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1. 发明申请

WO2006095910A1 HYDROGEN-GENERATING APPARATUS AND FUEL CELL SYSTEM 审中-公开
标题翻译：氢气发生装置和燃料电池系统
公开(公告)号：WO2006095910A1
公开(公告)日：2006-09-14
申请号：PCT/JP2006/305069
申请日：2006-03-08
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , Kabushiki Kaisha Toyota Chuo Kenkyusho , NAGASAKA, Keisuke , ITO, Naoki , IGUCHI, Satoshi , AOYAMA, Satoshi , AOKI, Hiroshi , SHIMAZU, Takashi , MITSUI, Hiroyuki
发明人： NAGASAKA, Keisuke , ITO, Naoki , IGUCHI, Satoshi , AOYAMA, Satoshi , AOKI, Hiroshi , SHIMAZU, Takashi , MITSUI, Hiroyuki
IPC分类号： H01M8/06 , C01B3/46
CPC分类号： B60L11/1898 , B60L11/1892 , C01B3/46 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , H01M8/04007 , H01M8/0612 , Y02P20/128 , Y02T90/34
摘要： The present invention provides a hydrogen-generating apparatus comprising two catalytic reators cylcically operating reforming and regeneration (combustion) mode, in which the reduction in reforming efficiency associated with an increase in switching frequency to the regeneration reaction can be suppressed, and generation of hydrogen by reforming can stably be performed. In the reforming reaction, a cathode offgas discharged from a hydrogen-separation-membrane fuel cell 30 having a hydrogen-permeating film is supplied to PSR reformers 10 and 20, in which the reforming reaction and the regeneration reaction are performed alternately.
摘要翻译：本发明提供了一种氢气发生装置，其包括两个催化转化器，其循环运行重整和再生（燃烧）模式，其中可以抑制与再生反应的开关频率的增加相关的重整效率的降低，以及通过可以稳定地进行重整。在重整反应中，从具有氢渗透膜的氢分离膜燃料电池30排出的阴极废气被供给到重整反应和再生反应交替进行的PSR重整器10和20中。

2. 发明申请

WO2005057711A3 FUEL CELL MANUFACTURING METHOD AND FUEL CELL 审中-公开
公开(公告)号：WO2005057711A3
公开(公告)日：2005-06-23
申请号：PCT/JP2004/018095
申请日：2004-11-29
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , AOYAMA, Satoshi , ITO, Naoki , SATO, Hiromichi
发明人： AOYAMA, Satoshi , ITO, Naoki , SATO, Hiromichi
IPC分类号： H01M8/12
摘要： The manufacturing method of the invention is applied to manufacture a unit fuel cell 20, which has a hydrogen-permeable metal layer 22 of a hydrogen-permeable metal and an electrolyte layer 21 that is located on the hydrogen-permeable metal layer 22 and has proton conductivity. The method first forms the electrolyte layer 21 on the hydrogen-permeable metal layer 22, and subsequently forms an electrically conductive cathode 24 on the electrolyte layer 21 to block off an electrical connection between the cathode 24 and the hydrogen-permeable metal layer 22. The method releases Pd toward the electrolyte layer 21 in a direction substantially perpendicular to the electrolyte layer 21 to form a Pd layer as the cathode 24 that is thinner than the electrolyte layer 21. This arrangement of the invention effective prevents a potential short circuit, for example, between the cathode and the hydrogen-permeable metal layer, in the fuel cell, due to pores present in the electrolyte layer.

3. 发明申请

WO2005057711A2 FUEL CELL MANUFACTURING METHOD AND FUEL CELL 审中-公开
标题翻译：燃料电池制造方法和燃料电池
公开(公告)号：WO2005057711A2
公开(公告)日：2005-06-23
申请号：PCT/JP2004018095
申请日：2004-11-29
申请人： TOYOTA MOTOR CO LTD , AOYAMA SATOSHI , ITO NAOKI , SATO HIROMICHI
发明人： AOYAMA SATOSHI , ITO NAOKI , SATO HIROMICHI
IPC分类号： H01M8/02 , H01M4/86 , H01M4/88 , H01M4/94 , H01M8/04 , H01M8/10 , H01M8/12
CPC分类号： H01M8/04216 , H01M4/881 , H01M4/8817 , H01M4/8867 , H01M4/94 , H01M8/1004 , H01M2300/0091 , Y02P70/56
摘要： The manufacturing method of the invention is applied to manufacture a unit fuel cell 20, which has a hydrogen-permeable metal layer 22 of a hydrogen-permeable metal and an electrolyte layer 21 that is located on the hydrogen-permeable metal layer 22 and has proton conductivity. The method first forms the electrolyte layer 21 on the hydrogen-permeable metal layer 22, and subsequently forms an electrically conductive cathode 24 on the electrolyte layer 21 to block off an electrical connection between the cathode 24 and the hydrogen-permeable metal layer 22. The method releases Pd toward the electrolyte layer 21 in a direction substantially perpendicular to the electrolyte layer 21 to form a Pd layer as the cathode 24 that is thinner than the electrolyte layer 21. This arrangement of the invention effective prevents a potential short circuit, for example, between the cathode and the hydrogen-permeable metal layer, in the fuel cell, due to pores present in the electrolyte layer.
摘要翻译：本发明的制造方法适用于制造具有透氢性金属的透氢性金属层22和位于透氢性金属层22上且具有质子的电解质层21的单位燃料电池20 电导率。该方法首先在氢可渗透金属层22上形成电解质层21，随后在电解质层21上形成导电阴极24，以阻断阴极24与透氢金属层22之间的电连接。方法在基本上垂直于电解质层21的方向上向电解质层21释放Pd，以形成比电解质层21薄的作为阴极24的Pd层。本发明的这种布置有效地防止了电位短路，例如在阴极和透氢性金属层之间，在燃料电池中，由于存在于电解质层中的孔。

4. 发明申请

WO2007105056A3 FUEL CELL ELECTRIC VEHICLE AND METHOD OF CHANGING POSITION OF FUEL CELL STACK 审中-公开
标题翻译：燃料电池车辆及其改变燃料电池堆叠位置的方法
公开(公告)号：WO2007105056A3
公开(公告)日：2008-01-17
申请号：PCT/IB2007000555
申请日：2007-03-09
申请人： TOYOTA MOTOR CO LTD , AOYAMA SATOSHI
发明人： AOYAMA SATOSHI
IPC分类号： B60K1/04
CPC分类号： B60K1/04 , B60K15/063 , B60K2001/005 , B60L11/1881 , H01M8/04007 , H01M2250/20 , Y02T90/32 , Y02T90/34
摘要： A fuel cell electric vehicle (100) includes a fuel cell stack (l), and a plurality of mounting/demounting sites (11-16) in or from which the fuel cell stack (l) can be mounted or demounted. The fuel cell stack (l) is mounted in a selected one of the mounting/demounting sites (11-16), so that the fuel cell stack (l) can be efficiently warmed up by effectively utilizing heat liberated from the ambient atmosphere or each device of the vehicle, or so that heat produced by the fuel cell stack (l) can be effectively utilized.
摘要翻译：燃料电池电动车辆（100）包括燃料电池堆（1），以及可以安装或拆卸燃料电池堆（1）的多个安装/拆卸位置（11-16）。燃料电池堆（1）安装在所选择的一个安装/拆卸位置（11-16）中，使得燃料电池堆（1）可以通过有效地利用从环境大气释放的热或每个车辆的装置，或者使得可以有效地利用由燃料电池堆（1）产生的热量。

5. 发明申请

WO2007069617A1 METHOD OF MANUFACTURING FUEL CELL WITH ELECTROLYTE LAYER FORMED ON A HYDROGEN-PERMEABLE MEMBRANE 审中-公开
标题翻译：在氢气渗透膜上形成电解质层的燃料电池的制造方法
公开(公告)号：WO2007069617A1
公开(公告)日：2007-06-21
申请号：PCT/JP2006/324783
申请日：2006-12-06
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , AOYAMA, Satoshi
发明人： AOYAMA, Satoshi
IPC分类号： H01M8/12
CPC分类号： H01M4/94 , B01D53/228 , B01D67/0083 , B01D71/022 , B01D2323/08 , C01B3/505 , C01B2203/066 , H01M4/8885 , H01M4/9058 , H01M8/124 , H01M8/126 , H01M2004/8684 , H01M2300/0068 , Y02E60/525 , Y02P70/56
摘要： A method of manufacturing a fuel cell includes thermally treating a hydrogen permeable membrane in a given temperature higher than an actual operating temperature of the fuel cell, and forming an electrolyte layer on the hydrogen permeable membrane subjected to the thermal treatment. The hydrogen permeable membrane is composed of a polycrystalline metal.
摘要翻译：制造燃料电池的方法包括在比燃料电池的实际工作温度高的给定温度下对氢可渗透膜进行热处理，并在经过热处理的氢可渗透膜上形成电解质层。氢可渗透膜由多晶金属组成。

6. 发明申请

WO2007049130A1 HYDROGEN SEPARATION MEMBRANE WITH A CARRIER, FUEL CELL AND HYDROGEN SEPARATION APPARATUS HAVING SAME, AND METHOD OF MANUFACTURING SAME 审中-公开
标题翻译：具有载体，燃料电池和氢分离装置的氢分离膜及其制造方法
公开(公告)号：WO2007049130A1
公开(公告)日：2007-05-03
申请号：PCT/IB2006/002991
申请日：2006-10-25
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , TOYO KOHAN CO., LTD. , AOYAMA, Satoshi , IZAWA, Yasuhiro , KIMURA, Kenji , OHSAWA, Shinji , YOSHIDA, Kazuo , NANBU, Kouji
发明人： AOYAMA, Satoshi , IZAWA, Yasuhiro , KIMURA, Kenji , OHSAWA, Shinji , YOSHIDA, Kazuo , NANBU, Kouji
IPC分类号： H01M8/06 , H01M4/94 , B01D53/22 , B01D71/02 , C01B3/50
CPC分类号： H01M8/0625 , B01D53/228 , B01D67/0062 , B01D69/10 , B01D71/022 , C01B3/505 , H01M4/94 , H01M8/0637 , H01M8/0662 , Y02E60/50 , Y02E60/566 , Y10T29/49108
摘要： A method of manufacturing a hydrogen separation membrane with a carrier is characterized by including a first step of providing, between the hydrogen separation membrane and the carrier that supports the hydrogen separation membrane, a low-hardness metal membrane having a hardness that is lower than the hardness of the hydrogen separation membrane, and a second step of joining the hydrogen separation membrane, the low-hardness metal membrane, and the carrier by a cold joining method. In this case, it is possible to suppress the deformation of the hydrogen separation membrane, the low-hardness metal membrane, and the carrier and, as a result, it is possible to prevent damaging of the hydrogen separation membrane. The adhesion of the contact between the hydrogen separation membrane and the carrier is also improved. The result is that it is not necessary to increase the severity of the cold joining conditions.
摘要翻译：一种制备具有载体的氢分离膜的方法的特征在于包括：在氢分离膜和支撑氢分离膜的载体之间提供硬度低于所述氢分离膜的低硬度金属膜的第一步骤氢分离膜的硬度，以及通过冷连接法连接氢分离膜，低硬度金属膜和载体的第二工序。在这种情况下，可以抑制氢分离膜，低硬度金属膜和载体的变形，结果可以防止氢分离膜的破坏。氢分离膜和载体之间的接触的粘附性也得到改善。结果是，不需要增加冷连接条件的严重性。

7. 发明申请

WO2006018705A2 MEMBRANE-ELECTRODE ASSEMBLY AND FUEL CELL 审中-公开
标题翻译：膜电极组件和燃料电池
公开(公告)号：WO2006018705A2
公开(公告)日：2006-02-23
申请号：PCT/IB2005002441
申请日：2005-08-17
申请人： TOYOTA MOTOR CO LTD , AOYAMA SATOSHI , IGUCHI SATOSHI , TANIGUCHI MAKOTO
发明人： AOYAMA SATOSHI , IGUCHI SATOSHI , TANIGUCHI MAKOTO
IPC分类号： H01M8/12 , H01M4/94
CPC分类号： C01B3/501 , C01B2203/0405 , H01M4/9033 , H01M4/9041 , H01M4/94 , H01M8/0232 , H01M8/0267 , H01M8/0297 , H01M8/241 , H01M8/2457 , H01M8/2483 , H01M2008/1293
摘要： An electrolyte layer (121) and a hydrogen-permeable metal layer (122) are fitted in a fitting portion (131) of a low thermal expansion member (130), and a cathode electrode (110) is provided on the electrolyte layer (121). Gas separators (100, 150) are provided such that a low thermal expansion member (130) is held between the gas separators (100, 150). Since the low thermal expansion member (130) is made of metal which has a. thermal expansion coefficient lower than that of the hydrogen-permeable metal layer (122), thermal expansion of the hydrogen-permeable metal layer (122) can be suppressed. Accordingly, it is possible to reduce shear stress applied to an interface between the electrolyte layer (121) and the hydrogen-permeable metal layer (122) due to the thermal expansion. It is possible to suppress separation of the electrolyte layer (121) from the hydrogen-permeable metal layer (122) and occurrence of a crack in the electrolyte layer (121).
摘要翻译：电解质层（121）和透氢性金属层（122）嵌合在低热膨胀部件（130）的嵌合部（131）中，阴极电极（110）设置在电解质层）。气体分离器（100,150）被设置成使得低热膨胀构件（130）保持在气体分离器（100,150）之间。由于低热膨胀构件（130）由具有a的金属制成。热膨胀系数低于透氢性金属层（122）的热膨胀系数，可以抑制透氢性金属层（122）的热膨胀。因此，由于热膨胀，可以减少施加到电解质层（121）和氢可渗透金属层（122）之间的界面的剪切应力。可以抑制电解质层（121）与透氢性金属层（122）的分离，并且在电解质层（121）中产生裂纹。

8. 发明申请

WO2005102918A1 HYDROGEN SEPARATION MEMBRANE AND FUEL CELL, AND MANUFACTURING METHOD THEREFOR 审中-公开
标题翻译：氢分离膜和燃料电池及其制造方法
公开(公告)号：WO2005102918A1
公开(公告)日：2005-11-03
申请号：PCT/JP2005/007270
申请日：2005-04-07
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , AOYAMA, Satoshi
发明人： AOYAMA, Satoshi
IPC分类号： C01B3/50
CPC分类号： C01B3/505 , B01D67/0072 , B01D67/0093 , B01D69/00 , B01D69/12 , B01D71/022 , B01D71/024 , B01D2325/06 , B01D2325/10 , B01D2325/26 , B01J23/40 , B01J35/065 , B01J37/0238 , C01B2203/0405 , H01M4/94 , H01M2004/8684 , Y10S55/05
摘要： A method of manufacturing a hydrogen separation membrane comprises the steps of forming an intermediate layer suitable for controlling oxidation of a hydrogen permeable metal layer on the surface of the hydrogen permeable metal layer on the surface of the hydrogen permeable metal used as a substrate; and attaching a catalytic metal in a granular form on the surface of the intermediate layer. This method can be used to manufacture a hydrogen separation membrane in which the quantity of catalytic metal used is controlled.
摘要翻译：制造氢分离膜的方法包括以下步骤：在用作基底的氢渗透性金属的表面上形成适于控制氢可渗透金属层表面上的氢可渗透金属层的氧化的中间层; 以及在所述中间层的表面上附着颗粒状的催化剂金属。该方法可用于制造控制所用催化金属的量的氢分离膜。

9. 发明申请

WO2008029900A1 FUEL CELL 审中-公开
标题翻译：燃料电池
公开(公告)号：WO2008029900A1
公开(公告)日：2008-03-13
申请号：PCT/JP2007/067459
申请日：2007-08-31
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , AOYAMA, Satoshi
发明人： AOYAMA, Satoshi
IPC分类号： H01M4/94 , H01M4/92 , H01M4/12 , H01M4/86
CPC分类号： H01M8/1246 , H01M4/8657 , H01M4/9058 , H01M4/92 , H01M4/921 , H01M4/94 , H01M8/1226 , H01M2004/8684 , Y02E60/525 , Y02P70/56
摘要： A fuel cell includes a hydrogen permeable metal substrate and an electrolyte layer. The hydrogen permeable metal substrate acts as an anode. The electrolyte layer is provided on the hydrogen permeable metal substrate and has proton conductivity. At least a part of the hydrogen permeable metal substrate is composed of a metal having a recrystallization temperature higher than a given temperature
摘要翻译：燃料电池包括透氢金属基底和电解质层。氢可渗透金属基底用作阳极。电解质层设置在氢可渗透金属基板上，具有质子传导性。氢可渗透金属基材的至少一部分由重结晶温度高于给定温度的金属构成

10. 发明申请

WO2005062412A3 FUEL CELL 审中-公开
公开(公告)号：WO2005062412A3
公开(公告)日：2005-07-07
申请号：PCT/JP2004/019292
申请日：2004-12-16
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , AOYAMA, Satoshi , ITO, Naoki , IIJIMA, Masahiko , OGINO, Shigeru , KIMURA, Kenji , SATO, Hiromichi , IZAWA, Yasuhiro , IGUCHI, Satoshi
发明人： AOYAMA, Satoshi , ITO, Naoki , IIJIMA, Masahiko , OGINO, Shigeru , KIMURA, Kenji , SATO, Hiromichi , IZAWA, Yasuhiro , IGUCHI, Satoshi
IPC分类号： H01M8/10 , H01M4/86 , H01M4/88 , H01M4/92 , H01M4/94 , H01M8/02
摘要： A fuel cell of the invention has a hydrogen permeable metal layer, which is formed on a plane of an electrolyte layer that has proton conductivity and includes a hydrogen permeable metal. The fuel cell includes a higher temperature zone and a lower temperature zone that has a lower temperature than the higher temperature zone. The hydrogen permeable metal layer includes a lower temperature area A corresponding to the lower temperature zone and a higher temperature area B corresponding to the higher temperature zone. The lower temperature area A and the higher temperature area B have different settings of composition and/or layout of components. This arrangement effectively prevents potential deterioration of cell performance due to an uneven distribution of internal temperature of the fuel cell including the hydrogen permeable metal layer.

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