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1. 发明授权

US06627708B2 Compositions comprising functionalized polyphenylene ether resins 有权
公开(公告)号：US06627708B2
公开(公告)日：2003-09-30
申请号：US10063152
申请日：2002-03-26
申请人： Adrianus J. F. M. Braat , Herbert Shin-I Chao , Hua Guo , Juraj Liska , Gary William Yeager
发明人： Adrianus J. F. M. Braat , Herbert Shin-I Chao , Hua Guo , Juraj Liska , Gary William Yeager
IPC分类号： C08G6300
CPC分类号： C08G65/485 , C08L71/02 , C08L2666/02
摘要： The invention relates to a polyphenylene ether resin containing residual aliphatic unsaturation as well as composites, blends, and articles made from the polyphenylene ether resin containing residual aliphatic unsaturation. Also included are reaction products between the polyphenylene ether resin containing residual aliphatic unsaturation and other resins and unsaturated resin formulations, e.g., thermosetting polyesters, acrylics, bismaleiimides, silicones, and allylics, and thermoplastics such as polyolefins, styrenics, rubbers, etc.

2. 发明授权

US06552105B2 Poly (arylene ether) composition, method for the preparation thereof, and articles derived therefrom 失效
标题翻译：聚（亚芳基醚）组合物，其制备方法和由其衍生的制品
公开(公告)号：US06552105B2
公开(公告)日：2003-04-22
申请号：US09782584
申请日：2001-02-13
申请人： Adrianus J. F. M. Braat , Amy Rene Freshour , Hua Guo , Rene de Jongh , Juraj Liska
发明人： Adrianus J. F. M. Braat , Amy Rene Freshour , Hua Guo , Rene de Jongh , Juraj Liska
IPC分类号： C08L9500
CPC分类号： C08L71/123 , C08L95/005 , C08L71/00
摘要： A composition comprises a bitumen and a poly(arylene ether) having an intrinsic viscosity less than 0.40 deciliters per gram. The composition exhibits high softening and flow temperatures, and high hardness.
摘要翻译：组合物包含沥青和特性粘度小于0.40分升/克的聚（亚芳基醚）。该组合物显示出高的软化和流动温度，以及高的硬度。

3. 发明授权

US06448327B1 Preparation process and properties of styrene butadiene random copolymer/poly(arylene ether) compositions 失效
标题翻译：苯乙烯丁二烯无规共聚物/聚（亚芳基醚）组合物的制备方法和性能
公开(公告)号：US06448327B1
公开(公告)日：2002-09-10
申请号：US09644473
申请日：2000-08-23
申请人： Adrianus J. F. M. Braat , Benny David , Hua Guo , Juraj Liska , Herb Chao , Kenneth P. Zarnoch
发明人： Adrianus J. F. M. Braat , Benny David , Hua Guo , Juraj Liska , Herb Chao , Kenneth P. Zarnoch
IPC分类号： C08L906
CPC分类号： C08L9/06 , C08L9/00 , C08L71/12 , C08L71/123 , C08L2205/02 , C08L2666/14 , C08L2666/24 , C08L2666/04
摘要： An elastomer-thermoplastic composition comprising styrene butadiene random copolymer and poly(arylene ether) resin and methods of making the composition are disclosed.
摘要翻译：公开了包含苯乙烯丁二烯无规共聚物和聚（亚芳基醚）树脂的弹性体 - 热塑性组合物及其制备方法。

4. 发明授权

US06417274B1 Process for the manufacture of functionalized polyphenylene ether resins 有权
标题翻译：制备官能化聚苯醚树脂的方法
公开(公告)号：US06417274B1
公开(公告)日：2002-07-09
申请号：US09245245
申请日：1999-02-05
申请人： Adrianus J. F. M. Braat , Rene de Jongh , Juraj Liska
发明人： Adrianus J. F. M. Braat , Rene de Jongh , Juraj Liska
IPC分类号： C08L7112
CPC分类号： C08G65/485
摘要： The invention relates to a novel process for preparing functionalized PPE, the process comprising oxidative coupling in a reaction solution at least one monovalent phenol species using an oxygen containing gas and a complex metal catalyst to produce a PPE; and functionalizing the PPE prior to and/or during at least one isolation step for devolatilization of the reaction solvent. The invention also relates to the polyphenylene ether resin made by the process as well as blends and articles containing the polyphenylene ether resin made by the process.
摘要翻译：本发明涉及一种制备官能化PPE的新方法，该方法包括使用含氧气体和复合金属催化剂在反应溶液中使至少一种一价酚物质氧化偶联以产生PPE; 以及在至少一个分离步骤之前和/或期间对所述反应溶剂的脱挥发分进行官能化。本发明还涉及通过该方法制备的聚苯醚树脂以及含有通过该方法制备的聚苯醚树脂的共混物和制品。

5. 发明授权

US06307010B1 Process for the manufacture of low molecular weight polyphenylene ether resins through redistribution 有权
标题翻译：通过再分配制造低分子量聚苯醚树脂的方法
公开(公告)号：US06307010B1
公开(公告)日：2001-10-23
申请号：US09245253
申请日：1999-02-05
申请人： Adrianus J. F. M. Braat , Hugo G. E. Engelbrecht , Juraj Liska
发明人： Adrianus J. F. M. Braat , Hugo G. E. Engelbrecht , Juraj Liska
IPC分类号： C08F612
CPC分类号： C08G65/44
摘要： The invention relates to a novel process for the manufacture of functionalized polyphenylene ether resins through redistribution with a functionalized phenolic compound in the polyphenylene ether resin polymerization reaction solution without the addition of an added redistribution catalyst or promoter. The invention also relates to the functionalized polyphenylene ether resin made by the process as well as blends and articles containing the functionalized polyphenylene ether resin made by the process.
摘要翻译：本发明涉及通过在聚苯醚树脂聚合反应溶液中与官能化酚类化合物重新分配而制备官能化聚苯醚树脂的新方法，而不添加添加的再分布催化剂或促进剂。本发明还涉及官能化聚苯醚通过该方法制备的树脂以及含有通过该方法制备的官能化聚苯醚树脂的共混物和制品。

6. 发明授权

US06437085B1 Process for the manufacture of low molecular weight polyphenylene ether resins 有权
标题翻译：制备低分子量聚苯醚树脂的方法
公开(公告)号：US06437085B1
公开(公告)日：2002-08-20
申请号：US09969310
申请日：2001-10-02
申请人： Adrianus J. F. M. Braat , Hugh Ingelbrecht , Ruud Trion
发明人： Adrianus J. F. M. Braat , Hugh Ingelbrecht , Ruud Trion
IPC分类号： C08G6538
CPC分类号： C08G65/44 , C08G65/46
摘要： The invention relates to a novel process for the manufacture of very low molecular weight polyphenylene ether resin, typically within the intrinsic viscosity range of about 0.08 dl/g to about 0.16 dl/g as measured in chloroform at 25° C. The method preferably comprises 2,6-dimethylphenol as a monovalent phenol species. The invention also relates to the polyphenylene ether resin made by the process as well as blends and articles containing the polyphenylene ether resin made by the process.
摘要翻译：本发明涉及一种用于制造极低分子量聚苯醚树脂的新方法，通常在25℃下在氯仿中测得的特性粘度范围为约0.08dl / g至约0.16dl / g。该方法优选包含 2,6-二甲基苯酚作为一价苯酚物质。本发明还涉及通过该方法制备的聚苯醚树脂以及含有通过该方法制备的聚苯醚树脂的共混物和制品。

7. 发明授权

US06306978B1 Capping of polyphenylene ether resin 失效
标题翻译：聚苯醚树脂封端
公开(公告)号：US06306978B1
公开(公告)日：2001-10-23
申请号：US09245255
申请日：1999-02-05
申请人： Adrianus J. F. M. Braat , Adrie Landa , Juraj Liska
发明人： Adrianus J. F. M. Braat , Adrie Landa , Juraj Liska
IPC分类号： C08G6548
CPC分类号： C08G65/485
摘要： The invention relates to methods of capping poly(phenylene ether) resin having an intrinsic viscosity between 0.05 and 0.35 dl/g. More particularly, the methods comprise capping a poly(phenylene ether) resin having an intrinsic viscosity between 0.05 and 0.35 dl/g in a solvent to produce a capped poly(phenylene ether) resin having an intrinsic viscosity between 0.05 and 0.35 dl/g and isolating the capped poly(phenylene ether) resin by removal of the solvent, preferably in a process other than precipitation. The invention also relates to the capped poly(phenylene ether) resin having an intrinsic viscosity between 0.05 and 0.35 dl/g.
摘要翻译：本发明涉及特征粘度在0.05和0.35dl / g之间的聚（苯醚）树脂的封端方法。更具体地说，该方法包括在特性粘度为0.05至0.35dl / g之间的特性粘度为0.05至0.35dl / g的聚苯醚树脂中，在特性粘度为0.05至0.35dl / g的范围内制备封端的聚苯醚树脂，通过除去溶剂来分离封端的聚（苯醚）树脂，优选以除沉淀之外的方法。本发明还涉及特性粘度在0.05和0.35dl / g之间的封端聚（苯醚）树脂。

8. 发明授权

US06291724B1 Suppression of highly alkylated phenols in the catalytic alkylation reaction of phenol 失效
标题翻译：在苯酚的催化烷基化反应中抑制高度烷基化的酚
公开(公告)号：US06291724B1
公开(公告)日：2001-09-18
申请号：US08936134
申请日：1997-09-24
申请人： Adrianus J. F. M. Braat
发明人： Adrianus J. F. M. Braat
IPC分类号： C07C3700
CPC分类号： C07C37/48 , C07C39/07
摘要： Selective catalytic reduction of the formation of alkylated phenols by transalkylation of ortho- and para-positions of alkylated phenols is accomplished by reacting ortho- and/or para-alkylated phenols with unreacted alkylated phenols in the presence of a metal oxide selected from the group consisting of Mg, Zn, Fe, V, Ce, Cs, Mn, or combinations thereof. This invention can be easily executed by recycling the alkylated phenols into the normal feed stream of the alkylation reactor.
摘要翻译：通过烷基化酚的邻位和对位的烷基转移来烷基化酚的选择性催化还原是通过邻位和/或对烷基化的酚与未反应的烷基化酚在金属氧化物的存在下反应来进行的，所述金属氧化物选自的Mg，Zn，Fe，V，Ce，Cs，Mn或它们的组合。通过将烷基化酚再循环到烷基化反应器的正常进料流中，可以容易地实现本发明。

9. 发明授权

US06472499B1 Preparation of high intrinsic viscosity poly(arylene ether) resins 有权
标题翻译：高特性粘度聚（亚芳基醚）树脂的制备
公开(公告)号：US06472499B1
公开(公告)日：2002-10-29
申请号：US09635040
申请日：2000-08-04
申请人： Adrianus J. F. M. Braat , Hugo G. E. Ingelbrecht
发明人： Adrianus J. F. M. Braat , Hugo G. E. Ingelbrecht
IPC分类号： C08G6538
CPC分类号： C08G65/46 , C08G65/44
摘要： Poly(arylene ether) resins having intrinsic viscosities greater than about 0.8 dL/g are produced in the reaction of a phenol with oxygen in the presence of an organic solvent and a metal complex catalyst, the phenol concentration being about 5 to about 15 weight percent of the sum of phenol and solvent, and the molar ratio of metal in the metal complex catalyst to the phenol being about 1:100 to about 1:200.
摘要翻译：在有机溶剂和金属络合物催化剂的存在下，在苯酚与氧的反应中产生特性粘度大于约0.8dL / g的聚（亚芳基醚）树脂，苯酚浓度为约5至约15重量％的苯酚和溶剂的总和，金属络合物催化剂中的金属与苯酚的摩尔比为约1:100至约1:200。

10. 发明授权

US06300461B1 Process for the manufacture of low molecular weight polyphenylene ether resins 有权
标题翻译：制备低分子量聚苯醚树脂的方法
公开(公告)号：US06300461B1
公开(公告)日：2001-10-09
申请号：US09735972
申请日：2000-12-13
申请人： Adrianus J. F. M. Braat , Hugh Ingelbrecht , Ruud Trion
发明人： Adrianus J. F. M. Braat , Hugh Ingelbrecht , Ruud Trion
IPC分类号： C08G6538
CPC分类号： C08G65/44 , C08G65/46
摘要： The invention relates to a novel process for the manufacture of very low molecular weight polyphenylene ether resin, typically within the intrinsic viscosity range of about 0.08 dl/g to about 0.16 dl/g as measured in chloroform at 25° C. The method preferably comprises 2,6-dimethylphenol as a monovalent phenol species. The invention also relates to the polyphenylene ether resin made by the process as well as blends and articles containing the polyphenylene ether resin made by the process.
摘要翻译：本发明涉及一种用于制造极低分子量聚苯醚树脂的新方法，通常在25℃下在氯仿中测得的特性粘度范围为约0.08dl / g至约0.16dl / g。该方法优选包含 2,6-二甲基苯酚作为一价苯酚物质。本发明还涉及通过该方法制备的聚苯醚树脂以及含有通过该方法制备的聚苯醚树脂的共混物和制品。

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