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    • 4. 发明专利
    • DE2446319C3
    • 1983-11-10
    • DE2446319
    • 1974-09-27
    • NIPPON LIGHT METAL RESEARCH LABORATORY LTD.TOHO CHEMICAL INDUSTRY CO. LTD., TOKYO, JP
    • SUGIYAMA, NOBORU, SHIZUOKA, JPSUZUKI, MASAMICHI, SHIMIZU, SHIZUOKA, JPWATANABE, KATUMISUGIYAMA, KEIICHI, FUJI, SHIZUOKA, JPTADENUMA, HACHIRO, TOKYO, JPKATO, TAKASHI, YOKOSUKA, KANAGAWA, JPKANEDA, RYOJI, ZUSHI, KANAGAWA, JPYOSHINO, MAKOTO, YOKOHAMA, KANAGAWA, JP
    • C10M173/00C10M3/40C10M3/20
    • A lubricating composition for metal working comprising A. about 10 to 60% by weight of a water-soluble non-ionic surfactant component comprising at least one of I. A POLYOXYALKYLENE GLYCOL ESTER OF A FATTY ACID REPRESENTED BY THE GENERAL FORMULA (I) R1COO(R2O)nH (I) or the general formula (II) R1COO(R2O)nOCR1 (II) ii. a polyoxyalkylene glycol ether of a fatty alcohol represented by the general formula (III) R3O(R2O)nH (III) iii. a polyoxyalkylene glycol ether of a fatty alcohol esterified with a fatty acid represented by the general formula (IV) R3O(R2O)nOCR1 (IV) and IV. A POLYOXYALKYLENE GLYCOL CONDENSATE OF A GLYCERIDE ESTERIFIED WITH A FATTY ACID REPRESENTED BY THE GENERAL FORMULA (V) CH2OCOR1 O(R2O)pOCR1 ¦ CH-OCOR1 O(R2O)qR4 (V) ¦ CH2OCOR1 O(R2O)rR4 wherein R1CO represents a saturated or unsaturated fatty acid acyl group having about 12 to 22 carbon atoms; R1 CO represents a saturated or unsaturated fatty acid acyl group having about 12 t0 22 carbon atoms and containing a hydroxy group; R2 represents an ethylene group; R3 represents an alkyl or alkenyl group having about 12 to 22 carbon atoms; R4 represents a hydrogen atom or a R1CO group; N IS AN INTEGER OF ABOUT 10 TO 20; AND P, Q, R, EACH IS AN INTEGER WITH THE SUM OF P, Q AND R RANGING FROM ABOUT 25 TO 40 WHEN ONE OR BOTH OF R4 is a hydrogen atom and from about 40 to 60 when R4 is a R1CO group; B. about 10 to 40% by weight of an oil-soluble nonionic surfactant component comprising at least one of I. A POLYOXYALKYLENE GLYCOL ESTER OF A FATTY ACID REPRESENTED BY THE GENERAL FORMULA (VI) R1COO(R5O)mH (VI) or the general formula (VII) R1COO(R5O)mOCR1 (VII) ii. a polyoxyalkylene glycol ether of a fatty alcohol represented by the general formula (VIII) R3O(R5O)mH (VIII) iii. a polyoxyalkylene glycol ether of a fatty alcohol esterified with a fatty acid represented by the general formula (IX) R3O(R5O)mOCR1 (IX) and IV. A POLYOXYALKYLENE GLYCOL CONDENSATE OF A GLYCERIDE ESTERIFIED WITH A FATTY ACID REPRESENTED BY THE GENERAL FORMULA (X) CH2OCOR1 O(R5O)sOCR1 ¦ CH-OCOR1 O(R5O)tR4 (X) ¦ CH2OCOR1 O(R5O)uR4 wherein R1 CO, R2, R3 and R4 are as defined above; R5 is an Alkylene group having 2 to 4 carbon atoms m is an integer of about 1 to 5; and s, t and u each is an integer with the sum of s, t and u ranging from about 3 to 20; and C. about 10 to 50% by weight of an anionic or nonionic surfactant component comprising at least one of i. a phosphate ester and/or salt of a phosphate ester with the adduct of a polyoxyalkylene glycol, with an alcohol or an alkylphenol represented by the general formula (XI) the general formula (XII) O PARALLEL R6O(R2O)a-P-OM (XI) ¦ OM or the general formula (XIII) O PARALLEL R6O(R2O)b-P-(R2O)bOR6 (XII) ¦ OM O PARALLEL R6O(R2O)d-P-(R2O)eOR6 (XIII) ¦ (R2O)fOR6 wherein R2 is as defined above; R6 is an alkyl group, an alkenyl group or an alkaryl group having about 12 to 18 carbon atoms; M is an alkali metal atom, an alkylamine group or an alkanolamine group; a is an integer ranging from about 2 to 15; b and c each is an integer with the sum of b and c divided by 2 ranging from about 2 to 15; and c, d and e each is an integer with the sum of c, d and e divided by 3 ranging from about 3 to 10; and ii. an alkali metal salt, alkylamine salt and/or alkanolamine salt of a fatty acid represented by the general formula (XIV) R1COOM (XIV) wherein R1CO and M are as above defined.
    • 10. 发明授权
    • Water-soluble metal working lubricants
    • US3945930A
    • 1976-03-23
    • US510193
    • 1974-09-30
    • Noboru SugiyamaMasamichi SuzukiKatami WatanabeKeiichi SugiyamaHachiro TadenumaTakashi KatoRyoji KanedaMakoto Yoshino
    • Noboru SugiyamaMasamichi SuzukiKatami WatanabeKeiichi SugiyamaHachiro TadenumaTakashi KatoRyoji KanedaMakoto Yoshino
    • C10M173/00C10M1/44C10M3/38C10M5/24C10M7/24
    • C10M173/00C10M2201/02C10M2207/022C10M2207/04C10M2207/046C10M2207/125C10M2207/129C10M2207/283C10M2207/289C10M2207/40C10M2207/404C10M2209/103C10M2209/104C10M2209/105C10M2209/106C10M2209/109C10M2215/04C10M2215/042C10M2215/044C10M2215/067C10M2215/26C10M2223/04C10M2223/042C10M2223/043C10M2225/00C10M2225/02C10N2240/402C10N2240/403C10N2240/404C10N2240/405C10N2240/406C10N2240/407C10N2240/408C10N2240/409C10N2250/02
    • A lubricating composition for metal working comprisingA. about 10 to 60% by weight of a water-soluble non-ionic surfactant component comprising at least one ofI. a polyoxyalkylene glycol ester of a fatty acid represented by the general formula (I)r.sup.1 coo(r.sup.2 o).sub.n H (I)or the general formula (II)R.sup.1 COO(R.sup.2 O).sub.n OCR.sup.1 (II)ii. a polyoxyalkylene glycol ether of a fatty alcohol represented by the general formula (III)R.sup.3 O(R.sup.2 O).sub.n H (III)iii. a polyoxyalkylene glycol ether of a fatty alcohol esterified with a fatty acid represented by the general formula (IV)r.sup.3 o(r.sup.2 o).sub.n OCR.sup.1 (IV)andIv. a polyoxyalkylene glycol condensate of a glyceride esterified with a fatty acid represented by the general formula (V) ##EQU1## wherein R.sup.1 CO represents a saturated or unsaturated fatty acid acyl group having about 12 to 22 carbon atoms;R.sup.1.sup.' co represents a saturated or unsaturated fatty acid acyl group having about 12 t0 22 carbon atoms and containing a hydroxy group;R.sup.2 represents an ethylene group;R.sup.3 represents an alkyl or alkenyl group having about 12 to 22 carbon atoms;R.sup.4 represents a hydrogen atom or a R.sup.1 CO group;n is an integer of about 10 to 20; andp, q, r, each is an integer with the sum of p, q and r ranging from about 25 to 40 when one or both of R.sup.4 is a hydrogen atom and from about 40 to 60 when R.sup.4 is a R.sup.1 CO group;B. about 10 to 40% by weight of an oil-soluble nonionic surfactant component comprising at least one ofI. a polyoxyalkylene glycol ester of a fatty acid represented by the general formula (VI)R.sup.1 COO(R.sup.5 O).sub.m H (VI)or the general formula (VII)R.sup.1 COO(R.sup.5 O).sub.m OCR.sup.1 (VII)ii. a polyoxyalkylene glycol ether of a fatty alcohol represented by the general formula (VIII)R.sup.3 O(R.sup.5 O).sub.m H (VIII)iii. a polyoxyalkylene glycol ether of a fatty alcohol esterified with a fatty acid represented by the general formula (IX)R.sup.3 O(R.sup.5 O).sub.m OCR.sup.1 (IX)andIv. a polyoxyalkylene glycol condensate of a glyceride esterified with a fatty acid represented by the general formula (X) ##EQU2## wherein R.sup.1.sup.' CO, R.sup.2, R.sup.3 and R.sup.4 are as defined above;R.sup.5 is an alkylene group having 2 to 4 carbon atomsm is an integer of about 1 to 5; ands, t and u each is an integer with the sum of s, t andu ranging from about 3 to 20;andC. about 10 to 50% by weight of an anionic or nonionic surfactant component comprising at least one ofi. a phosphate ester and/or salt of a phosphate ester with the adduct of a polyoxyalkylene glycol, with an alcohol or an alkylphenol represented by the general formula (XI)the general formula (XII) ##EQU3## or the general formula (XIII) ##EQU4## whereinR.sup.2 is as defined above; R.sup.6 is an alkyl group, an alkenyl group or an alkaryl group having about 12 to 18 carbon atoms;M is an alkali metal atom, an alkylamine group or an alkanolamine group;a is an integer ranging from about 2 to 15;b and c each is an integer with the sum ofb and c divided by 2 ranging from about 2 to 15; and c, d and e each is an integer with the sum of c, d and e divided by 3 ranging from about 3 to 10; andii. an alkali metal salt, alkylamine salt and/or alkanolamine salt of a fatty acid represented by the general formula (XIV)R.sup.1 COOM (XIV)wherein R.sup.1 CO and M are as above defined.