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1. 发明专利

CA2896514C MICROCAPSULE PARTICLES 未知
公开(公告)号：CA2896514C
公开(公告)日：2021-01-26
申请号：CA2896514
申请日：2013-12-12
申请人： APPVION INC
发明人： SCHWANTES TODD
IPC分类号： B01J13/14 , B01J13/18
摘要： The present invention teaches microcapsule particles comprising an oil soluble or dispersible core material; and a wall material at least partially surrounding the core material, the microcapsule wall material consisting of the reaction product of a first composition in the presence of a second composition; the first composition comprising a water phase: the water phase comprising a water soluble or dispersible initiator having at least one -COOH or amine functional group and a nonionic emulsifier, the emulsifier comprising a water soluble or dispersible material at a pH from 4 to 12, the water soluble or dispersible initiator is selected from initiators having a C-N=N-C type structure and of formulas I, II or III (set forth in the specification) having amine or carboxyl functionality. The second composition comprises an oil phase. The oil phase comprises: i) one or more multi functional acrylate or methacrylate monomers or oligomers and substantially free of amine acrylate or amine methacrylate monomer or oligomer, and an initiator dispersible in the oil phase; ii) from 0 to 10% by weight of the oil phase, of a monofunctional acrylate or methacrylate monomer or oligomer; iii) an intended core material; and iv) a diluent selected from esters of glycerol and fatty acids wherein at least one of the fatty acids is C12 or greater; wherein the ratio of the water phase initiator to multifunctional acrylate or methacrylate is from 0.1 :99.9 to 20:80 by weight; wherein the ratio of the diluent to the core material is from 0.1 :99.9 to 90:10 on a weight basis; and whereby the reaction product of the first composition and second composition results in the formation of a population of micro-capsules.

2. 发明专利

MX2017003643A MATERIAL PARA GRABAR SIN REVESTIMIENTO. 未知
公开(公告)号：MX2017003643A
公开(公告)日：2017-06-26
申请号：MX2017003643
申请日：2015-09-17
申请人： APPVION INC
发明人： MARK ROBERT FISHER
IPC分类号： B41M5/26 , B32B7/00 , B32B27/00 , B41M5/40 , B41M5/50 , C09J7/02
摘要： La invención describe una composición y un método para proporcionar un material para grabar mejorado, tal como material para grabar receptor de tinta o material para grabar térmicamente sensible útil para etiquetas sin revestimiento. El material para grabar comprende un soporte que tiene provisto sobre una superficie un material adhesivo y en al menos la otra superficie un material receptor de tinta o un revestimiento formador de imágenes térmicamente sensible. El método consiste aplicar a una primera superficie una primera capa de un revestimiento de un material receptor de tinta o una composición formadora de color térmicamente sensible la composición formador de color comprende un material aglutinante y un precursor de colorante sustancialmente incoloro y un material revelador ácido en una relación sustancialmente continua. El adhesivo se activa por calor. El material para grabar no presenta sustancialmente pegajosidad a 23°C, humedad relativa de 40% cuando se aplica presión, sin embargo desarrolla una lata resistencia al desprendimiento (300 gramos/pulgada - 118 gramos/cm) después de la aplicación de 7 mJ/mm2 a 13 mJ/mm2 de energía calorífica.

3. 发明专利

CA2897208A1 COATED PAPER 未知
公开(公告)号：CA2897208A1
公开(公告)日：2014-12-24
申请号：CA2897208
申请日：2014-06-11
申请人： APPVION INC
发明人： YAN NIANXI , DEBRAAL JOHN CHARLES
IPC分类号： D21H19/36 , D21H19/38 , D21H19/58 , D21H19/60 , D21H19/66
摘要： A coated paper with enhanced properties and/or lower cost can be obtained by using a coating that contains a binder and stanchion-encapsulated titanium dioxide. The stanchion- encapsulated titanium dioxide can provide the same or similar brightness, gloss, and/or opacity while using less titanium dioxide.

4. 发明专利

CA2896514A1 MICROCAPSULE PARTICLES 未知
公开(公告)号：CA2896514A1
公开(公告)日：2014-07-03
申请号：CA2896514
申请日：2013-12-12
申请人： APPVION INC
发明人： SCHWANTES TODD ARLIN
IPC分类号： B01J13/14 , B01J13/18
摘要： The present invention teaches microcapsule particles comprising an oil soluble or dispersible core material; and a wall material at least partially surrounding the core material, the microcapsule wall material consisting of the reaction product of a first composition in the presence of a second composition; the first composition comprising a water phase: the water phase comprising a water soluble or dispersible initiator having at least one -COOH or amine functional group and a nonionic emulsifier, the emulsifier comprising a water soluble or dispersible material at a pH from 4 to 12, the water soluble or dispersible initiator is selected from initiators having a C-N=N-C type structure and of formulas I, II or III (set forth in the specification) having amine or carboxyl functionality. The second composition comprises an oil phase. The oil phase comprises: i) one or more multi functional acrylate or methacrylate monomers or oligomers and substantially free of amine acrylate or amine methacrylate monomer or oligomer, and an initiator dispersible in the oil phase; ii) from 0 to 10% by weight of the oil phase, of a monofunctional acrylate or methacrylate monomer or oligomer; iii) an intended core material; and iv) a diluent selected from esters of glycerol and fatty acids wherein at least one of the fatty acids is C12 or greater; wherein the ratio of the water phase initiator to multifunctional acrylate or methacrylate is from 0.1 :99.9 to 20:80 by weight; wherein the ratio of the diluent to the core material is from 0.1 :99.9 to 90:10 on a weight basis; and whereby the reaction product of the first composition and second composition results in the formation of a population of microcapsules.

5. 发明专利

CA2897208C PAPER COATED WITH STANCHION ENCAPSULATED PIGMENT 未知
公开(公告)号：CA2897208C
公开(公告)日：2021-06-15
申请号：CA2897208
申请日：2014-06-11
申请人： APPVION INC
发明人： YAN NIANXI , DEBRAAL JOHN CHARLES
IPC分类号： D21H19/36 , D21H19/38 , D21H19/44 , D21H19/58 , D21H19/60
摘要： A coated paper with enhanced properties and/or lower cost can be obtained by using a coating that contains a binder and stanchion-encapsulated titanium dioxide. The stanchion- encapsulated titanium dioxide can provide the same or similar brightness, gloss, and/or opacity while using less titanium dioxide.

6. 发明专利

CA2915013A1 THERMAL RECORDING MATERIALS 未知
公开(公告)号：CA2915013A1
公开(公告)日：2015-06-25
申请号：CA2915013
申请日：2014-12-02
申请人： APPVION INC
发明人： CHAKAR FADI SELIM , WARNER JOHN CHARLES , WHITFIELD JUSTIN ROBERT , LUGUS MICHELLE WANCH LI , BANERJEE DEBOSHRI
IPC分类号： B41M5/323 , B41M5/333 , B41M5/337
摘要： A thermal recording material having a heat-sensitive color-forming layer that contains a phosphate modifier in addition to an activator and lueco dye can provide good imaging. The phosphate modifier such as unsubstituted dibenzyl phosphate can be paired with an activator such 3 -(4-hydroxyphenyl)propionic acid to provide an environmentally friendly thermal recording material.

7. 发明专利

CA2888456A1 THERMALLY-RESPONSIVE RECORD MATERIAL 未知
公开(公告)号：CA2888456A1
公开(公告)日：2014-09-18
申请号：CA2888456
申请日：2013-10-11
申请人： APPVION INC
发明人： CHAKAR FADI SELIM , FISHER MARK ROBERT
IPC分类号： B41M5/327 , B41M5/333 , B41M5/337 , G06K19/08 , G06K19/14
摘要： The invention describes a thermally-responsive record material substantially free of aromatic isocyanate. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless dye precursor comprising a fluoran; and a developer material selected from the group consisting of 4,4'-diaminodiphenylsulfone and 3,3'-diaminodiphenylsulfone, which upon being heated react with said dye precursor to develop color, and including a binder material. Optionally, one or more of an organic acid, a modifier compound, or magnesium stearate is included in the heat-sensitive composition. The modifier compound can be selected from the a fatty acid amide, preferably a saturated fatty acid amide such as an alkyl amide, a bis methylene alkyl amide, or a bis ethylene alkyl amide.

8. 发明专利

AU2012262798A1 Charcoal having encapsulated igniter material 未知
公开(公告)号：AU2012262798A1
公开(公告)日：2014-01-16
申请号：AU2012262798
申请日：2012-05-22
申请人： APPVION INC
发明人： SEEHAFER TROY RONALD , DEBRAAL JOHN CHARLES
IPC分类号： C10L5/44 , C10L5/14 , C10L5/32 , C10L9/00
摘要： The properties of charcoal can be improved by providing microcapsules containing an ignitable material on or within the charcoal. The microcapsules can be made of polyacrylate and the ignitable material includes hydrocarbons such as a paraffin combination, alcohols, and combinations.

9. 发明申请

US20190193447A1 PRINTABLE AND SCUFF RESISTANT SILICONE RELEASE COATING FOR LINERLESS THERMALLY-RESPONSIVE RECORD MATERIAL 审中-公开
公开(公告)号：US20190193447A1
公开(公告)日：2019-06-27
申请号：US15855608
申请日：2017-12-27
申请人： APPVION, INC.
发明人： Mark FISHER , Yves DEFRENNE , Lei XU
IPC分类号： B41M5/40 , C09D183/04 , C09D7/61
CPC分类号： B41M5/40 , C09D7/61 , C09D183/04
摘要： The present invention is directed to a composition and method of providing a silicone release coating material for a thermally-responsive record material while maintaining strong printability with UV inks and water based inks, as well as scuff resistance. The thermally-responsive record material includes a substrate with first and second surfaces. The first surface includes a heat sensitive coating having a colorless dye precursor and an acidic developer material in contiguous relationship. The release coating is provided with an aqueous mixture of a water soluble or water dispersible polymeric material, a silicone release agent, an excess of platinum catalyst, and a hydrophilic silica. The platinum catalyst is preferably provided in excess of 150 ppm. The hydrophilic silica is preferably fumed silica. The release coating is cured at a temperature of 160° C. or less, or even from 70° C. to 120° C.

10. 发明申请

US20170340955A1 THERMALLY IMAGEABLE SUBSTRATE WITH ENCAPSULATED COREACTANT 审中-公开
公开(公告)号：US20170340955A1
公开(公告)日：2017-11-30
申请号：US15163129
申请日：2016-05-24
申请人： APPVION, INC.
发明人： Michael Gerald COVE
IPC分类号： A63F3/06 , B41J2/32 , B41J2/525
CPC分类号： A63F3/0665 , A63F3/0685 , B41J2/32 , B41J2/525
摘要： A substrate thermal sensitive system for creating a latent image that is useful as a scratch-off ticket that comprises a substrate and a first layer that is superimposed on the substrate. The first layer contains a plurality of microcapsules with a dye precursor or a solvent. The microcapsules are configured to rupture from pressure. The substrate thermal sensitive system further has an acidic developer layer coated over the first layer and containing a co-reactant. Particles of the co-reactant are coated with a meltable material, which is configured to melt when the heat is applied. The system further may include a scratch-off layer coated over the acidic developer layer. The system is configured such that when the meltable material is melted by the thermal printing device and the microcapsules are ruptured, the co-reactant of acidic developer layer reacts with the dye or the solvent of the first layer to develop color.

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