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1. 发明授权

US07273919B1 High heat polyethersulfone compositions 有权
标题翻译：高热聚醚砜组合物
公开(公告)号：US07273919B1
公开(公告)日：2007-09-25
申请号：US11286181
申请日：2005-11-21
申请人： Daniel Steiger , Farid Fouad Khouri , Daniel Joseph Brunelle , Amy Beth Koren
发明人： Daniel Steiger , Farid Fouad Khouri , Daniel Joseph Brunelle , Amy Beth Koren
IPC分类号： C08G75/00 , C08G61/02 , C08G65/38 , C08G65/40
CPC分类号： C08G75/23
摘要： High heat polyethersulfone compositions are provided which possess unexpectedly high glass transition temperatures. The polyethersulfone compositions comprise structural units derived from phthalimide bisphenols such as 3,3-bis(4 -hydroxyphenyl)-N-phenylphthalimide, and structural units derived from at least one biphenyl-bissulfone such as 4,4′-bis((4-chlorophenyl)sulfonyl)-1,1′-biphenyl. The novel polyethersulfone compositions may further comprise structural units derived from one or more biphenols such as 4,4′-biphenol, bisphenols such as BPA, or other electrophilic sulfone monomers, such as bis(4-chlorophenyl)sulfone. In one embodiment, the polyethersulfone composition of the present invention comprises structural groups derived exclusively from 3,3-bis(4-hydroxyphenyl)-N-phenylphthalimide, and 4,4′-bis((4-chlorophenyl)sulfonyl)-1,1′-biphenyl and exhibits a single glass transition of greater than 300° C.
摘要翻译：提供了具有出人意料的高玻璃化转变温度的高热聚醚砜组合物。聚醚砜组合物包含衍生自邻苯二甲酰亚胺双酚的结构单元，例如3,3-双（4-羟基苯基）-N-苯基邻苯二甲酰亚胺，以及衍生自至少一种联苯基 - 砜的结构单元，例如4,4'-双（（4- 氯苯基）磺酰基）-1,1'-联苯。新型聚醚砜组合物还可以包含衍生自一种或多种双酚的结构单元，例如4,4'-联苯酚，双酚如BPA或其它亲电子砜单体如双（4-氯苯基）砜。在一个实施方案中，本发明的聚醚砜组合物包含仅由3,3-双（4-羟基苯基）-N-苯基邻苯二甲酰亚胺衍生的结构基团和4,4'-双（（4-氯苯基）磺酰基） 1'-联苯并且表现出大于300℃的单一玻璃化转变。

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