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1. 发明授权

US08802843B2 Tagatose production using simulated moving bed separation 有权
标题翻译：使用模拟移动床分离的塔格斯生产
公开(公告)号：US08802843B2
公开(公告)日：2014-08-12
申请号：US13506889
申请日：2012-05-22
申请人： Anil R. Oroskar , Omkar M. Kulkarni , David W. House , Deepak Sharma , Rakesh Vikraman Nair Rema
发明人： Anil R. Oroskar , Omkar M. Kulkarni , David W. House , Deepak Sharma , Rakesh Vikraman Nair Rema
IPC分类号： C07H1/06 , C07H1/08
CPC分类号： C13K13/00 , B01D15/185 , B01D15/365 , B01J39/05 , B01J39/26 , B01J47/022 , C13K1/00
摘要： Disclosed is a process for the production of d-tagatose from lactose after acid hydrolysis to provide a hydrolysate having 1 equiv of d-glucose and 1 equiv of d-galactose for each unit of lactose converted. More particularly, the invention relates to a process for the isomerization of d-galactose to d-tagatose and the use of a simplified separation scheme based on simulated moving bed (SMB) separation. The isomerization of d-galactose to d-tagatose is carried out in the presence of calcium oxide or calcium hydroxide. The process is useful for providing a simplified processing route to providing pure d-tagatose and glucose as two products from lactose hydrolysate. In an alternate embodiment, a process is disclosed for the production of d-tagatose from fermented lactose hydrolysate to provide a crystallized d-tagatose product. D-tagatose is useful as a food additive, as a sweetener, as a texturizer, as a stabilizer, or as a humectant.
摘要翻译：公开了一种在酸水解之后从乳糖生产d-塔格糖的方法，以提供具有1当量的D-葡萄糖和1当量的D-半乳糖的水解产物，用于每单位转化的乳糖。更具体地，本发明涉及将D-半乳糖异构化为d-塔格糖的方法，以及使用基于模拟移动床（SMB）分离的简化分离方案。 D-半乳糖与D-塔格糖的异构化在氧化钙或氢氧化钙的存在下进行。该方法可用于提供简单的处理途径以从乳糖水解产物中提供纯的d-塔格糖和葡萄糖作为两种产物。在替代实施方案中，公开了用于从发酵乳糖水解产物生产d-塔格糖的方法，以提供结晶的d-塔格糖产品。 D-塔格糖可用作食品添加剂，甜味剂，增白剂，稳定剂，或作为保湿剂。

2. 发明申请

US20130065771A1 Apparatus and method for parallel collection and analysis of the proteome and complex compositions 有权
公开(公告)号：US20130065771A1
公开(公告)日：2013-03-14
申请号：US13199811
申请日：2011-09-09
申请人： Asha A. Oroskar , Anil R. Oroskar , John P. LaCava , Michael P. Rout
发明人： Asha A. Oroskar , Anil R. Oroskar , John P. LaCava , Michael P. Rout
IPC分类号： C40B30/04 , C40B60/12 , G01N30/02 , C40B60/08
CPC分类号： B01L3/50255 , B01L2200/0631 , B01L2300/0829 , B01L2300/087 , B01L2400/0409 , B01L2400/0487 , G01N33/6803 , G01N35/00
摘要： This invention relates to a kit and a method for the collection and analysis of complex protein mixtures. More particularly, the invention relates to a kit comprising a single barrel filtration well or a multi-well filtration plate wherein each well comprises an upper filtration zone; a lower filtration zone; a conical flow director zone; and, an elution tip, wherein the upper filtration zone and the lower filtration zone are separated by a retainer ring disposed within the lower filtration zone. The upper filtration zone comprises an upper collection zone, a sponge zone, and a deep bed filtration zone; and, the lower filtration zone comprises the retainer ring, a supported hydrophilic membrane and a lower bed filtration media. When used with an array of selected buffer solutions, the multi-well filtration plate can provide accurate, automated, high-throughput protein analysis by affinity chromatography.

3. 发明授权

US07329624B1 Regenerable adsorbents for the purification of silicone based solvents 失效
标题翻译：用于纯化硅酮溶剂的可再生吸附剂
公开(公告)号：US07329624B1
公开(公告)日：2008-02-12
申请号：US11130649
申请日：2005-05-17
申请人： Laszlo T. Nemeth , Anil R. Oroskar , Santi Kulprathipanja , Rusty M. Pittman
发明人： Laszlo T. Nemeth , Anil R. Oroskar , Santi Kulprathipanja , Rusty M. Pittman
IPC分类号： B01J37/30
CPC分类号： C07F7/20 , C07F7/089
摘要： An adsorbent for removal of impurities from silicone based solvents is presented. The adsorbent is regenerable for repeated use in cleaning silicone based solvents.
摘要翻译：提出了一种用于从有机硅类溶剂中除去杂质的吸附剂。吸附剂可再生，以重复使用以清洁硅酮类溶剂。

4. 发明授权

US07258795B1 Regenerable adsorbents for purification of cleaning solvents 失效
标题翻译：用于净化清洁溶剂的可再生吸附剂
公开(公告)号：US07258795B1
公开(公告)日：2007-08-21
申请号：US11260965
申请日：2005-10-28
申请人： Laszlo T. Nemeth , Anil R. Oroskar , Edith M. Flanigen
发明人： Laszlo T. Nemeth , Anil R. Oroskar , Edith M. Flanigen
IPC分类号： B01D15/00
CPC分类号： B01D15/00 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/186 , B01J20/20 , B01J20/205 , B01J20/28064 , B01J20/28078 , B01J20/3057 , B01J20/3204 , B01J20/3236 , B01J20/3433 , B01J20/3483
摘要： A process and adsorbent for removing contaminants from silicone based solvents is disclosed. The process provides for cleaning a solvent for reuse, and regeneration of the adsorbent. The adsorbents are for adsorbing organic and inorganic compounds that have accumulated in the silicone solvents.
摘要翻译：公开了一种用于从有机硅基溶剂中除去污染物的方法和吸附剂。该方法提供清洗溶剂以便再利用和再生吸附剂。吸附剂用于吸附积聚在有机硅溶剂中的有机和无机化合物。

5. 发明授权

US07112307B2 Riser reactor system for hydrocarbon cracking 失效
标题翻译：用于烃开裂的提升管反应器系统
公开(公告)号：US07112307B2
公开(公告)日：2006-09-26
申请号：US10868052
申请日：2004-06-15
申请人： Hayim Abrevaya , Joel T. Walenga , Michael A. Schultz , Anil R. Oroskar
发明人： Hayim Abrevaya , Joel T. Walenga , Michael A. Schultz , Anil R. Oroskar
IPC分类号： B01J8/26 , B01J8/12
CPC分类号： C07C4/06 , C07C11/06 , C07C11/04
摘要： A riser reactor system for conversion of hydrocarbon feedstock to ethylene and propylene is described. The riser reactor system prevents riser reactors with a plurality of inlet ports for feeding gases having different compositions and for controlling the residence time of a gas catalyst within the riser reactor.
摘要翻译：描述了用于将烃原料转化成乙烯和丙烯的提升管反应器系统。提升管反应器系统防止具有多个入口端口的提升管反应器用于进料具有不同组成的气体并用于控制气体催化剂在提升管反应器内的停留时间。

6. 发明授权

US06506510B1 Hydrogen generation via methane cracking for integrated heat and electricity production using a fuel cell 失效
标题翻译：使用燃料电池进行集成热电生产的甲烷裂解产生氢气
公开(公告)号：US06506510B1
公开(公告)日：2003-01-14
申请号：US09737990
申请日：2000-12-15
申请人： Daniel R. Sioui , Gavin P. Towler , Anil R. Oroskar , Lubo Zhou , Stephen R. Dunne , Santi Kulprathipanja , Leonid B. Galperin , Frank S. Modica , Timur V. Voskoboinikov
发明人： Daniel R. Sioui , Gavin P. Towler , Anil R. Oroskar , Lubo Zhou , Stephen R. Dunne , Santi Kulprathipanja , Leonid B. Galperin , Frank S. Modica , Timur V. Voskoboinikov
IPC分类号： H01M804
CPC分类号： H01M8/04014 , H01M8/0612
摘要： A novel integrated system for the co-production of heat and electricity for residences or commercial buildings is based on the cracking of hydrocarbons to generate hydrogen for a fuel cell. Compared to prior art reforming methods for hydrogen production, the cracking reaction provides an input stream to the fuel cell that is essentially free of CO, a known poison to the anode catalyst in many fuel cell designs, such as PEM fuel cells. The cracking reaction is coupled with an air or steam regeneration cycle to reactivate that cracking catalyst for further use. This regeneration can provide a valuable source of heat or furnace fuel to the system. A novel control method for system adjusts the durations of the cracking and regeneration cycles to optimize the recovery of reaction heat.
摘要翻译：用于住宅或商业建筑共同生产热电的新型综合系统是基于碳氢化合物的裂解以产生燃料电池的氢气。与现有技术的用于氢气生产的重整方法相比，裂化反应为燃料电池提供基本上不含CO的输入流，这是许多燃料电池设计中的阳极催化剂的已知毒物，例如PEM燃料电池。裂化反应与空气或蒸汽再生循环相结合，使该裂化催化剂再次使用。这种再生可以为系统提供有价值的热源或炉燃料。一种新颖的系统控制方法，可以调节裂解和再生循环的持续时间，以优化反应热的回收。

7. 发明授权

US5856606A Turbulent bed solid catalyst hydrocarbon alkylation process 失效
标题翻译：湍流床固体催化剂烃烷基化方法
公开(公告)号：US5856606A
公开(公告)日：1999-01-05
申请号：US723207
申请日：1996-09-27
申请人： Anil R. Oroskar
发明人： Anil R. Oroskar
IPC分类号： C07C2/58 , C07C2/66 , C07C2/64 , C07C2/56
CPC分类号： C07C2/58 , C07C2/66
摘要： Paraffins or other hydrocarbons are alkylated in a process featuring a reaction zone containing a pool of liquid maintained at its boiling point and containing a suspended solid catalyst, which allows the heat of reaction to vaporize a portion of the liquid phase feed hydrocarbon. The vapor phase withdrawn from the top of the reaction zone is at least partially recycled to the reaction zone either as vapor or liquid. The feed hydrocarbons are introduced to the bottom of the reaction zone as a vapor phase stream, which may contain hydrogen. The catalyst is suspended within the liquid in the reaction zone.
摘要翻译：石蜡或其他烃在具有包含保持在其沸点并含有悬浮固体催化剂的液体池的反应区的过程中烷基化，其允许反应热量蒸发一部分液相进料烃。从反应区顶部排出的气相至少部分地以蒸气或液体的方式再循环到反应区。原料烃以可能含有氢的气相物流引入反应区的底部。催化剂悬浮在反应区内的液体中。

8. 发明授权

US5849977A Metal cation-modified alkylation catalysts 失效
标题翻译：金属阳离子改性烷基化催化剂
公开(公告)号：US5849977A
公开(公告)日：1998-12-15
申请号：US630318
申请日：1996-04-10
申请人： Joseph A. Kocal , Anil R. Oroskar
发明人： Joseph A. Kocal , Anil R. Oroskar
IPC分类号： B01J23/02 , B01J23/04 , B01J27/08 , C07C2/58
CPC分类号： B01J23/02 , B01J23/04 , B01J27/08 , C07C2/58 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/12 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755 , C07C2527/125 , C07C2527/126
摘要： A process for the alkylation of alkenes having from 2 to 6 carbon atoms with an alkane having from 4 to 6 carbon atoms to afford an alkylate comprises reacting in the liquid phase the alkene and alkane under alkylation conditions in the presence of a novel catalyst comprising: a) a refractory inorganic oxide, b) the reaction product of a first metal halide and bound surface hydroxyl groups of the refractory inorganic oxide, c) a second metal cation, and d) optionally a zerovalent third metal. The refractory inorganic oxide is selected form the group consisting of alumina, titania, zirconia, chromia, silica, boria, silica-alumina, and combinations thereof and the first metal halide is a fluoride, chloride, or bromide of aluminum or boron. The second metal cation is selected from the group consisting of: monovalent metal cations in an amount from 0.0026 up to about 0.20 gram atoms per 100 grams refractory inorganic oxide for lithium, potassium, cesium, rubidium, silver, and copper, and from 0.012 to about 0.12 gram atoms for sodium; and alkaline earth metal cations in an amount from about 0.0013 up to about 0.01 gram atoms per 100 grams of refractory inorganic oxide for beryllium, strontium, and barium, and in an amount from about 0.004 up to about 0.1 gram atoms per 100 grams support for magnesium and calcium, or combinations thereof. The third metal is selected from the group consisting of platinum, palladium, nickel ruthenium, rhodium, osmium and iridium, and any combination thereof.
摘要翻译：具有2至6个碳原子的烯烃与具有4至6个碳原子的烷烃烷基化以得到烷基化物的方法包括在烷烃化反应条件下在液相中在烯烃和烷烃的存在下，在新催化剂下反应的方法包括： a）耐火无机氧化物，b）第一金属卤化物与耐火无机氧化物的结合表面羟基的反应产物，c）第二金属阳离子，和d）任选的零价第三金属。耐火无机氧化物选自氧化铝，二氧化钛，氧化锆，氧化铬，二氧化硅，氧化硼，二氧化硅 - 氧化铝及其组合，第一金属卤化物是铝或硼的氟化物，氯化物或溴化物。第二金属阳离子选自：一价金属阳离子，其量为0.0026至约0.20克原子/ 100克锂，钾，铯，铷，银和铜的耐火无机氧化物，并且0.012至约0.12克原子钠; 和碱土金属阳离子，其量为约0.0013至约0.01克原子/ 100克铍，锶和钡的耐火无机氧化物，其量为约0.004至约0.1克原子/ 100克载体镁和钙，或其组合。第三种金属选自铂，钯，镍钌，铑，锇和铱，以及它们的任何组合。

9. 发明授权

US5220102A Process for separating normal olefins from non-normal olefins 失效
标题翻译：从正常烯烃分离正常烯烃的方法
公开(公告)号：US5220102A
公开(公告)日：1993-06-15
申请号：US895769
申请日：1992-06-09
申请人： Gregory A. Funk , James R. Lansbarkis , Anil R. Oroskar , Beth McCulloch
发明人： Gregory A. Funk , James R. Lansbarkis , Anil R. Oroskar , Beth McCulloch
IPC分类号： C07C7/13
CPC分类号： C07C7/13
摘要： A chromatographic process for separating linear olefins from mixtures with branched-chain olefins with a high silica zeolitic molecular sieve, e.g., silicalites, ZSM-5, etc., having low acid catalytic reactivity, which selectively adsorbs the normal olefins, and uses ketones as desorbents.
摘要翻译：使用具有低酸催化反应性的高硅沸石分子筛（例如硅沸石，ZSM-5等）从支链烯烃与混合物中分离线性烯烃的色谱法，其选择性吸附普通烯烃，并使用酮作为脱矿

10. 发明授权

US4851573A Separation of citric acid from fermentation broth with a weakly basic anionic exchange resin adsorbent 失效
标题翻译：用弱碱性阴离子交换树脂吸附剂从发酵液中分离柠檬酸
公开(公告)号：US4851573A
公开(公告)日：1989-07-25
申请号：US121830
申请日：1987-11-16
申请人： Santi Kulprathipanja , Anil R. Oroskar , James W. Priegnitz
发明人： Santi Kulprathipanja , Anil R. Oroskar , James W. Priegnitz
IPC分类号： C07C51/47
CPC分类号： C07C51/47
摘要： Citric acid is separated from a fermentation broth by using an adsorbent comprising a water-insoluble macroreticular or gel weakly basic anionic exchange resin possessing tertiary amine functional groups or pyridine functional groups, said anionic exchange resin comprising a cross-linked acrylic or styrene resin matrix. Citric acid is desorbed by water or dilute sulfuric acid. The pH of the feed is maintained below the first ionization constant (pKa.sub.1) of citric acid to maintain selectivity.
摘要翻译：通过使用包含具有叔胺官能团或吡啶官能团的水不溶性大网络或凝胶弱碱性阴离子交换树脂的吸附剂将柠檬酸与发酵液分离，所述阴离子交换树脂包含交联的丙烯酸或苯乙烯树脂基质。柠檬酸被水或稀硫酸解吸。饲料的pH值保持在柠檬酸的第一电离常数（pKa1）以下以保持选择性。

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