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    • 2. 发明授权
    • Block copolymer composition, hot melt adhesive composition containing
it, and process for the preparation thereof
    • 嵌段共聚物组合物,含有它的热熔粘合剂组合物,及其制备方法
    • US5461095A
    • 1995-10-24
    • US265072
    • 1994-06-24
    • Arie Van DongenJacqueline M. VeurinkJeroen Van Westrenen
    • Arie Van DongenJacqueline M. VeurinkJeroen Van Westrenen
    • C08K5/36C08K5/378C08K5/524C08K5/526C08L53/00C08L53/02C09J153/00C09J153/02C08K5/3492C08K5/52
    • C08K5/526C08K5/378C08L53/02C09J153/02
    • A block copolymer composition comprising:(a) 100 parts by weight of a linear block copolymer comprising two polystyrene endblocks and one poly(conjugated diene) midblock, which block copolymer is obtained via a coupling reaction using a diglycidyloxy coupling agent and which block copolymer has a styrene content in the range of from 10 to 50% by weight based on the total weight of block copolymer and an apparent molecular weight in the range of from 100,000 to 400,000; and(b) 0.1 to 2 parts by weight of a stabilizer package consisting of:(b1) 6-(4-hydroxy-3,5-di-t-butylanilino)-2,4-bis-octylthio-1,3,5-triazine, and(b2) a tris-(nonylated phenyl) phosphite, in a weight ratio b1/b2 in the range of from 0.5 to 0.1.The block copolymer composition can be suitably applied in hot melt adhesive compositions.A process for preparing the block copolymer composition comprising the subsequent steps of preparing lithium terminated styrene-conjugated diene diblock copolymer chains, coupling these polymer chains by adding the diglycidyloxy coupling agent, adding the stabilizer package and recovering the block copolymer composition.
    • 一种嵌段共聚物组合物,其包含:(a)100重量份的包含两个聚苯乙烯端嵌段和一个聚(共轭二烯)中间嵌段的直链嵌段共聚物,该嵌段共聚物通过使用二缩水甘油氧基偶联剂的偶联反应获得,并且该嵌段共聚物具有 基于嵌段共聚物的总重量为10至50重量%,表观分子量为100,000至400,000的苯乙烯含量; 和(b)0.1至2重量份的稳定剂包,其包含:(b1)6-(4-羟基-3,5-二叔丁基苯胺基)-2,4-双辛基硫基-1,3, (b2)三(非 - 苯基)亚磷酸酯,重量比b1 / b2在0.5至0.1的范围内。 嵌段共聚物组合物可以适用于热熔粘合剂组合物。 一种制备嵌段共聚物组合物的方法,包括随后的制备锂封端的苯乙烯 - 共轭二烯二嵌段共聚物链的步骤,通过加入二缩水甘油氧基偶联剂偶联这些聚合物链,加入稳定剂包装并回收嵌段共聚物组合物。
    • 3. 发明授权
    • Process for manufacturing isoprene containing block copolymers
    • 制造含异戊二烯的嵌段共聚物的方法
    • US5736612A
    • 1998-04-07
    • US590712
    • 1996-08-19
    • Arie Van DongenHelmuth EinbergerJeroen Van Westrenen
    • Arie Van DongenHelmuth EinbergerJeroen Van Westrenen
    • C08F2/00C08F2/08C08F4/42C08F4/48C08F297/04
    • C08F297/04
    • Process for manufacturing block copolymers derived from predominantly styrene and predominantly isoprene, used in the form of an isoprene concentrate obtainable by contacting an isoprene concentrate, obtainable by removal of piperylene from a gasoline pyrrolysis fraction of hydrocarbons having 5 carbon atoms, with finely dispersed alkali metal and/or alkaline earth metal, and separating it from the free and bound metal, said process comprising at least the steps of polymerizing predominantly styrene monomer in an inert non-aromatic hydrocarbon solvent in the presence of a monofunctional organolithium initiator, adding predominantly isoprene monomer in the form of pretreated isoprene concentrate to the polymerization mixture, either adding a coupling agent to couple a predominant part of the living diblock copolymer or adding a second portion of predominantly styrene monomer, and adding a terminating agent.
    • 制备主要由苯乙烯和主要为异戊二烯衍生的嵌段共聚物的方法,以异戊二烯浓缩物的形式使用,该异戊二烯浓缩物可通过将可从通过从具有5个碳原子的烃的汽油吡咯解部分除去戊间二烯获得的异戊二烯浓缩物与精细分散的碱金属 和/或碱土金属,并将其与游离和结合的金属分离,所述方法至少包括在单官能有机锂引发剂存在下在惰性非芳族烃溶剂中主要聚合苯乙烯单体的步骤,主要加入异戊二烯单体 以预处理的异戊二烯浓缩物的形式加入到聚合混合物中,加入偶联剂以偶联活性二嵌段共聚物的主要部分或加入主要为苯乙烯单体的第二部分,并加入终止剂。