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1. 发明授权

US06417269B1 Methods of making modified condensation polymers 失效
标题翻译：改性缩聚物的制备方法
公开(公告)号：US06417269B1
公开(公告)日：2002-07-09
申请号：US09617653
申请日：2000-07-17
申请人： David Logan Murray , Allan Scott Jones , Douglas Weldon Carico, Jr. , Sara Stanley Wells
发明人： David Logan Murray , Allan Scott Jones , Douglas Weldon Carico, Jr. , Sara Stanley Wells
IPC分类号： C08F208
CPC分类号： C08J11/24 , C08J2367/02 , Y02W30/706
摘要： The invention pertains to methods for preparing modified condensation polymers wherein the steps include: preparing a polymer colloid system comprising a first polymer dispersed in a liquid continuous phase; introducing the polymer colloid system into a condensation reaction medium prior to or during the condensation reaction, wherein the condensation reaction medium comprises (1) a diacid, di-isocyanate, dialkyl carbonate, diaryl carbonate, dihalo carbonate or a mixture thereof, wherein the condensation reaction medium optionally comprises a diol component; and polymerizing the diol component and component (1), thereby forming a modified condensation polymer.
摘要翻译：本发明涉及制备改性缩聚物的方法，其中步骤包括：制备包含分散在液体连续相中的第一聚合物的聚合物胶体体系; 在缩合反应之前或期间将聚合物胶体系统引入缩合反应介质中，其中缩合反应介质包括（1）二酸，二异氰酸酯，碳酸二烷基酯，碳酸二芳基酯，二卤代碳酸酯或其混合物，其中缩合反应介质任选地包含二醇组分; 并使二醇组分和组分（1）聚合，从而形成改性缩合聚合物。

2. 发明授权

US06329462B1 Nylon 6/silicone blends 失效
标题翻译：尼龙6 /硅胶混纺
公开(公告)号：US06329462B1
公开(公告)日：2001-12-11
申请号：US09517464
申请日：2000-03-02
申请人： Wesley R. Hale , David Logan Murray , Allan Scott Jones
发明人： Wesley R. Hale , David Logan Murray , Allan Scott Jones
IPC分类号： C08K5419
CPC分类号： C08L77/02 , C08G69/04 , C08G69/08 , C08G69/16 , C08G77/06 , C08G77/14 , C08G77/20 , C08G77/26 , C08G77/28 , C08G77/42 , C08G77/70 , C08L83/04 , C08L83/00 , C08L2666/14
摘要： In one aspect, the invention provides a method of making a nylon 6/silicone polymer blend comprising the steps of preparing a silicone polymer emulsion comprising a silicone polymer dispersed in a liquid continuous phase; introducing the silicone polymer emulsion into a nylon 6 ring opening reaction either prior to or during the nylon 6 ring opening reaction medium wherein the reaction medium comprises caprolactam; and opening the ring and reacting the caprolactam, thereby providing a nylon 6/silicone polymer emulsion blend. Nylon 6/silicone polymer blends are also provided by the invention herein.
摘要翻译：一方面，本发明提供了制备尼龙6 /硅氧烷聚合物共混物的方法，其包括以下步骤：制备包含分散在液体连续相中的硅氧烷聚合物的硅氧烷聚合物乳液; 在尼龙6开环反应介质之前或期间将硅氧烷聚合物乳液引入尼龙6开环反应中，其中反应介质包含己内酰胺; 并打开环并使己内酰胺反应，从而提供尼龙6 /硅氧烷聚合物乳液共混物。本发明也提供尼龙6 /硅氧烷聚合物共混物。

3. 发明授权

US6001952A Polyester containing benzylidene having reduced fluorescence 失效
标题翻译：含有亚苄基的聚酯具有降低的荧光
公开(公告)号：US6001952A
公开(公告)日：1999-12-14
申请号：US095036
申请日：1998-06-10
申请人： Karen Lynn Carman , Martin Emerson Rogers , Allan Scott Jones , Max Allen Weaver
发明人： Karen Lynn Carman , Martin Emerson Rogers , Allan Scott Jones , Max Allen Weaver
IPC分类号： C08G63/685 , C08K5/00 , C08K5/315 , C08L67/02 , C08G63/00
CPC分类号： C08K5/0008 , C08G63/6854 , C08K5/315 , C08L67/02
摘要： A polymer composition having naphthalenedicarboxylic residue includes a fluorescence quenching benzylidene compound capable of absorbing ultraviolet light radiation. In a preferred embodiment, the composition includes at least a 0.1 mole percent of naphthalene-2,6-dicarboxylate and about 0.01 mole percent to about 5 mole percent of a benzylidene compound having the following structure: ##STR1## wherein R is selected from the group consisting of hydrogen, C.sub.1 -C.sub.8 alkyl, substituted C.sub.1 -C.sub.8 alkyl, C.sub.3 -C.sub.8 alkenyl, C.sub.3 -C.sub.8 alkynyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.8 cycloalkenyl and --R.sub.2 --X, wherein R.sub.2 is selected from the group consisting of C.sub.1 -C.sub.8 alkylene, C.sub.2 -C.sub.8 alkylene-O--C.sub.2 -C.sub.8 alkylene, C.sub.2 -C.sub.8 alkylene-S--C.sub.1 -C.sub.8 alkylene, C.sub.2 -C.sub.8 alkylene, C.sub.2 -C.sub.8 alkylene-S--C.sub.2 -C.sub.8 alkylene, C.sub.2 -C.sub.8 alkylene-N(SO.sub.2 C.sub.1-C.sub.8 alkyl)-C.sub.2 -C.sub.8 alkylene and X is selected from the group consisting of hydroxy, carboxy, carboalkoxy and acyloxy; R.sub.1 is hydrogen or has 1-3 groups independently selected from the group consisting of hydroxy, C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkoxy and halogen; Y is selected from the group consisting of carbalkoxy, cyano, carbamoyl, substituted carbamoyl, aryl, aroyl, C.sub.1 -C.sub.8 alkylsulfonyl and arylsulfonyl.
摘要翻译：具有萘二羧酸残基的聚合物组合物包括能够吸收紫外光辐射的荧光淬灭亚苄基化合物。在优选的实施方案中，组合物包含至少0.1摩尔％的2,6-二甲酸萘酯和约0.01摩尔％至约5摩尔％的具有以下结构的亚苄基化合物：其中R选自氢，C1-C8烷基，取代的C1-C8烷基，C3-C8烯基，C3-C8炔基，C3-C8环烷基，C3-C8环烯基和-R2-X，其中R2选自C1-C8 亚烷基，C2-C8亚烷基-O-C2-C8亚烷基，C2-C8亚烷基-S-C1-C8亚烷基，C2-C8亚烷基，C2-C8亚烷基-S-C2-C8亚烷基，C2-C8亚烷基-N（ SO 2 C 1 -C 8烷基）-C 2 -C 8亚烷基，X选自羟基，羧基，烷氧羰基和酰氧基; R 1是氢或具有1-3个独立地选自羟基，C 1 -C 8烷基，C 1 -C 8烷氧基和卤素的基团; Y选自烷氧基，氰基，氨基甲酰基，取代的氨基甲酰基，芳基，芳酰基，C 1 -C 8烷基磺酰基和芳基磺酰基。

4. 发明授权

US5919403A Polymeric fluorescence quenching compounds and their use 失效
标题翻译：聚合物荧光猝灭化合物及其用途
公开(公告)号：US5919403A
公开(公告)日：1999-07-06
申请号：US578873
申请日：1995-12-22
申请人： Allan Scott Jones , Jean Carroll Fleischer , Max Allen Weaver
发明人： Allan Scott Jones , Jean Carroll Fleischer , Max Allen Weaver
IPC分类号： C08G63/18 , C08G63/181 , C08G63/189 , C08G63/682 , C08G63/688 , C08L67/02 , F21V9/00 , C08G63/00 , C08G63/02
CPC分类号： C08G63/6886 , C08G63/18 , C08G63/189 , C08G63/6826 , C08L67/02
摘要： This invention relates to homopolyester compositions having fluorescence quenchers polymerized therein ("poly quenchers"). Specifically the "poly quencher" polymeric compositions comprises repeating units from(a) a dicarboxylic acid component and(b) a diol component, wherein at least one of (a) and (b) is comprised of at least one fluorescence polyquencher capable of reducing fluorescence of a polymer below the fluorescence displayed when said polyquencher is not included.
摘要翻译：本发明涉及在其中聚合有荧光猝灭剂的均聚酯组合物（“聚猝灭剂”）。具体地，“聚猝灭剂”聚合物组合物包含来自（a）二羧酸组分和（b）二醇组分的重复单元，其中（a）和（b）中的至少一个由至少一种能够还原的荧光聚合物当不包括所述聚合物时，显示出低于荧光的聚合物的荧光。

5. 发明授权

US06403698B1 Polyamide/emulsion polymer blends 失效
标题翻译：聚酰胺/乳液聚合物共混物
公开(公告)号：US06403698B1
公开(公告)日：2002-06-11
申请号：US09517501
申请日：2000-03-02
申请人： David Logan Murray , Allan Scott Jones , Wesley R. Hale , William R. Darnell
发明人： David Logan Murray , Allan Scott Jones , Wesley R. Hale , William R. Darnell
IPC分类号： C08J302
CPC分类号： C08L77/02 , C08L77/00 , C08L77/06 , C08L77/12 , C08L2666/08
摘要： The invention provides a method of making an amide-type polymer/first polymer blend comprising the steps of: a) preparing a polymer colloid system comprising a first polymer dispersed in a liquid continuous phase; b) introducing the polymer colloid system into an amide-type polymerization reaction medium prior to or during the reaction, wherein the reaction medium comprises 1) a diacid component and a diamine component, an oligomer of a diacid and a diamine component, or a mixture thereof; and c) polymerizing the components of b)1, thereby providing an amide-type polymer/first polymer blend. Polymer blends made by the methods herein are also provided.
摘要翻译：本发明提供一种制备酰胺型聚合物/第一聚合物共混物的方法，包括以下步骤：a）制备包含分散在液体连续相中的第一聚合物的聚合物胶体体系; b）在反应之前或反应期间将聚合物胶体体系引入酰胺型聚合反应介质中，其中反应介质包括1）二酸组分和二胺组分，二酸和二胺组分的低聚物或混合物的; 和c）聚合b）1的组分，从而提供酰胺型聚合物/第一聚合物共混物。还提供了通过本文方法制备的聚合物共混物。

6. 发明授权

US06353052B1 Amide-type polymer/silicone polymer blends and processes of making the same 失效
标题翻译：酰胺型聚合物/硅氧烷聚合物的共混物和制造方法
公开(公告)号：US06353052B1
公开(公告)日：2002-03-05
申请号：US09517254
申请日：2000-03-02
申请人： Allan Scott Jones , William R. Darnell , David Logan Murray , Wesley R. Hale
发明人： Allan Scott Jones , William R. Darnell , David Logan Murray , Wesley R. Hale
IPC分类号： C08K55419
CPC分类号： C08L77/10 , C08G69/04 , C08G69/265 , C08G69/32 , C08G69/44 , C08G77/06 , C08G77/14 , C08G77/16 , C08G77/20 , C08G77/26 , C08G77/28 , C08G77/70 , C08L77/00 , C08L77/06 , C08L77/12 , C08L83/00 , C08L83/04 , C08L2666/14
摘要： The invention provides a method of making an amide-type polymer/silicone polymer blend comprising the steps of preparing a silicone polymer emulsion comprising a silicone polymer dispersed in a liquid continuous phase; introducing the silicone polymer emulsion into an amide-type polymerization reaction medium prior to or during the reaction, wherein the reaction medium comprises 1) a diacid component and a diamine component, an oligomer of a diacid and a diamine component, or a mixture thereof; and polymerizing the components of b)1, thereby providing an amide-type polymer/silicone polymer blend. A amide-type polymer/silicone polymer blends are also provided.
摘要翻译：本发明提供一种制备酰胺型聚合物/硅氧烷聚合物共混物的方法，包括以下步骤：制备包含分散在液体连续相中的硅氧烷聚合物的硅氧烷聚合物乳液; 在反应之前或期间将硅氧烷聚合物乳液引入酰胺型聚合反应介质中，其中反应介质包括1）二酸组分和二胺组分，二酸和二胺组分的低聚物或其混合物; 并聚合b）1的组分，从而提供酰胺型聚合物/硅氧烷聚合物共混物。还提供酰胺型聚合物/硅氧烷聚合物共混物。

7. 发明授权

US06417239B1 Methods of making modified condensation polymers 失效
标题翻译：改性缩聚物的制备方法
公开(公告)号：US06417239B1
公开(公告)日：2002-07-09
申请号：US09617632
申请日：2000-07-17
申请人： David Logan Murray , Allan Scott Jones , Wesley R. Hale , William R. Darnell , Douglas Weldon Carico, Jr. , Sara Stanley Wells
发明人： David Logan Murray , Allan Scott Jones , Wesley R. Hale , William R. Darnell , Douglas Weldon Carico, Jr. , Sara Stanley Wells
IPC分类号： C08J1124
CPC分类号： C08J11/24 , C08J2367/02 , Y02W30/706
摘要： The invention pertains to methods for preparing modified condensation polymers wherein the steps include: (a) preparing a polymer colloid system comprising a first polymer dispersed in a liquid continuous phase; (b) introducing the polymer colloid system into a glycolysis reaction medium prior to or during a glycolysis reaction wherein the glycolysis reaction medium comprises a polyester, copolyester, polyesteramide, polycarbonate or a mixture thereof; wherein the glycolysis reaction medium optionally comprises a diol component; and polymerizing the fully or partially glycolyzed polyester, copolyester, polyesteramide, polycarbonate or mixture thereof, thereby providing a condensation polymer/first polymer matrix.
摘要翻译：本发明涉及制备改性缩聚物的方法，其中步骤包括：（a）制备包含分散在液体连续相中的第一聚合物的聚合物胶体体系; （b）在糖酵解反应之前或期间将聚合物胶体系统引入糖酵解反应介质中，其中糖酵解反应介质包含聚酯，共聚酯，聚酯酰胺，聚碳酸酯或其混合物; 其中所述糖酵解反应介质任选地包含二醇组分; 并且使全部或部分糖酵解的聚酯，共聚酯，聚酯酰胺，聚碳酸酯或其混合物聚合，从而提供缩聚物/第一聚合物基质。

8. 发明授权

US06340726B1 Silicone polymer diol compositions and condensation polymer/silicone polymer blends 失效
标题翻译：硅氧烷聚合物二醇组合物和缩聚物/硅氧烷聚合物共混物
公开(公告)号：US06340726B1
公开(公告)日：2002-01-22
申请号：US09518071
申请日：2000-03-02
申请人： David Logan Murray , Allan Scott Jones , Wesley R. Hale
发明人： David Logan Murray , Allan Scott Jones , Wesley R. Hale
IPC分类号： C08K55419
CPC分类号： C08J3/095 , C08J3/09 , C08J2383/04 , C08L67/02 , C08L69/00 , C08L83/00
摘要： The invention herein provides a silicone polymer emulsion comprising: a) a silicone polymer; and b) a surfactant; and a liquid continuous phase comprising a diol, wherein the diol comprises from about 25 to about 100% by weight of the continuous phase. Further provided is a method of making a condensation polymer/silicone polymer blend comprising the steps of: a) preparing a silicone/polymer emulsion comprising a silicone polymer in a liquid continuous phase; b) introducing the silicone polymer emulsion into a condensation polymerization reaction medium prior to or during the condensation polymerization reaction, wherein the condensation polymerization reaction medium comprises (1) a diacid, di-isocyanate, dialkyl carbonate, diaryl carbonate, dihalo carbonate or a mixture thereof, wherein the continuous phase, the condensation polymerization reaction medium or both comprises a diol component; and c) polymerizing the diol and component b(1) thereby forming a condensation polymer/silicone polymer blend. Polymer blends comprising a condensation polymer/silicone polymer blend are also provided.
摘要翻译：本发明提供一种硅氧烷聚合物乳液，其包含：a）硅氧烷聚合物; 和b）表面活性剂; 和包含二醇的液体连续相，其中所述二醇包含约25至约100重量％的连续相。还提供了制备缩聚物/硅氧烷聚合物共混物的方法，其包括以下步骤：a）制备包含液体连续相中的硅氧烷聚合物的硅氧烷/聚合物乳液; b）在缩聚反应之前或期间将硅氧烷聚合物乳液引入缩聚反应介质中，其中缩聚反应介质包括（1）二酸，二异氰酸酯，碳酸二烷基酯，碳酸二芳基酯，二卤代碳酸酯或混合物其中连续相，缩聚反应介质或二者均包含二醇组分; 和c）使二醇和组分b（1）聚合，由此形成缩聚物/硅氧烷聚合物共混物。还提供了包含缩聚物/硅氧烷聚合物共混物的聚合物共混物。

9. 发明授权

US6103857A Poly(ethylene terephthalate) (PET) copolymers containing both 1,4-cyclohexanedimethanol and isophthalic acid moieties 失效
标题翻译：含有1,4-环己烷二甲醇和间苯二甲酸部分的聚（对苯二甲酸乙二醇酯）（PET）共聚物
公开(公告)号：US6103857A
公开(公告)日：2000-08-15
申请号：US96278
申请日：1998-06-11
申请人： Allan Scott Jones , Timothy Edward Long , Sara Stanley Wells
发明人： Allan Scott Jones , Timothy Edward Long , Sara Stanley Wells
IPC分类号： C08G63/181 , C08G63/199 , C08G63/02
CPC分类号： C08G63/199 , C08G63/181
摘要： This invention relates to PET copolymer composition that have both 1,4-cyclohexanedimethal (CHDM) and isophthalic acid moieties copolymerized. These compositions have better oxygen and carbon dioxide barrier properties than either PET homopolymer or CHDM-modified PET copolymers. These copolymer compositions are useful for packaging applications (such as carbonated soft drink bottles) requiring barrier properties to oxygen and carbon dioxide at least as good or better than PET homopolymer.
摘要翻译：本发明涉及共聚有1,4-环己烷二甲醇（CHDM）和间苯二甲酸部分的PET共聚物组合物。这些组合物比PET均聚物或CHDM改性的PET共聚物具有更好的氧气和二氧化碳阻隔性能。这些共聚物组合物可用于包装应用（例如碳酸软饮料瓶），其需要至少与PET均聚物一样好或优于对氧和二氧化碳的阻隔性。

10. 发明授权

US5705600A Polyester/naphthalenedicarboxylic acid-containing polymer blends displaying reduced fluorescence 失效
标题翻译：聚酯/萘二甲酸的聚合物共混物显示出降低的荧光
公开(公告)号：US5705600A
公开(公告)日：1998-01-06
申请号：US577796
申请日：1995-12-22
申请人： Allan Scott Jones , Jean Carroll Fleischer , Max Allen Weaver
发明人： Allan Scott Jones , Jean Carroll Fleischer , Max Allen Weaver
IPC分类号： C08L67/02 , C08L77/12 , C08G63/189
CPC分类号： C08L67/02 , C08L77/12
摘要： The present invention relates to blends of a polyester, polyamide or polyester/amide containing a copolymerizable fluorescence quenching compound and a second polymer. The blends of the present invention display reduced fluorescence. Specifically the blends comprise (a) a polyester/amide comprising: (1) a dicarboxylic acid component which comprises at least 0.1 mol % of a dicarboxylic acid selected from the group consisting of terephthalic acid and/or terephthalate ester; (2) a diol and/or diamine component; (3) 0.1 to 99.9 mol %, based on 100 mol % dicarboxylic acid and 100 mol % diol, of a copolymerizable fluorescence quenching compound; (b) a second polymer selected from the group poly(alkylene terephthalate) homo and copolyesters, poly(alkylene naphthalate) homo and copolyesters, poly(cycloalkylene terephthalate) homo and copolyesters, poly(alkylene 1,4-cyclohexanedicarboxylate) homo and copolyesters, and polycarbonate homo and copolymers.
摘要翻译：本发明涉及含可共聚荧光淬灭化合物和第二聚合物的聚酯，聚酰胺或聚酯/酰胺的共混物。本发明的共混物显示出降低的荧光。具体地，共混物包含（a）聚酯/酰胺，其包含：（1）二羧酸组分，其包含至少0.1mol％的选自对苯二甲酸和/或对苯二甲酸酯的二羧酸; （2）二醇和/或二胺组分; （3）相对于100摩尔％二羧酸和100摩尔％二醇的可共聚荧光淬灭化合物为0.1〜99.9摩尔％（b）选自聚（对苯二甲酸亚烷基酯）均聚和共聚酯，聚（萘二甲酸亚烷基酯）均聚和共聚酯，聚（对苯二甲酸亚烷基酯）共聚酯和共聚酯，聚（1,4-环己烷二羧酸亚烷基酯）均聚和共聚酯的第二聚合物，和聚碳酸酯均聚物和共聚物。

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