所述第二步骤中,有机溶剂或稀释剂或这类试剂的选自一混合物与另外的烯化氧的常规中性或碱性催化剂的存在下进行的,并且其中在第二阶段中实施,除去水和酸后 的(a)醇类和酚,以及它们的烷氧基化物,(b)中其基于环氧乙烷,环氧丙烷,环氧丁烷或它们的混合物,(C)多元醇的N-取代的羧酰胺,(d)中链烷醇单胺和alkanolpolyamines及其烷氧基化物,(e)其他 烷氧基化物低聚胺或多胺( F)芳香烃,(克)脂族烃,(H)醚和(i)砜或亚砜溶液。