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1. 发明授权

US08101254B2 Rubber composition, crosslinked product and foam thereof, molded product therefrom, and use thereof 有权
标题翻译：橡胶组合物，交联产物和泡沫，其成型产品及其用途
公开(公告)号：US08101254B2
公开(公告)日：2012-01-24
申请号：US12314155
申请日：2008-12-04
申请人： Yuji Noguchi , Takashi Hakuta , Hiroki Ebata , Kotaro Ichino , Shuichi Nonaka , Satoshi Hase , Kazuyoshi Kaneko , Akinori Takehara
发明人： Yuji Noguchi , Takashi Hakuta , Hiroki Ebata , Kotaro Ichino , Shuichi Nonaka , Satoshi Hase , Kazuyoshi Kaneko , Akinori Takehara
IPC分类号： C08L47/00 , C08L9/00 , C08K3/04 , B32B1/08
CPC分类号： C08L23/02 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F210/16 , C08F210/18 , C08J9/0061 , C08J9/0066 , C08J9/06 , C08J2201/024 , C08J2323/16 , C08J2423/00 , C08K3/04 , C08K3/06 , C08K3/22 , C08K3/26 , C08K3/346 , C08K5/0025 , C08K5/09 , C08K5/17 , C08L23/04 , C08L23/0815 , C08L23/10 , C08L23/16 , C08L91/00 , C08L2205/025 , C08L2312/00 , C08L2666/02 , C08L2666/06 , C08L2666/08 , C09K3/10 , C09K2200/0617 , C09K2200/062 , C09K2200/0642 , Y10T428/1386 , C08F4/6592 , C08F236/20 , C08F2500/17 , C08F210/06
摘要： The present invention provides a molded product exhibiting excellent various properties by improving compatibility of an ethylene/α-olefin/non-conjugated polyene copolymer with a polyolefin resin and a rubber composition for forming the molded product. The present invention further provides a molded product which comprises a rubber composition, is inhibited from fogging and tackiness and is excellent in mechanical strength and heat aging resistance. The rubber composition of the invention comprises an ethylene/α-olefin/non-conjugated polyene copolymer (A), and a polyolefin resin (B) having Mn of not less than 10,000 and/or an ethylene/α-olefin copolymer (C) having Mn of 2500 to 5000, and satisfies the following requirements: (1) a maximum value and a minimum value of an ethylene distribution parameter P of the component (A) have a relationship of Pmax/Pmin≦1.4, and (2) the B value of the component (C) ([EX]/(2[E]×[X])) ([E] and [X] are molar fractions of ethylene and the α-olefin of 3 to 20 carbon atoms, respectively, and [EX] is a fraction of dyad sequence of ethylene/α-olefin of 3 to 20 carbon atoms) is not more than 1.05.
摘要翻译：本发明提供通过改善乙烯/α-烯烃/非共轭多烯共聚物与聚烯烃树脂的相容性和用于形成模塑产品的橡胶组合物来显示出优异的各种性能的模制产品。本发明还提供一种包含橡胶组合物的模塑制品，其防止起雾和粘合，并且机械强度和耐热老化性优异。本发明的橡胶组合物包含乙烯/α-烯烃/非共轭多烯共聚物（A）和Mn不小于10,000的聚烯烃树脂（B）和/或乙烯/α-烯烃共聚物（C） Mn为2500〜5000，满足以下要求：（1）成分（A）的乙烯分布参数P的最大值和最小值具有Pmax / Pmin＆lt; N1和1.4的关系，（2）组分（C）（[EX] /（2 [E]×[X]））（[E]和[X]）分别为乙烯和3-20个碳原子的α-烯烃的摩尔分数，[EX]为3〜20个碳原子的乙烯/α-烯烃的二元序列的分数）不大于1.05。

2. 发明申请

US20110233448A1 COPOLYMER, RUBBER COMPOSITION, CROSS-LINKED RUBBER, CROSS-LINKED FOAM, AND USES THEREOF 有权
标题翻译：共聚物，橡胶组合物，交联橡胶，交联泡沫及其用途
公开(公告)号：US20110233448A1
公开(公告)日：2011-09-29
申请号：US13130746
申请日：2009-11-26
申请人： Hiroki Ebata , Akinori Takehara , Mitsunao Arino , Masao Kunizane , Yoshiharu Kikuchi , Takayuki Kajihara
发明人： Hiroki Ebata , Akinori Takehara , Mitsunao Arino , Masao Kunizane , Yoshiharu Kikuchi , Takayuki Kajihara
IPC分类号： C08F4/6592 , C08L9/00 , C08J9/00 , E04B1/74
CPC分类号： C08L23/16 , C08F4/65908 , C08F4/6592 , C08F210/18 , C08F232/08 , C08F2420/02 , C08J9/04 , C08J2201/026 , C08J2323/16 , C08L2203/14 , C08L2312/00 , C08L2314/06 , C08L2666/08 , C08F210/06 , C08F236/20
摘要： The present invention provides a rubber composition having adequate foamability, uses thereof, a copolymer contained in the rubber composition, a rubber composition capable of providing a cross-linked foam, which has a low specific gravity and an excellent shape-retaining property even when the usage of a nonconjugated polyene is reduced, and a cross-linked rubber and a cross-linked foam, which are produced from the rubber composition. A copolymer (A) according to the present invention is a copolymer including structural units derived from ethylene [A], an α-olefin [B], a nonconjugated polyene [C-1], in which one carbon-carbon double bond (C═C) polymerizable with a metallocene catalyst is present in one molecule, and a nonconjugated polyene [C-2], in which two bonds of C═C polymerizable with the metallocene catalyst are present in one molecule, and being synthesized with the metallocene catalyst, wherein (1) the units derived from the component [B] constitute 10 to 50 percent by mole, (2) the total of the units derived from the component [C-1] and the units derived from the component [C-2] is 1.0 to 6.0 percent by mole, (3) the molar ratio of the units derived from the component [C-1] to the units derived from the component [C-2] is 75/25 to 99.5/0.5, (4) [ML (1+4) 100° C.] is 10 to 200, and (5) 50>activation energy of fluidization (kJ/mol)>35 is satisfied.
摘要翻译：本发明提供一种橡胶组合物，其具有足够的发泡性，其用途，包含在橡胶组合物中的共聚物，能够提供交联泡沫的橡胶组合物，即使在降低了非共轭多烯的使用，以及由橡胶组合物制备的交联橡胶和交联泡沫。根据本发明的共聚物（A）是包含衍生自乙烯[A]，α-烯烃[B]，非共轭多烯[C-1]的结构单元的共聚物，其中一个碳 - 碳双键可用金属茂催化剂聚合的≡C）存在于一个分子中，并且在一分子中存在可与金属茂催化剂聚合的C = C的两个键的非共轭多烯[C-2]，并与茂金属催化剂合成其中（1）衍生自组分[B]的单元构成10至50摩尔％，（2）衍生自组分[C-1]的单元和衍生自组分[C-2 ]为1.0〜6.0摩尔％，（3）[C-1]成分的单元与来自成分[C-2]的单元的摩尔比为75/25〜99.5 / 0.5，（4））[ML（1 + 4）100℃]为10〜200，（5）50>流化活化能（kJ / mol）> 35。

3. 发明申请

US20090239014A1 Rubber composition, crosslinked product and foam thereof, molded product therefrom, and use thereof 有权
标题翻译：橡胶组合物，交联产物和泡沫，其成型产品及其用途
公开(公告)号：US20090239014A1
公开(公告)日：2009-09-24
申请号：US12314155
申请日：2008-12-04
申请人： Yuji Noguchi , Takashi Hakuta , Hiroki Ebata , Kotaro Ichino , Shuichi Nonaka , Satoshi Hase , Kazuyoshi Kaneko , Akinori Takehara
发明人： Yuji Noguchi , Takashi Hakuta , Hiroki Ebata , Kotaro Ichino , Shuichi Nonaka , Satoshi Hase , Kazuyoshi Kaneko , Akinori Takehara
IPC分类号： C08L47/00 , C08L9/00 , C08K3/04 , B32B1/08
CPC分类号： C08L23/02 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F210/16 , C08F210/18 , C08J9/0061 , C08J9/0066 , C08J9/06 , C08J2201/024 , C08J2323/16 , C08J2423/00 , C08K3/04 , C08K3/06 , C08K3/22 , C08K3/26 , C08K3/346 , C08K5/0025 , C08K5/09 , C08K5/17 , C08L23/04 , C08L23/0815 , C08L23/10 , C08L23/16 , C08L91/00 , C08L2205/025 , C08L2312/00 , C08L2666/02 , C08L2666/06 , C08L2666/08 , C09K3/10 , C09K2200/0617 , C09K2200/062 , C09K2200/0642 , Y10T428/1386 , C08F4/6592 , C08F236/20 , C08F2500/17 , C08F210/06
摘要： The present invention provides a molded product exhibiting excellent various properties by improving compatibility of an ethylene/α-olefin/non-conjugated polyene copolymer with a polyolefin resin and a rubber composition for forming the molded product. The present invention further provides a molded product which comprises a rubber composition, is inhibited from fogging and tackiness and is excellent in mechanical strength and heat aging resistance. The rubber composition of the invention comprises an ethylene/α-olefin/non-conjugated polyene copolymer (A), and a polyolefin resin (B) having Mn of not less than 10,000 and/or an ethylene/α-olefin copolymer (C) having Mn of 2500 to 5000, and satisfies the following requirements: (1) a maximum value and a minimum value of an ethylene distribution parameter P of the component (A) have a relationship of Pmax/Pmin≦1.4, and (2) the B value of the component (C) ([EX]/(2[E]×[X])) ([E] and [X] are molar fractions of ethylene and the α-olefin of 3 to 20 carbon atoms, respectively, and [EX] is a fraction of dyad sequence of ethylene/α-olefin of 3 to 20 carbon atoms) is not more than 1.05.
摘要翻译：本发明提供通过改善乙烯/α-烯烃/非共轭多烯共聚物与聚烯烃树脂和用于形成模塑产品的橡胶组合物的相容性而显示出优异的各种性能的模制产品。本发明还提供一种包含橡胶组合物的模塑制品，其防止起雾和粘合，并且机械强度和耐热老化性优异。本发明的橡胶组合物包含乙烯/α-烯烃/非共轭多烯共聚物（A）和Mn不低于10,000的聚烯烃树脂（B）和/或乙烯/α-烯烃共聚物（C） Mn为2500〜5000，满足以下要求：（1）成分（A）的乙烯分布参数P的最大值和最小值具有Pmax / Pmin <= 1.4的关系，（2）组分（C）（[EX] /（2 [E] x [X]））（[E]和[X]）的B值是乙烯和3-20个碳原子的α-烯烃的摩尔分数，分别为[EX]为3-20个碳原子的乙烯/α-烯烃的二元序列的分数）不大于1.05。

4. 发明申请

US20050107505A1 Biodegradable resin composition and molded object thereof 审中-公开
标题翻译：生物降解性树脂组合物及其成型体
公开(公告)号：US20050107505A1
公开(公告)日：2005-05-19
申请号：US10503225
申请日：2003-01-31
申请人： Hosei Shinoda , Takeshi Kashima , Takayuki Kuroki , Akinori Takehara , Shoji Obuchi
发明人： Hosei Shinoda , Takeshi Kashima , Takayuki Kuroki , Akinori Takehara , Shoji Obuchi
IPC分类号： C08L67/06 , C08F299/02 , C08G69/40 , C08J5/18 , C08K5/00 , C08K5/05 , C08K5/09 , C08K5/14 , C08L1/12 , C08L29/04 , C08L67/00 , C08L67/02 , C08L67/04 , C08L77/00 , C08L77/08 , C08L101/00 , C08L101/12 , C08L101/16
CPC分类号： C08L67/02 , C08G69/40 , C08J5/18 , C08J2367/04 , C08K5/00 , C08K5/14 , C08L1/12 , C08L29/04 , C08L67/00 , C08L67/04 , C08L67/06 , C08L77/00 , C08L101/00 , C08L2201/06 , C08L2666/02 , C08L2666/14
摘要： A resin composition (AA) comprising an aliphatic polyester or aliphatic polyamide (component (A)), a plastic having a melting point or glass transition temperature (Tg) of −10° C. or more (component (B)) and a radical generating agent (C), wherein the compounding ratio of the component (A), the component (B) and the radical generating agent (C), based on the total weight thereof, is: 1 to 98.995% by weight of the component (A), 98.995 to 1% by weight of the component (B), and 0.005 to 5% by weight of the radical generating agent (C), and an aliphatic unsaturated polybasic acid (a) is contained in the polymer constituent of the component (A) and/or the component (B). The resin composition is suitable as a starting material of biodegradable material which maintains transparency, is free of bleeding of a plasticizer, is endowed with flexibility and has other advantageous characteristics so that it can be used in various fields.
摘要翻译：包含脂族聚酯或脂肪族聚酰胺（组分（A））的树脂组合物（AA），熔点或玻璃化转变温度（Tg）为-10℃以上的组分（组分（B））和基团（C），其中组分（A），组分（B）和自由基产生剂（C）的配混比基于其总重量计为：组分（1）的1-98.995重量％ A），98.995〜1重量％的组分（B）和0.005-5重量％的自由基产生剂（C）和脂族不饱和多元酸（a）包含在组分（A）和/或组分（B）。该树脂组合物适合作为可保持透明性，不含增塑剂渗色性的生物降解材料的起始材料，具有柔软性并具有其它有利特征，因此可用于各种领域。

5. 发明授权

US09193856B2 Copolymer, rubber composition, cross-linked rubber, cross-linked foam, and uses thereof 有权
标题翻译：共聚物，橡胶组合物，交联橡胶，交联泡沫及其用途
公开(公告)号：US09193856B2
公开(公告)日：2015-11-24
申请号：US13130746
申请日：2009-11-26
申请人： Hiroki Ebata , Akinori Takehara , Mitsunao Arino , Masao Kunizane , Yoshiharu Kikuchi , Takayuki Kajihara
发明人： Hiroki Ebata , Akinori Takehara , Mitsunao Arino , Masao Kunizane , Yoshiharu Kikuchi , Takayuki Kajihara
IPC分类号： C08F210/18 , C08F4/6592 , C08L23/16 , C08F232/08
CPC分类号： C08L23/16 , C08F4/65908 , C08F4/6592 , C08F210/18 , C08F232/08 , C08F2420/02 , C08J9/04 , C08J2201/026 , C08J2323/16 , C08L2203/14 , C08L2312/00 , C08L2314/06 , C08L2666/08 , C08F210/06 , C08F236/20
摘要： The present invention provides a rubber composition having adequate foamability, uses thereof, a copolymer contained in the rubber composition, a rubber composition capable of providing a cross-linked foam, which has a low specific gravity and an excellent shape-retaining property even when the usage of a nonconjugated polyene is reduced, and a cross-linked rubber and a cross-linked foam, which are produced from the rubber composition. A copolymer (A) according to the present invention is a copolymer including structural units derived from ethylene [A], an α-olefin [B], a nonconjugated polyene [C-1], in which one carbon-carbon double bond (C═C) polymerizable with a metallocene catalyst is present in one molecule, and a nonconjugated polyene [C-2], in which two bonds of C═C polymerizable with the metallocene catalyst are present in one molecule, and being synthesized with the metallocene catalyst, wherein (1) the units derived from the component [B] constitute 10 to 50 percent by mole, (2) the total of the units derived from the component [C-1] and the units derived from the component [C-2] is 1.0 to 6.0 percent by mole, (3) the molar ratio of the units derived from the component [C-1] to the units derived from the component [C-2] is 75/25 to 99.5/0.5, (4) [ML (1+4) 100° C.] is 10 to 200, and (5) 50>activation energy of fluidization (kJ/mol)>35 is satisfied.
摘要翻译：本发明提供一种橡胶组合物，其具有足够的发泡性，其用途，包含在橡胶组合物中的共聚物，能够提供交联泡沫的橡胶组合物，即使在降低了非共轭多烯的使用，以及由橡胶组合物制备的交联橡胶和交联泡沫。根据本发明的共聚物（A）是包含衍生自乙烯[A]，α-烯烃[B]，非共轭多烯[C-1]的结构单元的共聚物，其中一个碳 - 碳双键可用金属茂催化剂聚合的≡C）存在于一个分子中，并且在一分子中存在可与金属茂催化剂聚合的C = C的两个键的非共轭多烯[C-2]，并与茂金属催化剂合成其中（1）衍生自组分[B]的单元构成10至50摩尔％，（2）衍生自组分[C-1]的单元和衍生自组分[C-2 ]为1.0〜6.0摩尔％，（3）[C-1]成分的单元与来自成分[C-2]的单元的摩尔比为75/25〜99.5 / 0.5，（4））[ML（1 + 4）100℃]为10〜200，（5）50>流化活化能（kJ / mol）> 35。

6. 发明授权

US08554449B2 Fuel injection control apparatus 有权
标题翻译：燃油喷射控制装置
公开(公告)号：US08554449B2
公开(公告)日：2013-10-08
申请号：US12912271
申请日：2010-10-26
申请人： Shinji Yokoyama , Ikuhiro Uemura , Hiroyuki Hayasaka , Akinori Takehara
发明人： Shinji Yokoyama , Ikuhiro Uemura , Hiroyuki Hayasaka , Akinori Takehara
IPC分类号： F02D41/06 , F02M51/00
CPC分类号： F02D41/345 , F02D41/0025 , F02D41/009 , F02M69/044 , Y02T10/44
摘要： A fuel injection control apparatus for controlling a fuel injection valve including an arithmetic processing section that determines whether a necessary fuel amount is injectable or not within a fuel injectable range from a first fuel injection start timing, computes a second fuel injection start timing in which the necessary fuel amount is injectable within the fuel injectable range in the case that it is not injectable, and controls the fuel injection valve at the computed second fuel injection start timing so as to start fuel injection.
摘要翻译：一种燃料喷射控制装置，用于控制包括运算处理部分的燃料喷射阀，所述运算处理部根据第一燃料喷射开始定时确定在燃料可喷射范围内是否可喷射必要的燃料量，计算第二燃料喷射开始定时，在不可喷射的情况下，在燃料可喷射范围内注入必要的燃料量，并且在所计算的第二燃料喷射开始时刻控制燃料喷射阀以开始燃料喷射。

7. 发明申请

US20110100330A1 FUEL INJECTION CONTROL APPARATUS 有权
标题翻译：燃油喷射控制装置
公开(公告)号：US20110100330A1
公开(公告)日：2011-05-05
申请号：US12912271
申请日：2010-10-26
申请人： Shinji YOKOYAMA , Ikuhiro UEMURA , Hiroyuki HAYASAKA , Akinori TAKEHARA
发明人： Shinji YOKOYAMA , Ikuhiro UEMURA , Hiroyuki HAYASAKA , Akinori TAKEHARA
IPC分类号： F02M51/00
CPC分类号： F02D41/345 , F02D41/0025 , F02D41/009 , F02M69/044 , Y02T10/44
摘要： A fuel injection control apparatus for controlling a fuel injection valve including an arithmetic processing section that determines whether a necessary fuel amount is injectable or not within a fuel injectable range from a first fuel injection start timing, computes a second fuel injection start timing in which the necessary fuel amount is injectable within the fuel injectable range in the case that it is not injectable, and controls the fuel injection valve at the computed second fuel injection start timing so as to start fuel injection.
摘要翻译：一种燃料喷射控制装置，用于控制包括运算处理部分的燃料喷射阀，所述运算处理部根据第一燃料喷射开始定时确定在燃料可喷射范围内是否可喷射必要的燃料量，计算第二燃料喷射开始定时，在不可喷射的情况下，在燃料可喷射范围内注入必要的燃料量，并且在所计算的第二燃料喷射开始时刻控制燃料喷射阀以开始燃料喷射。

8. 发明授权

US06984443B2 Aliphatic polyester resin composition and films containing the same 失效
标题翻译：脂肪族聚酯树脂组合物和含有它们的膜
公开(公告)号：US06984443B2
公开(公告)日：2006-01-10
申请号：US10380051
申请日：2002-07-09
申请人： Takayuki Kuroki , Takayuki Watanabe , Yasuhiro Kitahara , Akinori Takehara , Shoji Obuchi
发明人： Takayuki Kuroki , Takayuki Watanabe , Yasuhiro Kitahara , Akinori Takehara , Shoji Obuchi
IPC分类号： C08L67/04 , C08J5/18 , C08K5/103
CPC分类号： C08J5/18 , C08J2367/04 , C08K5/103 , C08L67/04 , C08L71/00 , Y10T428/31786 , C08L2666/22
摘要： The invention provides an aliphatic polyester resin composition that contains 100 parts by weight of an aliphatic polyester resin and from 10 to 60 parts by weight of at least one compound of a formula (1): wherein n indicates an integer of from 1 to 9, R1 to R4 each independently represent an alkyl group having from 1 to 17 carbon atoms, and when n is 2 or more, R3 may differ in different units, a film formed of the composition, and packages with the film. The aliphatic polyester film of the invention keeps the degradability in the natural environment that is intrinsic to lactic acid-based polymer, and has good heat resistance, flexibility, transparency and adhesiveness, and, in addition, the plasticizer does not migrate to the surface of the film.
摘要翻译：本发明提供一种脂肪族聚酯树脂组合物，其含有100重量份的脂族聚酯树脂和10至60重量份的至少一种式（1）化合物：其中n表示1至9的整数， R 1至R 4各自独立地表示具有1至17个碳原子的烷基，当n为2以上时，R 3' 可能在不同的单位不同，由组合物形成的薄膜和与薄膜组合。本发明的脂肪族聚酯膜在乳酸类聚合物固有的自然环境中保持降解性，并且具有良好的耐热性，柔软性，透明性和粘合性，另外，增塑剂不会迁移到这个电影。

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