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2. 发明申请

WO2012129659A1 FLEXIBLE, SEMICONDUCTING NANOCOMPOSITE MATERIALS BASED ON NANOCRYSTALLINE CELLULOSE AND POLYANILINE 审中-公开
标题翻译：基于纳米晶体纤维素和聚氨酯的柔性，半导体纳米复合材料
公开(公告)号：WO2012129659A1
公开(公告)日：2012-10-04
申请号：PCT/CA2012000281
申请日：2012-03-28
申请人： FPINNOVATIONS , HAMAD WADDOD YASSER , ATIFI SIHAM
发明人： HAMAD WADDOD YASSER , ATIFI SIHAM
IPC分类号： C08L79/02 , C08J5/24 , C08L1/02
CPC分类号： H01B1/20 , B82Y30/00 , C08L1/04 , C08L79/02
摘要： A new approach is conceived for the development of organic polymeric conducting materials synthesized from nanocomposites of nanocrystalline cellulose (NCC) and polyaniline (PANI). The process involves oxidative-radical polymerization of aniline in the presence of NCC using either in situ or emulsion polymerization. The resulting NCC-PANI nanocomposite material can be obtained in film or powder form and exhibits electrical conductive properties typical of semiconducting materials. Unlike PANI, a brittle conductive polymer, NCC-PANI nanocomposite materials can be engineered to possess significant flexibility, strength and/or hardness as a result of the NCC acting as a reinforcing scaffold. Depending on the preparation conditions, electrical conductivities for the NCC-PANI nanocomposite materials prepared according to this disclosure range from 9.98 x 10-5 to 1.88 x 10-2 S.cm-1; they could also have hardness > 0.189 GPa or be formed into flexible films of tensile strength of the order of 9.74 MPa and stretch of the order of 0.54%. These unique electrical and mechanical properties render these materials suitable for use in a variety of value-added industrial products, such as batteries, electronics, electrical sensors, separation membranes, anti-static coatings for aerospace applications, as well as anti-corrosive coatings for automotives and other industrial applications.
摘要翻译：设计了一种从纳米晶体纤维素（NCC）和聚苯胺（PANI）的纳米复合材料合成的有机聚合物导电材料的开发的新方法。该方法包括使用原位或乳液聚合在NCC存在下苯胺进行氧化自由基聚合。所得到的NCC-PANI纳米复合材料可以以薄膜或粉末形式获得，并且表现出典型的半导体材料的导电性能。与PANI不同，脆性导电聚合物NCC-PANI纳米复合材料可以被设计成具有显着的柔韧性，强度和/或硬度，这是NCC作为增强支架的结果。根据制备条件，根据本公开制备的NCC-PANI纳米复合材料的电导率范围为9.98×10 -5至1.88×10 -2 S.cm -1; 它们也可以具有> 0.189GPa的硬度，或者形成拉伸强度为9.74MPa，拉伸度为0.54％的柔性膜。这些独特的电气和机械性能使这些材料适用于各种增值工业产品，如电池，电子，电气传感器，分离膜，航空航天应用的防静电涂料，以及防腐涂料汽车和其他工业应用。

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