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    • 5. 发明授权
    • Lustrous, antisoiling flame retardant acrylic fibers and process therefor
    • 光泽,防污阻燃丙烯酸纤维及其工艺
    • US4081498A
    • 1978-03-28
    • US358743
    • 1973-05-09
    • Arutun Maranci
    • Arutun Maranci
    • D01F6/18C08L33/20
    • D01F8/08D01F6/54Y10S260/24Y10S260/32
    • Acrylic fibers of a fiber-forming first acrylonitrile polymer containing at least 50% acrylonitrile, a flame retardant amount of a halogen-containing vinyl monomer, and any balance of a halogen-free vinyl monomer having heterogeneously dispersed therein a small amount of an incompatible, halogen-free, second acrylonitrile polymer containing at least 70% acrylonitrile and one or more halogen-free vinyl monomers. The fibers are prepared by wet-spinning an intimate mixture of the polymers separately dissolved in aqueous inorganic solutions of the same salt following conventional procedures but including a hot-wet relaxation of the stretched wet-gel filaments prior to drying.
    • 含有至少50%丙烯腈,阻燃剂量的含卤乙烯基单体的纤维形成的第一丙烯腈聚合物的丙烯酸纤维,以及其中不均匀分散有少量不相容的乙烯基单体的任何其余的无卤乙烯基单体, 含有至少70%丙烯腈和一种或多种无卤乙烯基单体的无卤素的第二丙烯腈聚合物。 通过按照常规方法将分开溶解在相同盐的无机水溶液中的聚合物的紧密混合物湿纺,但在干燥之前包括拉伸的湿凝胶长丝的热湿松弛来制备纤维。