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    • 1. 发明授权
    • Permanent magnet
    • 永久磁铁
    • US06475302B2
    • 2002-11-05
    • US09749803
    • 2000-12-28
    • Wu MeiToshiya SakamotoShinya SakuradaTakao SawaAkihiko TsutaiAkiko SaitoMasashi Sahashi
    • Wu MeiToshiya SakamotoShinya SakuradaTakao SawaAkihiko TsutaiAkiko SaitoMasashi Sahashi
    • H01F1055
    • H01F1/058H01F1/0306H01F1/055H01F1/057
    • Disclosed is a permanent magnet which comprises an alloy containing a hard magnetic phase having a ThMn12 type tetragonal structure and a nonmagnetic phase. The alloy is represented by a general formula given below: [R1-a(M1)a][T1-b-c(M2)b(M3)c]dx&agr; where R is at least one rare earth element (including Y), Ml is at least one element selected from the group consisting of Zr and Hf, T is at least one element selected from the group consisting of Fe, Co and Ni, M2 is at least one element selected from the group consisting of Cu, Bi, Sn, Mg, In and Pb, M3 is at least one element selected from the group consisting of Al, Ga, Ge, Zn, B, P and S, X is at least one element selected from the group consisting of Si, Ti, V, Cr, Mn, Nb, Mo, Ta and W, and the atomic ratios of a, b, c, d and &agr; fall within the ranges of 0≦a≦0.6, 0.01≦b≦0.20, 0≦c≦0.05, 6≦d≦11, and 0.5≦&agr;≦2.0.
    • 公开了一种永磁体,其包含含有ThMn 12型四方晶系的硬磁相和非磁性相的合金。 该合金由以下给出的通式表示:其中R是至少一种稀土元素(包括Y),M1是选自Zr和Hf中的至少一种元素,T是至少一种选自 由Fe,Co和Ni构成的组,M2是选自Cu,Bi,Sn,Mg,In和Pb中的至少一种元素,M3是选自Al,Ga,Ge中的至少一种元素 ,Zn,B,P和S中的至少一种,X是选自由Si,Ti,V,Cr,Mn,Nb,Mo,Ta和W组成的组中的至少一种元素,并且a,b,c, d和α落在0 <= a <= 0.6,0.01 <= b <= 0.20,0 <= c <= 0.05,6 <= d <= 11和0.5 <=α<2.0的范围内。
    • 6. 发明授权
    • Magnetic material
    • 磁性材料
    • US5549766A
    • 1996-08-27
    • US288808
    • 1994-08-12
    • Akihiko TsutaiTakahiro HiraiShinya Sakurada
    • Akihiko TsutaiTakahiro HiraiShinya Sakurada
    • H01F1/055H01F1/058H01F1/059
    • H01F1/059H01F1/055H01F1/058
    • A permanent magnet is composed of a magnetic material which is represented by a general formula R1.sub.x R2.sub.y A.sub.z Co.sub.u Fe.sub.100-x-y-z-u (where R1 is at least one element selected from rare earth elements, R2 is at least one element selected from the group consisting of Sc, Zr and Hf, A is at least one element selected from the group of C, N and P, and x,y,z and u are atomic percent defined as 2.ltoreq.x, 4.ltoreq.x+y.ltoreq.20, 0.ltoreq.z.ltoreq.20, 0.ltoreq.u.ltoreq.70), wherein the material includes a principal phase of TbCu.sub.7 structure and .alpha.-Fe, a peak width at half height of the main peak of X-ray diffraction of the principal phase obtained by using Cu-K.alpha. X-rays with the resolution of 0.02.degree. or less is about 0.8.degree. or less, and a ratio of peak intensity between the principal phase and .alpha.-Fe satisfies a relation that the value of I.sub.Fe /(I.sub.p +I.sub.Fe) is about 0.4 or less where I.sub.p is the peak intensity of main peak of X-ray diffraction of the principal phase obtained by using Cu-K.alpha. X-rays and I.sub.Fe is that of .alpha.-Fe.
    • 永久磁铁由通式为R1xR2yAzCouFe100-xyzu(其中R1为选自稀土元素中的至少一种元素,R2为选自Sc,Zr和Hf中的至少一种元素)的磁性材料构成 A是选自C,N和P组中的至少一种元素,x,y,z和u是原子百分比,其定义为2
    • 10. 发明授权
    • Magnetic material
    • 磁性材料
    • US5480495A
    • 1996-01-02
    • US86379
    • 1993-07-06
    • Shinya SakuradaTakahiro HiraiAkihiko TsutaiMasashi Sahashi
    • Shinya SakuradaTakahiro HiraiAkihiko TsutaiMasashi Sahashi
    • H01F1/055H01F1/059
    • H01F1/0593H01F1/055
    • Disclosed is a magnetic material which suppresses formation of impurity phase of Fe, Co or Fe-Co alloy, possesses a stable ThMn.sub.12 crystal structure as the principal phase, and is excellent in magnetic properties and lower in cost. Such magnetic material is expressed in a general formula:R1.sub.x R2.sub.y Si.sub.z M.sub.u T.sub.vwhere R1is at least one element selected from Zr and Hf, R2is at least one element selected from rare earth element, M is at least one element selected from C, N and P, T is at least one element selected from Fe and Co, x+y+z+u+v=100, x, y, z, u, v are atomic percent individually defined as 0.1.ltoreq.x.ltoreq.20, 2.ltoreq.y.ltoreq.20, 0.5.ltoreq.z.ltoreq.20, 0.ltoreq.u.ltoreq.20, v.gtoreq.50, and of which principal phase possesses a ThMn.sub.12 crystal structure.
    • 公开了抑制Fe,Co或Fe-Co合金的杂质相的形成的磁性材料,其具有稳定的ThMn12晶体结构作为主相,磁性优异,成本低。 这种磁性材料以通式表示:R1xR2ySizMuTv其中R1为选自Zr和Hf中的至少一种元素,R2为选自稀土元素中的至少一种元素,M为选自C,N和P中的至少一种元素,T为 选自Fe和Co中的至少一种元素,x + y + z + u + v = 100,x,y,z,u,v是原子百分数,各自定义为0.1≤x≤20,2/ = y / = 50,其主相具有ThMn12晶体结构。