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1. 发明授权

US5000853A Process for the improved separation of clarified liquid from biomass in the biological treatment of sewage 失效
标题翻译：在污水生物处理中改善澄清液体与生物质分离的方法
公开(公告)号：US5000853A
公开(公告)日：1991-03-19
申请号：US457205
申请日：1989-12-26
申请人： Artur Reischl , Hanno Henkel , Friedhelm Sahlmen
发明人： Artur Reischl , Hanno Henkel , Friedhelm Sahlmen
IPC分类号： C02F1/52 , B01D21/00 , B01D21/28 , B03C1/00 , C02F1/48 , C02F3/12
CPC分类号： B01D21/00 , B01D21/0009 , B01D21/01 , B01D21/02 , B03C1/01 , B03C1/0332 , B03C1/14
摘要： The present invention relates to a process for the improved separation of clarified liquids from biomass or rather for the separation of clarified sludges in the (aerobic and/or anaerobic) biological treatment of sewage using magnetically separable materials as carrier masses. The carrier masses are organic materials containing magnetically separable inorganic materials incorporated in abrasion-resistant form. These magnetically separable carriers occupy a suspension volume of from 1 to 85% by volume, based on the clarified liquid.The carriers contain magnetically separable inorganic materials incorporated as fillers in organic polymeric materials, particularly in cellular polymeric carriers. Other organic or inorganic fillers may also be used in these organic carriers. The magnetically separable materials used are oxides or mixed oxides of heavy metals, preferably iron oxides, such as Fe.sub.3 O.sub.4 (magnetite) and .gamma.-Fe.sub.2 O.sub.3, which are used in average particle sizes of less than 50 .mu.m, preferably less than 10 .mu.m and more preferably less than 3 .mu.m, for example from 0.1 to 1 .mu.m.These magnetic carriers provide for magnetic separation of the biomasses containing these magnetic materials in the biological treatment of sewage.

2. 发明授权

US4608397A Filler-containing polyurethane (urea) compositions prepared from prepolymers reacted with water in the presence of lignite or peat 失效
标题翻译：由预聚物制备的含有填料的聚氨酯（尿素）组合物在褐煤或泥炭存在下与水反应
公开(公告)号：US4608397A
公开(公告)日：1986-08-26
申请号：US672440
申请日：1984-11-16
申请人： Artur Reischl
发明人： Artur Reischl
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/65 , C08K3/04 , C08K11/00 , C08L75/00 , C08L75/04 , C08G18/14
CPC分类号： C08K3/04 , C08G18/0814 , C08G18/10 , C08K11/00
摘要： The invention relates to a process for the production of polyurethane(urea) compositions which contain lignite and/or peat bound in an abrasion-proof manner, which are preferably modified cationically and which have a very high water absorbability. The compositions are produced by reacting isocyanate-terminated prepolymers, which are preferably cationically modified, and which preferably have a functionality of more than 2.1, with more than the stoichiometric quantity of water in the presence of lignite and/or peat and optionally in the presence of organic and/or inorganic fillers and biomasses (living cells, living bacteria or enzymes). The corresponding polyurethane(urea) compositions contain up to 95% by weight of lignite and/or peat in the filler-containing polyurethane(urea) composition and are already swollen from production. The water absorbability (WAF) value thereof when suspended in water is from 33 to 97% by weight of water.The compositions can be used, in a form optionally containing biomasses incorporated therein, as carriers in microbial synthesis processes for the production of complicated organic compounds, or as carriers for the growth of plants.
摘要翻译：本发明涉及一种生产聚氨酯（尿素）组合物的方法，该组合物含有以耐磨损方式结合的褐煤和/或泥煤，其优选是阳离子改性且具有非常高的吸水性。组合物通过异氰酸酯封端的预聚物（其优选阳离子改性，优选具有大于2.1的官能度）与在褐煤和/或泥炭存在下具有超过化学计算量的水反应而产生，并且任选地存在的有机和/或无机填料和生物质（活细胞，活细菌或酶）。相应的聚氨酯（尿素）组合物在含填料的聚氨酯（脲）组合物中含有高达95重量％的褐煤和/或泥炭，并且已经从生产中膨胀。悬浮在水中时的吸水率（WAF）值为33〜97重量％。组合物可以任选地含有其中并入的生物质的形式用作用于生产复杂有机化合物的微生物合成方法中的载体，或用作植物生长的载体。

3. 发明授权

US4576718A Use of water-absorbing, highly-filled polyurethane (urea) compositions for biological treatment of waste-containing liquids 失效
标题翻译：使用吸水性高填充聚氨酯（尿素）组合物进行生物处理含废液体
公开(公告)号：US4576718A
公开(公告)日：1986-03-18
申请号：US672441
申请日：1984-11-16
申请人： Artur Reischl , Kurt Mack
发明人： Artur Reischl , Kurt Mack
IPC分类号： C02F3/06 , C02F3/08 , C02F3/10
CPC分类号： C02F3/10 , Y02W10/15
摘要： The present invention relates to the use of non-floating, non-abrasive, highly-filled polyurethane (urea) compositions of high water-absorbability, which during their production contain no cells capable of growth as carriers for biomasses in the biological treatment of waste-containing liquids. These carriers have a filler content of greater than 15% by weight and less than 95% by weight (based on the moisture-free weight of the filler-containing polyurethanes). The fillers are selected from the group consisting of natural materials containing finely-divided fossil lignocelluloses or the secondary products thereof (e.g., peat, lignite, mineral coal or coke), active carbon, finely-divided distillation residues, inorganic fillers, homogeneous or cellular plastics particles (and more particularly polyurethane foam (waste) particles) and mixtures thereof. The polyurethane (urea) is a hydrophilic and/or hydrophobic polyurethane(urea), and preferably contains cationic groups. These highly-filled, polyurethane (urea) carriers have a water-absorbability exceeding 33% by weight of water in the swollen carrier.These carriers allow improved treatment of industrial and municipal liquid waste to be achieved in biologically-operating treatment plants. Treated waste which has reduced toxicity, a diminished smell, improved clarity and a very small residual content of organic, decomposable material is obtained due to the increased decomposition effect thereof.
摘要翻译：本发明涉及使用具有高吸水性的非浮动，非研磨，高填充的聚氨酯（尿素）组合物，其在生产过程中不含能够生长的细胞作为废物生物处理中生物质的载体含液体。这些载体的填料含量大于15重量％且小于95重量％（基于含填料的聚氨酯的无水重量）。填料选自含有细碎化石油木质纤维素的天然材料或其二次产物（例如，泥煤，褐煤，矿物煤或焦炭），活性炭，精细分馏的蒸馏残余物，无机填料，均相或细胞塑料颗粒（尤其是聚氨酯泡沫（废物）颗粒）及其混合物。聚氨酯（尿素）是亲水和/或疏水性聚氨酯（尿素），优选含有阳离子基团。这些高填充性聚氨酯（尿素）载体在溶胀载体中的吸水率超过33重量％。这些载体允许在生物操作的处理设备中实现工业和城市废液的改进处理。由于其分解效果的增加，得到了具有降低的毒性，减少的气味，改善的澄清度和非常小的有机可分解材料残留量的废弃物。

4. 发明授权

US4260530A Process for the preparation of polyurethane resins using stable dispersions as a starting component 失效
标题翻译：使用稳定分散体作为起始组分制备聚氨酯树脂的方法
公开(公告)号：US4260530A
公开(公告)日：1981-04-07
申请号：US46585
申请日：1979-06-07
申请人： Artur Reischl , Hanns Muller , Kuno Wagner
发明人： Artur Reischl , Hanns Muller , Kuno Wagner
IPC分类号： C08L61/00 , C08G18/00 , C08G18/40 , C08G18/54 , C08L61/04 , C08L61/20 , C08L75/04 , C08L77/00 , C08L61/10 , C08L75/10
CPC分类号： C08G18/409 , C08L75/04
摘要： This invention relates to a process for the preparation of a finely divided, stable and relatively low viscosity dispersion of a polyisocyanate polyaddition product and an aminoplast and/or phenoplast and/or copolymer thereof in a hydroxyl containing compound and the use of such a dispersion as the starting component for the production of a polyurethane resin.
摘要翻译：本发明涉及一种制备在含羟基化合物中的多异氰酸酯加聚产物和氨基塑料和/或酚醛树脂和/或其共聚物的细分散，稳定和相对低粘度分散体的方法，以及使用这样的分散体用于生产聚氨酯树脂的起始组分。

5. 发明授权

US4251638A Process for the production of polyurethane plastics 失效
标题翻译：聚氨酯塑料生产工艺
公开(公告)号：US4251638A
公开(公告)日：1981-02-17
申请号：US89322
申请日：1979-10-29
申请人： Artur Reischl
发明人： Artur Reischl
IPC分类号： C08G18/00 , C08G18/08 , C08G18/64 , C08G18/70 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L67/00 , C08L75/00 , C08L77/00 , C08G18/14
CPC分类号： C08G18/08 , C08G18/64 , C08G18/6484 , C08G18/70
摘要： This invention relates to a process for the production of optionally cellular polyurethane plastics using a reactive filler obtained by finely grinding a distillation residue of the type accumulating in the commercial production of tolylene diisocyanate. It is possible in this way to recycle the previously unuseable slag-like residues and at the same time to improve the mechanical properties of the polyurethane plastics filled with them.
摘要翻译：本发明涉及使用通过细粉碎在商业生产甲苯二异氰酸酯中积聚的蒸馏残余物获得的反应性填料来生产任选的细胞聚氨酯塑料的方法。以这种方式回收以前不可使用的渣状残留物，同时可以改善填充有它们的聚氨酯塑料的机械性能。

6. 发明授权

US4093569A Polyurethane resins produced from active hydrogen containing material which is a dispersion of polyisocyanate-polyaddition products in hydroxyl containing compounds as dispersing agents 失效
标题翻译：由含活性氢的材料制成的聚氨酯树脂，其是含羟基化合物作为分散剂的多异氰酸酯加聚产物的分散体
公开(公告)号：US4093569A
公开(公告)日：1978-06-06
申请号：US740452
申请日：1976-11-10
申请人： Artur Reischl , Gert Jabs , Alberto Carlos Gonzalez-Dorner
发明人： Artur Reischl , Gert Jabs , Alberto Carlos Gonzalez-Dorner
IPC分类号： C08G18/08 , C08G18/12 , C08G18/30 , C08G18/84
CPC分类号： C08G18/84 , C08G18/08 , C08G18/0804 , C08G18/12 , C08G18/302
摘要： This invention relates to the use of certain finely divided, stable and relatively low viscosity dispersions of polyisocyanate polyaddition products in compounds having hyroxyl groups. The dispersions are produced by reacting1. organic polyisocyanates with2. compounds having primary and/or secondary amino groups and/or primary hydroxyl groups in3. compounds having at least one hydroxyl group, whereinCompounds (3) have secondary hydroxyl groups in cases when compounds (2) have primary hydroxyl groups and wherein the components are reacted in the presence of more than 4% by weight of water, based on the quantity of reaction mixture including water.
摘要翻译：本发明涉及在具有羟基的化合物中使用某些细分散，稳定且相对低粘度的多异氰酸酯加成产物的分散体。分散体是通过使有机聚异氰酸酯与2.具有主要和/或二级氨基团和/或主要羟基基团的化合物反应生成的。3.具有至少一个羟基的化合物（其中化合物（3）具有二次羟基组合）当化合物（2）具有主要的羟基组合，并且组分根据包含水的反应混合物的量在水中以重量计超过4％反应时，反应。

7. 发明授权

US4834003A Combustion of aqueous sewage sludge by the fluidized bed process 失效
标题翻译：通过流化床工艺燃烧含水污泥
公开(公告)号：US4834003A
公开(公告)日：1989-05-30
申请号：US236087
申请日：1988-08-24
申请人： Artur Reischl , Friedhelm Sahlmen
发明人： Artur Reischl , Friedhelm Sahlmen
IPC分类号： C02F1/02 , C02F11/06 , F23G5/30 , F23G7/00
CPC分类号： F23G5/30 , C02F11/06 , F23G7/001 , F23G2207/101 , F23G2207/50 , Y02W10/40
摘要： This invention relates to a process for the combustion of aqueous sewage sludge comprising burning, in a fluidized bed furnace, an aqueous mixture of a sewage sludge and a TDI residue, said aqueous mixture having a total solids content of from 25 to 98% by weight of the aqueous mixture, wherein the TDI residue comprises 25 to 95% by weight of the total solids content.
摘要翻译：本发明涉及一种用于燃烧含水污水污泥的方法，包括在流化床炉中将下游污泥和TDI残渣的含水混合物燃烧，所述含水混合物的总固体含量为25至98重量％的水性混合物，其中TDI残余物占总固体含量的25至95重量％。

8. 发明授权

US4472558A Process for carrying out reactions caused by the transport of substances 失效
标题翻译：进行由物质运输引起的反应的过程
公开(公告)号：US4472558A
公开(公告)日：1984-09-18
申请号：US45028
申请日：1979-06-04
申请人： Clemens Casper , Henning Klussmann , Gunter Lehr , Johannes O. Sajben , Artur Reischl , Rudolf Binsack , Frank Wingler
发明人： Clemens Casper , Henning Klussmann , Gunter Lehr , Johannes O. Sajben , Artur Reischl , Rudolf Binsack , Frank Wingler
IPC分类号： B01D3/28 , B01J3/04 , B01J10/02 , B01J19/24 , C08F2/00 , C08F2/06 , C08G18/00 , C08G18/08
CPC分类号： C08G18/0838 , B01J10/02 , B01J19/243 , B01J3/042 , B01J2219/00085 , B01J2219/00162 , B01J2219/00164
摘要： This invention relates to a process for carrying out reactions which primarily occur during the transport of compounds in the liquid phase or at the liquid-gas interface. Starting components are reacted with one another and/or with gases of the inner space in a multi-phase flow tube having a liquid ring flow which may contain dissolved and/or dispersed constituents. Any necessary heat exchange takes place between the liquid and the wall of the tube or the gases.
摘要翻译：本发明涉及一种进行反应的方法，主要发生在化合物在液相或液 - 液界面输送过程中。起始组分在具有可能含有溶解和/或分散成分的液体环流的多相流动管中彼此反应和/或与内部空间的气体反应。在液体和管壁或气体之间进行任何必要的热交换。

9. 发明授权

US4454259A Process for the preparation of polyaddition products of isocyanates and denatured biomasses, their use as reactive fillers and as plant nutrients and a process for the production of sheets or shaped articles using the polyaddition products 失效
标题翻译：制备异氰酸酯和变性生物质的加聚产物的方法，它们作为反应性填料和植物营养物的用途以及使用加聚产物生产片状或成型制品的方法
公开(公告)号：US4454259A
公开(公告)日：1984-06-12
申请号：US480536
申请日：1983-03-30
申请人： Artur Reischl , Kuno Wagner
发明人： Artur Reischl , Kuno Wagner
IPC分类号： C08G18/00 , C02F11/00 , C05C9/00 , C08G18/30 , C08G18/64 , C08L97/02 , C12N11/08 , C02F11/14 , C08F8/28 , C08L61/20 , C08L61/32
CPC分类号： C12N11/08 , C02F11/00 , C08G18/30 , C08G18/64 , C08L97/02 , Y02W30/47 , Y10S210/928
摘要： The instant invention is directed to a process for the production of denatured polyaddition products of biomasses and isocyanates, comprising reacting(A) from 5 to 98%, by weight, based on (A)+(B), of a biomass based on microorganisms or derivative and decomposition products thereof with(B) from 95 to 2%, by weight, based on (A)+(B), of a compound containing isocyanate groups, at temperatures of at least 50.degree. C. with complete denaturing of component (A).
摘要翻译：本发明涉及一种用于生产生物质和异氰酸酯的变性加聚产物的方法，其包括使（A）基于（A）+（B）的基于微生物的生物质的重量计为5至98重量％或其衍生物和分解产物，其中（B）在至少50℃的温度下，基于（A）+（B），基于（A）+（B）的95至2重量％（一个）。

10. 发明授权

US4311800A Process for working up cross-linked isocyanate distillation residues containing urea groups and use of the products of the process as starting components for the production of synthetic resins 失效
标题翻译：用于处理含有尿素基团的交联异氰酸酯蒸馏残余物的方法以及该方法的产物用作生产合成树脂的起始组分的方法
公开(公告)号：US4311800A
公开(公告)日：1982-01-19
申请号：US197447
申请日：1980-10-16
申请人： Artur Reischl
发明人： Artur Reischl
IPC分类号： C07C265/14 , C07C67/00 , C07C241/00 , C08G18/38 , C08G18/46 , C08G18/50 , C09J175/04 , C08G18/14
CPC分类号： C08G18/3831 , C08G18/4615 , C08G18/5033 , C09J175/04
摘要： This invention relates to the preparation of soluble compounds containing hydroxyalkyl and urethane groups by alcoholysis from highly cross-linked insoluble distillation residues (from the commercial production of tolylene diisocyanate) which have reacted completely or almost completely with water. The products obtained as solutions, solvent-free melts or powders may be used as raw materials for the production of synthetic resins or their intermediates which are characterized by reduced combustibility. They may also be recyclized by simple hydrolysis into the tolylene diamines ("TDA") from which tolylene diisocyanate ("TDI") is derived.
摘要翻译：本发明涉及通过高度交联的不完全蒸馏残余物（商业生产的甲苯二异氰酸酯），其完全或几乎完全与水进行反应来制备含有羟基烷基和氨基甲酸酯基团的可溶性化合物。作为溶液获得的产品，无溶剂的熔体或粉末可以用作生产合成树脂或其中间体的原料，其特征在于可燃性降低。它们也可以通过简单的水解回到衍生甲苯二异氰酸酯（“TDI”）的甲苯二胺（“TDA”）中。

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