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    • 1. 发明申请
    • Method for preparing ziconia ceramics using hybrid composites as precursor materials shaped by CAD/CAM process
    • 使用混合复合材料作为通过CAD / CAM工艺成型的前体材料制备圆锥形陶瓷的方法
    • US20060135652A1
    • 2006-06-22
    • US11014979
    • 2004-12-20
    • Abdeslam KassehElmekki EnnajimiJamal Chaouki
    • Abdeslam KassehElmekki EnnajimiJamal Chaouki
    • C08K9/00
    • C08K9/02C08K3/22C08K9/04
    • This invention is a novel method for making zirconia ceramic from hybrid composite biomaterials. The inorganic particles of zirconium oxide with a desired size and controlled shape were synthesized in an alcohol solution in the presence of water and a morphologic catalyst. Zirconium alkoxides and/or zirconium oxychloride, Yttrium alkoxide, Yttrium nitrate hexahydrate and Yttrium chloride, were used as the precursor materials for the preparation of zirconium oxide colloidal suspensions. Particle surface modification by the introduction of polymerization precursors was carried out in colloidal suspension. Highly-filled and well dispersed composite biomaterials with thermoplastic and/or thermo-hardening matrices are easily obtained using several polymerization techniques, like catalytic polymerization, controlled free radical polymerization, and polycondensation. This new method makes it possible to prepare composite biomaterials with monodispersed and spherical colloidal particles that are well dispersed and highly compacted in the polymeric matrix and with an easy control of the number of grafted polymeric chains per particle. The obtained biomaterials have the advantage of being sintered isotropically with a weak and controlled shrinkage. These properties offer the possibility of shaping these materials using CAD/CAM technology in the composite state followed by a sintering process leading to TZP (tetragonal zirconia polycrystal) ceramic.
    • 本发明是从混合复合生物材料制备氧化锆陶瓷的新方法。 在水和形态催化剂的存在下,在醇溶液中合成具有所需尺寸和受控形状的氧化锆的无机颗粒。 使用锆锆盐和/或氧氯化锆,醇钇,六水合硝酸钇和氯化钇作为制备氧化锆胶体悬浮液的前体材料。 通过引入聚合前体的颗粒表面改性在胶态悬浮液中进行。 使用几种聚合技术,如催化聚合,受控自由基聚合和缩聚,可容易地获得具有热塑性和/或热硬化基质的高度填充且分散良好的复合生物材料。 这种新方法使得可以制备复合生物材料与单分散和球形胶体颗粒,其在聚合物基质中分散和高度压实,并且易于控制每个颗粒的接枝聚合物链的数量。 所得到的生物材料具有各向同性地烧结和控制收缩的优点。 这些性质提供了使用CAD / CAM技术在复合状态下形成这些材料的可能性,接着是导致TZP(四方晶氧化锆多晶)陶瓷的烧结过程。
    • 2. 发明申请
    • Implant system and method of installation thereof
    • 植入系统及其安装方法
    • US20050136378A1
    • 2005-06-23
    • US10740050
    • 2003-12-19
    • Elmekki EnnajimiAbdeslam KassehJamal ChaoukiGustavo Labbe
    • Elmekki EnnajimiAbdeslam KassehJamal ChaoukiGustavo Labbe
    • A61C8/00
    • A61C8/0066A61C8/005A61C8/0054A61C8/006A61C13/0022
    • The present invention provides an implant system of facilitated use and installation which comprise an implant and a prosthesis support and a method of installation thereof. The prosthesis support disclosed herein includes an abutment and a collar member. Prior art implant systems are mostly made of metallic parts which are assembled with a screw and are shaped to receive a tooth prosthesis. The design of the abutment allows it to be made from highly filled composite materials being of a better optical quality and being easily machinable and further allows its installation without the use of a screwing member. The design of the collar member allows minimization of bacteria growth and tartar formation. The optimization of the implant system proposed herein may reduce stress to the jaw bone and therefore minimize the risk of injury for the patient.
    • 本发明提供一种易于使用和安装的植入系统,其包括植入物和假体支撑件及其安装方法。 本文公开的假体支撑件包括支座和套环构件。 现有技术的植入物系统大多由金属部件制成,其由螺钉组装并且被成形为接收牙齿假体。 基台的设计允许其由具有更好的光学质量的高填充复合材料制成,并且易于加工,并且进一步允许其安装而不使用螺纹构件。 衣领构件的设计允许最小化细菌生长和牙垢形成。 本文提出的植入系统的优化可以减少对颚骨的压力,从而使患者的伤害风险最小化。