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81. 发明授权

US5109098A Imines and secondary amines containing hydrogen bonding moieties in their backbone and polymers made therefrom 失效
标题翻译：在其主链中含有氢键部分的亚胺和仲胺和由其制备的聚合物
公开(公告)号：US5109098A
公开(公告)日：1992-04-28
申请号：US497383
申请日：1990-03-21
申请人： Robert F. Harris , Clarence E. Habermann , Michael D. Joseph
发明人： Robert F. Harris , Clarence E. Habermann , Michael D. Joseph
IPC分类号： C08G18/10 , C08G18/12 , C08G18/50 , C08L63/00
CPC分类号： C08G18/5072 , C08G18/10 , C08G18/12 , C08G18/503 , C08G18/5036 , C08L63/00
摘要： Imines and secondary amines comprising a backbone portion containing a plurality of polyalkyleneoxy moieties and one or more internal urea, thiourea, biuret, thiobiuret, amide, or thioamide moieties, and a plurality of imino or secondary amino end groups, wherein each imino or secondary amino end group is separated from a urea, thiourea, biuret, dithiobiuret, amide, or thioamide moiety by at least one alkylene, cycloalkylene, aralkylene, arylene, alkyleneoxy, or ppolyalkyleneoxy moiety are disclosed. Prepolymers and polymers prepared from the imines and secondary amines are also disclosed. In addition, the imines and secondary amines of the invention are also useful as epoxy resin curing agents.
摘要翻译：包含含有多个聚亚烷基氧基部分和一个或多个内部尿素，硫脲，缩二脲，硫代嘌呤，酰胺或硫代酰胺部分的骨架部分和多个亚氨基或仲氨基端基的亚胺和仲胺，其中每个亚氨基或仲氨基公开了通过至少一个亚烷基，亚环烷基，亚芳基，亚芳基，亚烷基氧基或聚亚烷基氧基部分的尿素，硫脲，缩二脲，二硫代脂肪族，酰胺或硫代酰胺部分。还公开了由亚胺和仲胺制备的预聚物和聚合物。此外，本发明的亚胺和仲胺也可用作环氧树脂固化剂。

82. 发明授权

US5055544A Amino-functional polyesters containing urea, biuret, thiourea, dithiobiuret, thioamide, and/or amide moieties in their backbone and urethane/urea prepolymers and polymers made therefrom 失效
标题翻译：在其主链中含有尿素，缩二脲，硫脲，二硫代比例脲，硫代酰胺和/或酰胺部分的氨基官能聚酯和由其制备的氨基甲酸酯/脲预聚物和聚合物
公开(公告)号：US5055544A
公开(公告)日：1991-10-08
申请号：US485678
申请日：1990-02-27
申请人： Robert F. Harris , Michael D. Joseph
发明人： Robert F. Harris , Michael D. Joseph
IPC分类号： C08G18/50 , C08G71/02
CPC分类号： C08G18/5024 , C08G18/5036 , C08G18/5072 , C08G71/02 , C08G2120/00
摘要： This invention relates to novel polymeric polyamines containing internal urea, biuret, thiourea, dithiobiuret, amide, and/or thioamide moieties, and to polymers prepared therefrom. This invention also relates to novel isocyanate-functional prepolymers containing urea, biuret, thiourea, dithiobiuret, amide, and/or thioamide moieties and to polymers prepared therefrom.
摘要翻译：本发明涉及含有内部尿素，缩二脲，硫脲，二硫代比例尿素，酰胺和/或硫代酰胺部分的新型聚合多胺，以及由其制备的聚合物。本发明还涉及含有尿素，缩二脲，硫脲，二硫代嘌呤，酰胺和/或硫代酰胺部分的新型异氰酸酯官能预聚物和由其制备的聚合物。

83. 发明授权

US4927864A Use of a polyamine as cell opener in polyurethane foam 失效
标题翻译：在聚氨酯泡沫中使用多胺作为开孔剂
公开(公告)号：US4927864A
公开(公告)日：1990-05-22
申请号：US304750
申请日：1989-01-31
申请人： Kurt C. Frisch, Jr. , Robert F. Harris
发明人： Kurt C. Frisch, Jr. , Robert F. Harris
IPC分类号： C08G18/38 , C08G18/50
CPC分类号： C08G18/5072 , C08G18/3823 , C08G18/3859 , C08G18/5036 , C08G2101/0008 , C08G2101/005 , C08G2101/0058 , C08G2101/0083
摘要： This invention relates to the use of polyamine compounds having their backbone modified by the incorporation of aminocarbonyl or aminothiocarbonyl moieties as cell opening agents in the preparation of open-celled flexible polyurethane foams.Use of the polyamine compound as cell opening agent provides for improved cell opening and provides foam with acceptable physical properties.
摘要翻译：本发明涉及其主链通过掺入氨基羰基或氨基硫代羰基部分作为开孔剂在开孔软质聚氨酯泡沫塑料制备中的用途。多胺化合物作为细胞开放剂的使用提供了改善的细胞开放性，并提供可接受的物理性质的泡沫。

84. 发明授权

US4753825A Vapor permeation curable coatings comprising polymercaptan resins and multi-isocyanate curing agents 失效
标题翻译：包含聚合硫醇树脂和多异氰酸酯固化剂的透气固化涂层
公开(公告)号：US4753825A
公开(公告)日：1988-06-28
申请号：US905700
申请日：1986-09-09
申请人： Gary L. Linden , Brent A. Blakley
发明人： Gary L. Linden , Brent A. Blakley
IPC分类号： C08G18/18 , C08G18/38 , C08G18/40 , C08G18/46 , C08G18/50 , B05D1/04 , B05D1/06
CPC分类号： C08G18/3876 , C08G18/1891 , C08G18/40 , C08G18/4676 , C08G18/5072
摘要： Disclosed is a method for curing a film of a coating composition under vapor permeation curable conditions. Such method comprises exposing a coating composition to a vaporous tertiary amine catalyst. The coating composition can be in the form of an atomizate which is concurrently generated and mixed with a vaporous tertiary amine catalyst followed by application to a substrate, or can be an applied film of the coating composition which is exposed to the vaporous tertiary amine catalyst. The coating composition comprises a polymercapto-compound and a multi-isocyanate curing agent. The coating composition can be formulated to contain very high solids content (e.g. in excess of 70% and on up to 100% non-volatile solids).
摘要翻译：公开了一种在蒸气渗透固化条件下固化涂料组合物的膜的方法。这种方法包括将涂料组合物暴露于气态叔胺催化剂。涂料组合物可以是雾化物的形式，其同时产生并与蒸气叔胺催化剂混合，然后施加到基材上，或者可以是暴露于蒸气叔胺催化剂的涂料组合物的涂布膜。涂料组合物包含聚合物巯基化合物和多异氰酸酯固化剂。涂料组合物可以配制成含有非常高的固体含量（例如超过70％，高达100％的非挥发性固体）。

85. 发明授权

US4133820A Perfluoroalkyl monoesters of anhydride 2,3,4,5-tetrahydrofurantetracarboxylic acid 失效
标题翻译：酸酐2,3,4,5-四氢呋喃四羧酸的全氟烷基单酯
公开(公告)号：US4133820A
公开(公告)日：1979-01-09
申请号：US828460
申请日：1977-08-29
申请人： Karl F. Mueller
发明人： Karl F. Mueller
IPC分类号： C08K5/00 , B05D7/26 , C07D307/60 , C07D307/77 , C07D307/89 , C07D307/93 , C07D407/12 , C07D493/04 , C07D493/06 , C08F8/00 , C08G12/00 , C08G12/40 , C08G18/00 , C08G18/10 , C08G18/50 , C08G18/83 , C08G63/00 , C08G63/46 , C08G63/52 , C08G65/32 , C08G77/00 , C08G77/22 , C08G77/38 , C08J5/12 , C08K5/10 , C08K5/12 , C08K5/16 , C08K5/37 , C08K5/372 , C08K5/5419 , C08L33/00 , C08L33/02 , C08L33/04 , C08L67/00 , C08L75/00 , C08L75/04 , C08L81/04 , C09D5/02 , C09D7/00 , C09D7/12 , C09D133/04 , C09D167/00 , C09K3/00 , C09K3/18 , D06M13/213
CPC分类号： C07D493/04 , C07C323/00 , C07D307/89 , C07D307/93 , C08G18/10 , C08G18/5072 , C08K5/12 , C08K5/16 , C08K5/37 , C08K5/372 , C09D5/024 , D06M13/213
摘要： This invention describes new perfluoroalkyl substituted esters, diesters and polyesters which contain at least one cyclic 5-membered anhydride group or two carboxy groups, as well as half amides and half esters thereof; their synthesis and their use as surface-active reactants in polycondensate resin systems.The anhydrides are synthesized by reaction of perfluoroalkyl substituted alcohols or diols with dianhydrides or an anhydrides-acid chloride and have the general structure ##STR1## wherein: Q is the tetra-radical rest of a tri- or tetracarboxylic acid, which contains at least one 1,2-dicarboxy grouping,X is hydrogen or COOH,R.sub.f is perfluoroalkyl or perfluoroalkoxyperfluoroalkyl group of 4 to 18 carbon atoms,A is 1 or 2,A is hydrogen or ##STR2## wherein: m is an integer from 0 to 5, and R.sup.3 is the residue of a R.sub.f substituted alcohol or diol.
摘要翻译：本发明描述了新的全氟烷基取代的酯，二酯和聚酯，其含有至少一个环状5元酸酐基团或两个羧基，以及其半酰胺和半酯; 它们的合成及其在缩聚树脂体系中作为表面活性反应物的用途。

86. 发明授权

US4058537A Esters of anhydride aromatic polycarboxylic acids with perfluoroalkyl alcohols 失效
标题翻译：酸酐芳族多元羧酸与全氟烷基醇的酯
公开(公告)号：US4058537A
公开(公告)日：1977-11-15
申请号：US646689
申请日：1976-01-05
申请人： Karl Friedrich Mueller
发明人： Karl Friedrich Mueller
IPC分类号： C08K5/00 , B05D7/26 , C07D307/60 , C07D307/77 , C07D307/89 , C07D307/93 , C07D407/12 , C07D493/04 , C07D493/06 , C08F8/00 , C08G12/00 , C08G12/40 , C08G18/00 , C08G18/10 , C08G18/50 , C08G18/83 , C08G63/00 , C08G63/46 , C08G63/52 , C08G65/32 , C08G77/00 , C08G77/22 , C08G77/38 , C08J5/12 , C08K5/10 , C08K5/12 , C08K5/16 , C08K5/37 , C08K5/372 , C08K5/5419 , C08L33/00 , C08L33/02 , C08L33/04 , C08L67/00 , C08L75/00 , C08L75/04 , C08L81/04 , C09D5/02 , C09D7/00 , C09D7/12 , C09D133/04 , C09D167/00 , C09K3/00 , C09K3/18 , D06M13/213
CPC分类号： C07D493/04 , C07C323/00 , C07D307/89 , C07D307/93 , C08G18/10 , C08G18/5072 , C08K5/12 , C08K5/16 , C08K5/37 , C08K5/372 , C09D5/024 , D06M13/213
摘要： This invention describes new perfluoroalkyl substituted esters, diesters and polyesters which contain at least one cyclic 5-membered anhydride group or two carboxy groups, as well as half amides and half esters thereof; their synthesis and their use as surface-active reactants in polycondensate resin systems.The anhydrides are synthesized by reaction of perfluoroalkyl substituted alcohols or diols with dianhydrides or an anhydrides-acid chloride and have the general structure ##STR1## wherein: Q is the tetra-radical rest of a tri- or tetracarboxylic acid, which contains at least one 1,2-dicarboxy grouping,X is hydrogen or COOH,R.sub.f is a perfluoroalkyl or perfluoroalkoxy-perfluoroalkyl group of 4 to 18 carbon atoms,a is 1 or 2,A is hydrogen or ##STR2## wherein: M IS AN INTEGER FROM 0 TO 5, ANDR.sup.3 is the residue of a R.sub.f substituted alcohol or diol.
摘要翻译：本发明描述了新的全氟烷基取代的酯，二酯和聚酯，其含有至少一个环状5元酸酐基团或两个羧基，以及其半酰胺和半酯; 它们的合成及其在缩聚树脂体系中作为表面活性反应物的用途。

87. 发明授权

US3808250A Polyethers containing terminal amino groups 失效
标题翻译：包含末端氨基酸的聚醚
公开(公告)号：US3808250A
公开(公告)日：1974-04-30
申请号：US13484171
申请日：1971-04-16
申请人： BAYER AG
发明人： KLEIMANN H , MUEHLHAUSEN C , BLAHAK J , MUELLER E
IPC分类号： C08G18/00 , C08G18/50 , C08G18/52 , C07C153/07
CPC分类号： C08G18/52 , C08G18/5027 , C08G18/5072
摘要： COMPOUNDS HAVING TERMINAL AMINO GROUPS AND THE GENERAL FORMULA

((2-NH2-PHENYL)-CO-X-)N-R

WHEREIN N IS AN INTEGER OF FROM 2 TO 8, X IS OXYGEN OR SULPHUR, AND R IS AN N-VALENT RADICAL OBTAINED BY THE REMOVAL OF HYDROXYL GROUPS OR MERCAPTO GROUPS FROM AN N-VALENT POLYALKYLENE ETHER POLYOL OF MOLECULAR WEIGHT 600 TO 10,000 OR FROM AN N-VALENT ALKYLENE THIOETHER POLYTHIOL OF MOLECULAR WEIGHT 600 TO 10,000. THESE COMPOUNDS ARE PREPARED BY REACTION POLYOLS WITH ISATOIC ACID, ANHYDRIDE AND ARE USEFUL IN REACTION WITH ORGANIC POLYISOCYANATES TO PREPARE ALL TYPE OF POLYURETHANE POLYMERS.

88. 发明授权

US3498936A Hydroxyalkylated phenol-sulfur halide resins and polyurethanes containing same 失效
标题翻译：羟基烷基酚硫化物树脂和含有它的聚氨酯
公开(公告)号：US3498936A
公开(公告)日：1970-03-03
申请号：US3498936D
申请日：1967-11-27
申请人： HOOKER CHEMICAL CORP
发明人： WILSON BRUCE N
IPC分类号： C08G18/38 , C08G18/50 , C08G18/64 , C08G75/02 , C08L67/00 , C08L75/04 , C08G22/16
CPC分类号： C07C323/00 , C08G18/3878 , C08G18/5072 , C08G18/6453 , C08G75/02 , C08L67/00 , C08L2666/14

89. 发明申请

WO2017100459A1 CURE-ON-DEMAND MOISTURE-CURABLE URETHANE-CONTAINING FUEL RESISTANT PREPOLYMERS AND COMPOSITIONS THEREOF 审中-公开
标题翻译：按需固化的可湿固化的含氨基的抗燃料预聚物及其组合物
公开(公告)号：WO2017100459A1
公开(公告)日：2017-06-15
申请号：PCT/US2016/065637
申请日：2016-12-08
申请人： PRC-DESOTO INTERNATIONAL, INC.
发明人： KELEDJIAN, Raquel , LIN, Renhe
IPC分类号： C08G18/75 , C08G75/045 , C08G18/50 , C08G18/38 , C08G18/28 , C08L75/00 , C08L101/10 , C08G18/10 , C08G18/12 , C08L81/02 , C08K9/10 , C08G18/52
CPC分类号： C08G18/758 , C08G18/10 , C08G18/12 , C08G18/289 , C08G18/3868 , C08G18/5072 , C08G18/52 , C08G75/045 , C08G2190/00 , C08K9/10 , C08L75/00 , C08L81/02 , C08L101/10 , C08G18/307
摘要： Cure-on-demand, moisture-curable, urethane-containing prepolymers having urethanes incorporated into a sulfur-containing prepolymer backbone and compositions thereof for use in sealant applications are disclosed. The cure-on-demand moisture-curable urethane-containing prepolymers are terminated with polyalkoxysilyl groups. The compositions contain a controlled-release moisture cure catalyst. Compositions containing the prepolymers provide cured sealants exhibiting improved tensile strength.
摘要翻译：公开了具有并入含硫预聚物主链中的氨基甲酸乙酯的含固化聚氨酯的预聚合物，以及用于密封剂应用的其组合物。按需固化的可湿固化含氨基甲酸酯预聚物用聚烷氧基甲硅烷基基团封端。该组合物含有控释湿固化催化剂。含有预聚物的组合物提供了固化的密封剂，其显示出改善的拉伸强度。

90. 发明申请

WO2015085277A1 POLYSULFIDE AND POLYFLUOROETHER COPOLYMER COMPOSITIONS 审中-公开
标题翻译：聚砜和聚氟乙烯共聚物组合物
公开(公告)号：WO2015085277A1
公开(公告)日：2015-06-11
申请号：PCT/US2014/068957
申请日：2014-12-06
申请人： HRL LABORATORIES, LLC
发明人： NOWAK, Andrew
IPC分类号： C08G75/14 , C08G65/32 , C08G65/48 , C08G18/83
CPC分类号： C08G18/5015 , C08G18/3206 , C08G18/5072 , C08G18/73 , C08G18/758 , C08G2190/00 , C09K3/1012 , C09K3/1021
摘要： Novel segmented polysulfide-polyfluoroether copolymers are disclosed. In particular, a polyurethane segmented copolymer composition is provided, comprising one or more polyurethane/urea hard segments, one or more polysulfide soft segments, one or more polyfluoroether soft segments, isocyanate species or derivatives thereof contained in each of the segments, and one or more curatives. The polysulfide soft segments and the polyfluoroether soft segments are together about 50 wt% to about 95 wt% of the copolymer. The weight ratio of the polysulfide soft segments to the polyfluoroether soft segments is from about 0.1 to about 10. The polyfluoroether soft segments are characterized by a glass-transition temperature of about -85°C or lower. These copolymers are useful in elastomers for improved fluid resistance, substrate adhesion, and low-temperature flexibility. These properties are desirable for sealants and other applications.
摘要翻译：公开了新的分段多硫醚 - 聚氟醚共聚物。特别地，提供了一种聚氨酯分段共聚物组合物，其包含一个或多个聚氨酯/脲硬链段，一个或多个多硫化物软链段，一个或多个多氟醚软链段，每个链段中包含的异氰酸酯物质或其衍生物，以及一个或多个更多的治疗药多硫化物软链段和多氟醚软链段共聚合约50重量％至约95重量％。多硫化物软链段与多氟醚软链段的重量比为约0.1至约10.多氟醚软链段的特征在于-85℃或更低的玻璃化转变温度。这些共聚物可用于弹性体以改善流体阻力，底物粘附性和低温柔韧性。这些性能对于密封剂和其它应用是理想的。

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