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    • 4. 发明授权
    • Process for production of 2,3-dichlorobutadiene-1,3
    • 2,3-二氯丁二烯-1,3的制备方法
    • US08026400B2
    • 2011-09-27
    • US12335583
    • 2008-12-16
    • Terry Wayne Redwine
    • Terry Wayne Redwine
    • C07C23/00
    • C07C17/10C07C17/23C07C17/25C07C17/395C07C21/20C07C21/21
    • Purified chlorinated alkenes are produced by a process in which a mixture of i) a first chlorinated alkene that has at least one beta-chlorine substituent and no alpha-chlorine substituents and ii) a second chlorinated alkene that has at least one alpha-chlorine substituent is contacted with chlorine in an amount sufficient to further chlorinate the second chlorinated alkene, but which is insufficient to cause conversion of more than 20% of the first chlorinated alkene. The resultant reaction product may be easily enriched to provide a chlorinated alkene product wherein a) the weight percentage of chlorinated alkenes having at least one beta-chlorine substituent and no alpha-chlorine substituents, based on the total weight of the chlorinated alkenes present in the enriched chlorinated alkene product compared to b) the weight percentage of chlorinated alkenes having at least one beta-chlorine substituent and no alpha-chlorine substituents, based on the total weight of the chlorinated alkenes present in the mixture prior to chlorination is increased by at least 0.25 wt. %.
    • 纯化的氯化烯烃通过以下方法制备,其中i)具有至少一个β-氯取代基且不具有α-氯取代基的第一氯代烯烃的混合物,和ii)具有至少一个α-氯取代基的第二氯代烯烃 与氯接触,其量足以进一步氯化第二氯化烯烃,但不足以引起超过20%的第一氯化烯烃的转化。 所得反应产物可以容易地富集以提供氯化烯烃产物,其中a)基于存在于氯化烯烃中的氯代烯烃的总重量,具有至少一个β-氯取代基且不具有α-氯取代基的氯化烯烃的重量百分数 富含氯化烯烃产物与b)相比,氯化作用下混合物中存在氯化烯烃的总重量至少有一个β-氯取代基和无α-氯取代基的氯化烯烃的重量百分数至少增加 0.25重量% %。
    • 9. 发明授权
    • Process for producing fluoropolymers
    • 制备含氟聚合物的方法
    • US07989566B2
    • 2011-08-02
    • US12354218
    • 2009-01-15
    • Michael Cregg CoughlinMing-Hong Hung
    • Michael Cregg CoughlinMing-Hong Hung
    • C08F12/20
    • C08F14/18C07F9/091C08F2/26C08F2/20
    • An emulsion polymerization process for the production of non-elastomeric fluoropolymers is disclosed wherein at least one fluorosurfactant is employed as dispersant, said fluorosurfactant being a fluoroalkylphosphoric acid ester of the formula X-Rf-(CH2)n—O—P(O)(OM)2, wherein n is 1 or 2, X═H or F, M=a univalent cation, and Rf is a C4-C6 fluoroalkyl or fluoroalkoxy group. Optionally, a second dispersing agent may be employed in the polymerization, said second agent being a perfluoropolyether having at least one endgroup selected from the group consisting of carboxylic acid, a salt thereof, sulfonic acid and a salt thereof, phosphoric acid and a salt thereof.
    • 公开了一种用于生产非弹性体含氟聚合物的乳液聚合方法,其中使用至少一种含氟表面活性剂作为分散剂,所述含氟表面活性剂是式X-Rf-(CH 2)n -O-P(O)的氟代烷基磷酸酯 OM)2,其中n为1或2,X = H或F,M =单价阳离子,Rf为C4-C6氟烷基或氟代烷氧基。 任选地,在聚合中可以使用第二分散剂,所述第二试剂是具有至少一个选自羧酸,其盐,磺酸及其盐的端基的全氟聚醚,磷酸及其盐 。