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1. 发明申请

WO1995029942A1 CROSS-LINKED ACRYLIC RESIN AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：交联丙烯酸树脂及其制造方法
公开(公告)号：WO1995029942A1
公开(公告)日：1995-11-09
申请号：PCT/JP1995000422
申请日：1995-03-15
申请人： LION CORPORATION , KUREHA KAGAKU KOGYO KABUSHIKI KAISHA , KIKAWA, Hitoshi , ASAO, Yoshikazu , SAKAGAMI, Teruo , SAITO, Akira
发明人： LION CORPORATION , KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
IPC分类号： C08F20/18
CPC分类号： C08F22/105
摘要： A cross-linked acrylic resin produced by (co)polymerizing a monomer composition comprising the following components (A) and/or (B) as the essential ingredient and optionally containing a component (C) comprising a monomer copolymerizable with the essential ingredient. The resin, having a long aliphatic carbon chain, has a low specific gravity and an excellent heat resistance while enjoying a high transparency. Component (A): an ester prepared from (1) a diol (a) obtained by reducing a dimer of a C11-C22 unsaturated fatty acid and/or a diol (b) obtained by reducing a dimer of a lower alkyl ester of a C11-C22 unsaturated fatty acid and (2) acrylic or methacrylic acid. Component (B): an ester prepared from (1) a triol (pa) obtained by reducing a trimer of a C11-C22 unsaturated fatty acid and/or a triol (b) obtained by reducing a trimer of a lower alkyl ester of a C11-C22 unsaturated fatty acid and (2) acrylic or methacrylic acid.
摘要翻译：通过（共）聚合包含以下组分（A）和/或（B）的单体组合物作为必需成分并任选地含有包含可与基本成分共聚的单体的组分（C）而制备的交联丙烯酸树脂。具有长脂肪族碳链的树脂在享受高透明性的同时具有低比重和优异的耐热性。组分（A）：由（1）通过还原C11-C22不饱和脂肪酸和/或二醇（b）的二聚体获得的（1）二醇（a）制备的酯，其通过将低级烷基酯的二聚体 C11-C22不饱和脂肪酸和（2）丙烯酸或甲基丙烯酸。组分（B）：由（1）通过还原C11-C22不饱和脂肪酸和/或三醇（b）的三聚体获得的三醇（pa）制备的酯，其通过还原三 C11-C22不饱和脂肪酸和（2）丙烯酸或甲基丙烯酸。

2. 发明申请

WO1995025133A1 MONOMER MIXTURE AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：单体混合物及其制造方法
公开(公告)号：WO1995025133A1
公开(公告)日：1995-09-21
申请号：PCT/JP1995000423
申请日：1995-03-15
申请人： LION CORPORATION , KIGAWA, Hitoshi , YAMAGISHI, Hiroshi , SUZUKI, Noriko , ASAO, Yoshikazu
发明人： LION CORPORATION
IPC分类号： C08F220/02
CPC分类号： C08F242/00 , C07C67/347 , C07C69/54 , C08F20/62 , C07C69/608 , C07C69/52 , C07C69/593
摘要： A monomer mixture which is useful for synthesizing polymers used as the material of various optical resins and has a hydroxyl value of 0-134 KOHmg/g. It is produced by the esterification between a mixture comprising substantially dimerdiol and trimertriol in aweight ratio of from 30/70 to 99/1 and (meth)acrylic acid or transesterification between the diol/triol mixture and a lower alkyl (meth)acrylate. The diol/triol mixture is prepared by polymerizing a feed mixture having an iodine value of 30-130 g (iodine)/100 g and comprising an unsaturated compound selected from the group consisting of C11-C22 fatty acids each having one carboxyl group and one double bond in its molecule and lower alkyl esters thereof and another unsaturated compound selected from the group consisting of C11-C22 fatty acids each having one carboxyl group and two to four double bonds in its molecule and lower alkyl esters thereof, and reducing the carboxyl groups (or lower alkyl ester groups in the case of the lower alkyl esters) of the obtained dimer and trimer molecules into hydroxyl groups.
摘要翻译：用于合成用作各种光学树脂的材料并且羟值为0-134KOHmg / g的聚合物的单体混合物。它是通过重量比为30/70至99/1的基本上二聚二醇和三羟甲基三醇的混合物与（甲基）丙烯酸或二醇/三醇混合物和（甲基）丙烯酸低级烷基酯之间的酯交换的酯化产生的。二醇/三醇混合物通过聚合碘值为30-130g（碘）/ 100g的进料混合物制备，并且包含不饱和化合物，其选自具有一个羧基的C 11 -C 22脂肪酸和一个分子中的双键和其低级烷基酯和选自分子中具有一个羧基和二至四个双键的C 11 -C 22脂肪酸和其低级烷基酯的另一种不饱和化合物，以及还原羧基（或低级烷基酯的情况下的低级烷基酯基）转化为羟基。

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