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    • 1. 发明授权
    • Smoking article including a filter for selectively removing carbonyls
    • 吸烟制品包括用于选择性除去羰基的过滤器
    • US06481442B1
    • 2002-11-19
    • US09723842
    • 2000-11-28
    • Alexander J. DyakonovDavid A. GriderTatyana A. Dyakonov
    • Alexander J. DyakonovDavid A. GriderTatyana A. Dyakonov
    • A24D104
    • A24D3/166A24D3/08A24D3/14A24D3/163
    • A smoking article including a wrapper surrounding a tobacco column and a selective filter element is disclosed. The selective filter element includes at least one carrier having a developed structure and a plurality of moieties capable of the nucleophilic attack of carbonyl-containing combustion products of the smoking article supported by the at least one carrier. The selective filter element may include at least one additional filter element such as cellulose acetate. The developed structure of the at least one carrier encourages the interaction of the carbonyl-containing combustion products and the plurality of moieties capable of the nucleophilic attack. Carries include polymers, which may have branch, such as partially oxidized cellulose and polyaniline. Carries may also be a zeolite or an inorganic oxide such as aluminum, of silicon, of aluminum and silicon, and combinations thereof. In yet another carrier is an activated carbon. A moiety capable of the nucleophillic attack includes a nitrogen and hydrogen containing group such as a hydrazide—(e.g., —NH—NH2), a hydrazone—(e.g., —HC═N—NH2), a semicarbazide—(e.g., —C(═O)—NH2), an imino—(e.g., —HC═NH), and an amino—(—NH2). Preferably, the nitrogen is a primary nitrogen such as a primary amino. A spacer may be used to attach the moiety to a carrier. Examples of spacers include at least one of a —CO— group, —CO—[CH2]n—CO— group with n=1 through 4 and more.
    • 公开了一种包括围绕烟草柱和选择性过滤元件的包装物的吸烟制品。 选择性过滤元件包括具有显影结构的至少一个载体和能够由至少一个载体支撑的吸烟制品的含羰基燃烧产物的亲核攻击的多个部分。 选择性过滤元件可以包括至少一种额外的过滤元件,例如醋酸纤维素。 所述至少一种载体的显影结构促进了含羰基燃烧产物和能够进行亲核攻击的多个部分的相互作用。 载体包括可以具有分支的聚合物,例如部分氧化的纤维素和聚苯胺。 携带物也可以是沸石或无机氧化物如铝,硅,铝和硅及其组合。 在另一载体中是活性炭。 能够进行嗜盐性攻击的部分包括含氮和氢的基团,例如酰肼 - (例如-NH-NH 2),腙 - (例如-HC = N-NH 2),氨基脲 - (例如-C (= O)-NH 2),亚氨基 - (例如-HC = NH)和氨基 - ( - NH 2)。 优选地,氮是初级氮,例如伯氨基。 可以使用间隔物将部分连接到载体上。 间隔基的实例包括具有n = 1至4以上的-CO-基团,-CO- [CH 2] n -CO-基团中的至少一个。
    • 2. 发明申请
    • Method of Imparting Reduced Ignition Propensity to Smoking Articles Using Phase Transition Materials
    • 使用相转移材料降低点烟倾向吸烟制品的方法
    • US20120305012A1
    • 2012-12-06
    • US13411876
    • 2012-03-05
    • Alexander J. DyakonovSteven E. BrownLuis A. Sanchez
    • Alexander J. DyakonovSteven E. BrownLuis A. Sanchez
    • A24C5/00
    • A24D1/025
    • A method for imparting reduced ignition propensity properties to a smoking article by treating the smoking article wrapper with a phase transition substance which, upon being subjected to the heat of the smoking article burning firecone, physically transforms and at least partially fills the pores of the smoking article wrapper to reduce the permeability of the wrapper in the vicinity of the burning firecone. The reduced permeability of the wrapper in the vicinity of the firecone will permit sufficient air flow to sustain free burn, but, when the smoking article is placed on a substrate, the reduced permeability of the wrapper imparts reduced ignition propensity such that there is insufficient air flow to sustain combustion of the firecone or insufficient air flow to sustain an intensity of the burning firecone necessary to ignite the substrate.
    • 一种通过用相变物质处理吸烟制品包装物来向吸烟制品赋予降低的点火倾向特性的方法,所述相转移物质在经受吸烟制品燃烧火焰的热量后物理转化并且至少部分地填充吸烟孔 用于减少燃烧火焰附近包装物的渗透性的物品包装物。 包裹物在火舌附近的渗透性降低将允许足够的空气流动以维持自由燃烧,但是当将吸烟物体放置在基底上时,包裹物的渗透性降低赋予降低的点火倾向,使得空气不足 流动以维持火焰的燃烧或气流不足以维持点燃基板所需的燃烧火焰的强度。
    • 3. 发明申请
    • Phase Transition Compositions Used to Impart Reduced Ignition Propensity to Smoking Articles
    • 用于减少点烟倾向的相变组合物
    • US20120298126A1
    • 2012-11-29
    • US13415728
    • 2012-03-08
    • Alexander J. DyakonovSteven E. BrownLuis A. Sanchez
    • Alexander J. DyakonovSteven E. BrownLuis A. Sanchez
    • C09K21/14C10L10/00C10G73/00A24D1/02
    • A24D1/025C09K5/063
    • A composition for imparting reduced ignition propensity properties to a smoking article by treating the smoking article wrapper. The composition comprising at least one phase transition substance which, upon being subjected to the heat of the smoking article burning firecone, physically transforms and at least partially fills the pores of the smoking article wrapper to reduce the permeability of the wrapper in the vicinity of the burning firecone. The reduced permeability of the wrapper in the vicinity of the firecone will permit sufficient air flow to sustain free burn, but, when the smoking article is placed on a substrate, the reduced permeability of the wrapper imparts reduced ignition propensity such that there is insufficient air flow to sustain combustion of the firecone or insufficient air flow to sustain an intensity of the burning firecone necessary to ignite the substrate.
    • 一种用于通过处理吸烟制品包装物来向吸烟制品赋予降低的点燃倾向性质的组合物。 所述组合物包含至少一种相转移物质,所述相转移物质在经受所述吸烟制品燃烧火焰的热量后物理转化并且至少部分地填充所述吸烟制品包装物的孔隙,以减少所述包装物在所述吸烟制品附近的渗透性 燃烧火鸡 包裹物在火舌附近的渗透性降低将允许足够的空气流动以维持自由燃烧,但是当将吸烟物体放置在基底上时,包裹物的渗透性降低赋予降低的点火倾向,使得空气不足 流动以维持火焰的燃烧或气流不足以维持点燃基板所需的燃烧火焰的强度。
    • 4. 发明授权
    • Method of applying phase transition materials to semi-porous, flexible substrates used to control gas permeability
    • 将相变材料施加到用于控制气体渗透性的半孔,柔性基材上的方法
    • US09038644B2
    • 2015-05-26
    • US13412357
    • 2012-03-05
    • Steven E. BrownAlexander J. DyakonovLuis A. Sanchez
    • Steven E. BrownAlexander J. DyakonovLuis A. Sanchez
    • A24D1/02
    • A24D1/025
    • Method of applying phase transition substance to impart reduced ignition propensity to a smoking article comprising a tobacco column and a wrapper surrounding the tobacco column and having a porous structure with a base permeability. The method comprising forming a pattern of phase transition material on the wrapper such that, when subjected to the heat of the tobacco column burning firecone, the phase transition material at least partially fills the wrapper porous structure in the vicinity of the burning firecone to form an area on the wrapper having reduced permeability lower than that of the wrapper base permeability. The reduced permeability of the wrapper in the vicinity of the burning firecone imparts reduced ignition propensity such that there is insufficient air flow to sustain combustion of the firecone or insufficient air flow to sustain an intensity of the burning firecone necessary to ignite the substrate.
    • 施加相变物质以赋予包括烟草柱和围绕烟草柱的包装物并且具有基础渗透性的多孔结构的吸烟制品降低的点火倾向的方法。 所述方法包括在包装上形成相变材料的图案,使得当经受烟草柱燃烧火焰的热时,相变材料至少部分地填充燃烧火舌附近的包裹多孔结构,以形成 包装纸上的面积比包装纸底部透气性的渗透性降低。 包裹物在燃烧式火炉附近的渗透性降低赋予了降低的点火倾向,使得气流不足以维持火焰的燃烧或空气流不足以维持点燃基板所需的燃烧火焰的强度。
    • 5. 发明申请
    • Method of Applying Phase Transition Materials to Semi-Porous, Flexible Substrates Used to Control Gas Permeability
    • 将相转移材料应用于用于控制透气性的半多孔柔性基板的方法
    • US20120305013A1
    • 2012-12-06
    • US13412357
    • 2012-03-05
    • Steven E. BrownAlexander J. DyakonovLuis A. Sanchez
    • Steven E. BrownAlexander J. DyakonovLuis A. Sanchez
    • A24C5/00
    • A24D1/025
    • Method of applying phase transition substance to impart reduced ignition propensity to a smoking article comprising a tobacco column and a wrapper surrounding the tobacco column and having a porous structure with a base permeability. The method comprising forming a pattern of phase transition material on the wrapper such that, when subjected to the heat of the tobacco column burning firecone, the phase transition material at least partially fills the wrapper porous structure in the vicinity of the burning firecone to form an area on the wrapper having reduced permeability lower than that of the wrapper base permeability. The reduced permeability of the wrapper in the vicinity of the burning firecone imparts reduced ignition propensity such that there is insufficient air flow to sustain combustion of the firecone or insufficient air flow to sustain an intensity of the burning firecone necessary to ignite the substrate.
    • 施加相变物质以赋予包括烟草柱和围绕烟草柱的包装物并且具有基础渗透性的多孔结构的吸烟制品降低的点火倾向的方法。 所述方法包括在包装上形成相变材料的图案,使得当经受烟草柱燃烧火焰的热时,相变材料至少部分地填充燃烧火舌附近的包裹多孔结构,以形成 包装纸上的面积比包装纸底部透气性的渗透性降低。 包裹物在燃烧式火炉附近的渗透性降低赋予了降低的点火倾向,使得气流不足以维持火焰的燃烧或空气流不足以维持点燃基板所需的燃烧火焰的强度。