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    • 6. 发明申请
    • METHOD FOR PRODUCING AQUEOUS ACTIVE SUBSTANCE COMPOSITIONS OF ACTIVE SUBSTANCES THAT ARE HARDLY SOLUBLE IN WATER
    • 法产水难溶活性剂的水性活性化合物
    • WO2006015791A3
    • 2006-05-04
    • PCT/EP2005008430
    • 2005-08-03
    • BASF AGAMRHEIN PATRICKSCHOEPKE HOLGERKLEIST GUNNARKLUGE MICHAEL
    • AMRHEIN PATRICKSCHOEPKE HOLGERKLEIST GUNNARKLUGE MICHAEL
    • A01N25/04A01N25/26A01N25/28A01N25A01N43/36A01N43/653A01N53/00B27K5/00
    • A01N43/36A01N25/04A01N25/26A01N25/28A01N43/653A01N53/00B27K3/007B27K3/15C08L33/08C08L35/02C08L97/02A01N2300/00
    • The invention relates to a method for producing aqueous active substance compositions of active substances that are hardly soluble in water, especially of active substances for use in the protection of plants and materials. The invention also relates to the active substance compositions obtained according to the inventive method and to their use in the control of harmful organisms in the protection of plants and materials. The inventive method comprises the following steps: a) providing an aqueous suspension of solid active substance particles of at least one active substance having a water solubility of not more than 5 g/l at 25 °C/1013 mbar and comprising at least one surface-active substance for stabilizing the active substance particles, whereby the active substance particles in the suspension have an average particle size, determined by dynamic light scattering, of not more than 1200 nm; b) emulsion polymerization of a first monomer composition M1 in the aqueous suspension of the active substance, whereby the monomer composition M1 comprises at least 95 % by weight, based on its total weight, of at least one neutral, monoethylenically unsaturated monomer M1.1 having a water solubility of not more than 30 g/l at 25 °C/1013 mbar, thereby obtaining an aqueous dispersion of polymer/active substance particles; and c) emulsion polymerization of a second monomer composition M2 in an aqueous dispersion of the polymer/active substance particles obtained in step b), whereby the monomer composition M2 comprises at least 60 % by weight, based on its total weight, of at least one neutral, monoethylenically unsaturated monomer M2.1 having a water solubility of not more than 30 g/l at 25 °C/1013 mbar.
    • 本发明涉及一种用于生产微溶于水的活性剂的含水活性物质组合物的方法,特别是对植物和材料保护的活性物质。 本发明还由处理它们在植物和材料保护Bekämpfungen使用的有害生物涉及药物组合物和获得。 该方法包括以下步骤:a)提供至少一种活性成分的固体活性化合物颗粒的水悬浮液与不大于5克/升,在25℃/ 1013毫巴下的水溶解度,其包括用于稳定活性化合物颗粒,至少一种表面活性剂,其中,所述 在悬浮液中的活性剂的颗粒具有不大于1200纳米的平均粒径,通过动态光散射测定,具有,b)第一单体ML中的活性成分的含水悬浮液,其中所述单体溶液在至少95重量%,基于乳液聚合其 包括总重量,至少一种中性,单烯属不饱和单体具有不超过30g / l,在25℃/ 1013毫巴下,由此获得的聚合物的药物颗粒的水性分散体的水溶解度和c)乳液聚合的M1.1 在第二单体组合物M2 在步骤b中得到的水分散液)聚合物 - 药物的颗粒,其中所述单体组合物M2至少60重量%,基于它的总重量,具有不超过30g的水溶解度的至少一种中性,单烯属不饱和单体M2.1 /升 25℃/ 1013毫巴下包括。