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81. 发明申请

US20140194276A1 Process for Obtaining a Catalyst Composite 审中-公开
标题翻译：获得催化剂复合材料的方法
公开(公告)号：US20140194276A1
公开(公告)日：2014-07-10
申请号：US14206329
申请日：2014-03-12
申请人： Total Research & Technology Feluy
发明人： Nikolai Nesterenko , Walter Vermeiren , Sander Van Donk , Delphine Minoux
IPC分类号： B01J29/06 , B01J29/40 , B01J23/00
CPC分类号： C07C1/20 , B01J21/16 , B01J23/00 , B01J27/16 , B01J29/06 , B01J29/08 , B01J29/40 , B01J29/60 , B01J29/65 , B01J29/7007 , B01J29/7026 , B01J29/7038 , B01J29/7046 , B01J37/10 , B01J37/28 , B01J2029/081 , B01J2229/16 , B01J2229/186 , B01J2229/42 , C07C4/06 , C07C2529/40 , C08F10/06 , Y02P30/42 , C07C11/02
摘要： A process for obtaining a catalyst composite comprising the following steps: a). selecting a molecular sieve having pores of 10-or more-membered rings b). contacting the molecular sieve with a metal silicate different from said molecular sieve comprising at least one alkaline earth metal and one or more of the following metals: Ga, Al, Ce, In, Cs, Sc, Sn, Li, Zn, Co, Mo, Mn, Ni, Fe, Cu, Cr, Ti and V, such that the composite comprises at least 0.1 wt % of silicate.
摘要翻译：一种获得催化剂复合材料的方法，包括以下步骤：a）。选择具有10或更多元环孔的分子筛b）。使分子筛与不同于包含至少一种碱土金属和一种或多种以下金属的分子筛的金属硅酸盐接触：Ga，Al，Ce，In，Cs，Sc，Sn，Li，Zn，Co，Mo ，Mn，Ni，Fe，Cu，Cr，Ti和V，使得复合材料包含至少0.1重量％的硅酸盐。

82. 发明申请

US20120283465A1 Oligomerisation Process 有权
标题翻译：低聚过程
公开(公告)号：US20120283465A1
公开(公告)日：2012-11-08
申请号：US13510501
申请日：2010-11-23
申请人： Paul Hamilton , John S. Godsmark , David E. Heather
发明人： Paul Hamilton , John S. Godsmark , David E. Heather
IPC分类号： C07C67/303 , C07C29/04 , C07C2/04
CPC分类号： B01J29/40 , B01J29/7026 , B01J29/7042 , B01J29/80 , B01J29/90 , B01J35/0006 , C07C2/12 , C08F110/06 , C08F210/16 , C10G50/00 , C10G2300/1088 , C10G2300/4031 , C10G2400/20 , C10G2400/22 , Y02P20/584 , C07C11/02 , C08F2500/02 , C08F210/08
摘要： The startup of a tubular reactor containing fresh or regenerated molecular sieve catalyst and cooled by steam generation on the shell side, as part of an olefin oligomerisation process, is improved by, during the startup phase of the reactor, controlling the pressure on the shell side of the reactor at maximum 10 barg. The startup may be further improved by controlling the inlet temperature of the hydrocarbon startup stream to the reactor, by controlling the flow of reactant olefins to the reactor, or by controlling the nature and/or concentration of the olefins in the reactor feed.
摘要翻译：包含新鲜或再生的分子筛催化剂的管式反应器的启动并且通过在壳侧的蒸汽产生而被冷却，作为烯烃低聚方法的一部分，通过在反应器的启动阶段中控制壳侧的压力来改进的反应器最大10巴。通过控制反应物烯烃进入反应器的流量，或通过控制反应器进料中烯烃的性质和/或浓度来控制通向反应器的烃启动流的入口温度，可以进一步改进启动。

83. 发明授权

US07976822B2 Crystalline oxide material and its synthesis 失效
标题翻译：结晶氧化物材料及其合成
公开(公告)号：US07976822B2
公开(公告)日：2011-07-12
申请号：US11667922
申请日：2004-11-19
申请人： Raman Ravishankar , Elango Shanmugam
发明人： Raman Ravishankar , Elango Shanmugam
IPC分类号： C01B39/04 , C01B39/48
CPC分类号： B01J29/7026 , C01B39/48
摘要： Zeolites may be natural or synthetic and are inorganic crystalline aluminosilicates, with a highly regular structure of pores and channels rendering them suitable for molecular sieving, adsorption, ion exchange, dehydration, and rehydration processes for example. They generally have a definite crystalline structure as evidenced by x-ray diffraction. The present invention relates to the area of zeolites and its method of production. More particularly but not exclusively it relates to a novel zeolite ICS-3 in its “as synthesized” and its calcined forms and the method of producing both these forms.
摘要翻译：沸石可以是天然的或合成的，并且是无机结晶硅铝酸盐，具有高度规则的孔和通道结构，使得它们适合于分子筛，吸附，离子交换，脱水和再水化过程。它们通常具有确定的晶体结构，如通过X射线衍射所证明的。本发明涉及沸石的面积及其制备方法。更特别但不排他地涉及其“合成”及其煅烧形式的新型沸石ICS-3以及这两种形式的生产方法。

84. 发明申请

US20080039669A1 Olefin Oligomerization Process 有权
标题翻译：烯烃低聚过程
公开(公告)号：US20080039669A1
公开(公告)日：2008-02-14
申请号：US11596168
申请日：2005-05-26
申请人： Stephen Brown , John Godsmark , Georges Mathys
发明人： Stephen Brown , John Godsmark , Georges Mathys
IPC分类号： C07C2/12
CPC分类号： B01J29/7042 , B01J29/06 , B01J29/7026 , B01J29/703 , B01J29/7046 , B01J37/0009 , B01J2229/42 , C07C2/12 , C07C2529/70 , C07C2529/80 , C10G50/00 , C07C11/02
摘要： In a process for oligomerizing an olefinic hydrocarbon feedstock comprising at least 65 wt % olefins and/or sulfur-containing molecules, the feedstock is contacted under oligomerization conditions with (a) a first unidimensional 10-ring molecular sieve catalyst and (b) a second multidimensional crystalline molecular sieve catalyst. The first and second catalysts may be contained in separate reactors or as separate beds in a single reactor.
摘要翻译：在包含至少65重量％的烯烃和/或含硫分子的烯烃原料低聚的方法中，原料在低聚条件下与（a）第一单维10环分子筛催化剂接触，（b）第二多维结晶分子筛催化剂。第一和第二催化剂可以包含在单独的反应器中或作为单个反应器中的分离床。

85. 发明申请

US20070191654A1 Oligomerization and catalysts therefor 有权
标题翻译：低聚和催化剂
公开(公告)号：US20070191654A1
公开(公告)日：2007-08-16
申请号：US11651160
申请日：2007-01-09
申请人： Jihad Dakka , Hans Goris , Georges Mathys , Roger Eijkhoudt , Marc Puttemans , Stephen Brown
发明人： Jihad Dakka , Hans Goris , Georges Mathys , Roger Eijkhoudt , Marc Puttemans , Stephen Brown
IPC分类号： C07C13/00 , C07C2/02
CPC分类号： B01J29/7042 , B01J29/7026 , B01J29/80 , B01J37/20 , B01J2229/186 , B01J2229/34 , C07C2/12 , C07C2529/70
摘要： Sulphur-containing olefinic feedstocks are oligomerized over zeolite catalysts.
摘要翻译：含硫烯烃原料在沸石催化剂上低聚。

86. 发明授权

US06974889B1 Processes for manufacture of molecular sieves 有权
标题翻译：分子筛制造工艺
公开(公告)号：US06974889B1
公开(公告)日：2005-12-13
申请号：US09744697
申请日：1999-07-28
申请人： Jannetje Maatje van den Berge, legal representative , Machteld Maria Wilfried Mertens , Wilfried Jozef Mortier , Marcel Johannes Janssen , Cornelius Maria Wilhelmus Van Oorschot
发明人： Johannes Petrus Verduijn, deceased
IPC分类号： B01D53/02 , B01J20/18 , B01J29/18 , B01J29/65 , B01J29/70 , B01J29/85 , B01J35/00 , C01B37/00 , C01B37/04 , C01B37/06 , C01B37/08 , C01B39/02 , C01B39/26 , C01B39/44 , C01B39/46 , C01B39/48 , C01B39/54 , C01G3/00 , C07B61/00 , C07C1/24 , C07C11/04 , C07C11/06 , C07C11/08 , C10G3/00 , C01B25/26 , B01J27/16 , B01J27/182 , C01B33/26 , C07C1/207
CPC分类号： B01J29/7026 , B01J20/0292 , B01J20/18 , B01J29/18 , B01J29/50 , B01J29/65 , B01J29/7011 , B01J29/7023 , B01J29/85 , B01J35/0013 , B01J2229/62 , C01B37/00 , C01B37/04 , C01B37/06 , C01B37/08 , C01B39/02 , C01B39/265 , C01B39/44 , C01B39/445 , C01B39/48 , C01G3/00 , C10G3/49 , C10G25/03 , C10G2400/20 , C10G2400/22 , Y02P30/20
摘要： Colloidal crystalline molecular sieve seeds are used in phosphorus-containing crystalline molecular sieve manufacture. Certain of the products have enhanced utility in oxygenate conversions.
摘要翻译：胶态结晶分子筛种子用于含磷结晶分子筛制造。某些产品具有提高氧合转化率的效用。

87. 发明申请

US20050013774A1 Crystalline molecular sieves 有权
标题翻译：结晶分子筛
公开(公告)号：US20050013774A1
公开(公告)日：2005-01-20
申请号：US10490537
申请日：2002-09-27
申请人： Jihad Dakka , Machteld Mertens , Daria Lissy
发明人： Jihad Dakka , Machteld Mertens , Daria Lissy
IPC分类号： B01J20/18 , B01J29/70 , C01B39/48
CPC分类号： B01J29/7026 , B01J20/18 , B01J2229/26 , B01J2229/42 , C01B39/48
摘要： MFS structure type zeolite manufacture is facilitated by using a second organic molecule in addition to the usual hexaethylpentane diammonium salt.
摘要翻译：除了通常的六乙基戊烷二铵盐之外，通过使用第二有机分子来促进MFS结构型沸石的制备。

88. 发明授权

US06821503B1 Molecular sieves and processes for their manufacture 有权
标题翻译：分子筛及其制造方法
公开(公告)号：US06821503B1
公开(公告)日：2004-11-23
申请号：US09744715
申请日：2001-08-10
申请人： Johannes Petrus Verduijn , Machteld Maria Wilfried Mertens , Wilfried Jozef Mortier , Marcel Johannes Janssen , Cornelis Wilhelmus Maria Van Oorschot , David E. W. Vaughan
发明人： Johannes Petrus Verduijn , Machteld Maria Wilfried Mertens , Wilfried Jozef Mortier , Marcel Johannes Janssen , Cornelis Wilhelmus Maria Van Oorschot , David E. W. Vaughan
IPC分类号： C01B3902
CPC分类号： B01J29/06 , B01J20/18 , B01J29/18 , B01J29/65 , B01J29/70 , B01J29/7026 , B01J29/7042 , B01J29/85 , B01J35/0013 , B01J37/02 , C01B37/00 , C01B37/04 , C01B37/06 , C01B37/08 , C01B39/02 , C01B39/265 , C01B39/44 , C01B39/445 , C01B39/48 , C01G3/00 , C10G3/49 , C10G2400/20 , C10G2400/22 , Y02P30/20
摘要： Crystalline molecular sieve particles of a size suitable for use as seeds in molecular sieve manufacture are obtained by washing larger particle sized product to dislodge smaller particles from the larger.
摘要翻译：通过洗涤较大粒度的产品以从较大的颗粒中去除更小的颗粒，获得适合用作分子筛制造中的种子的尺寸的结晶分子筛颗粒。

89. 发明授权

US5258114A Ultra large pore cracking catalyst and process for catalytic cracking 失效
标题翻译：超大孔裂解催化剂及催化裂化工艺
公开(公告)号：US5258114A
公开(公告)日：1993-11-02
申请号：US735227
申请日：1991-07-24
申请人： Brent A. Aufdembrink , Arthur W. Chester , Joseph A. Herbst , Charles T. Kresge
发明人： Brent A. Aufdembrink , Arthur W. Chester , Joseph A. Herbst , Charles T. Kresge
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： B01J29/005 , B01D53/8628 , B01J20/16 , B01J20/18 , B01J29/04 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42 , B01J29/084 , B01J29/405 , B01J29/65 , B01J29/7026 , B01J29/703 , B01J29/7034 , B01J29/7038
摘要： A process and catalyst for catalytic cracking comprising a non-layered, ultra-large pore crystalline material. The crystalline material preferably has a benzene adsorption capacity greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C. Preferred materials have a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units and a hexagonal arrangement of uniformly sized pores with a maximum perpendicular cross section of at least about 13 Angstrom units. Preferred cracking catalysts comprise ultra-large pore materials having pore openings formed by at least 20 tetrahedrally coordinated members, most preferably with 36 or 42 tetahedrally coordinated members.
摘要翻译：一种用于催化裂化的方法和催化剂，包括非层状的超大孔结晶材料。结晶材料优选在50托和25℃下具有大于约15克苯/ 100克的苯吸附能力。优选的材料具有六角形电子衍射图，其可以以大于约18埃单位的d100值进行索引，并且具有至少约13埃单位的最大垂直截面的均匀尺寸孔的六边形排列。优选的裂化催化剂包括具有由至少20个四面体配位的构件形成的孔隙的超大孔材料，最优选地具有36或42个四面体配位的构件。

90. 发明授权

US5110776A Cracking catalysts containing phosphate treated zeolites, and method of preparing the same 失效
标题翻译：含有磷酸盐处理的沸石的裂化催化剂及其制备方法
公开(公告)号：US5110776A
公开(公告)日：1992-05-05
申请号：US667853
申请日：1991-03-12
申请人： Girish K. Chitnis , Joseph A. Herbst
发明人： Girish K. Chitnis , Joseph A. Herbst
IPC分类号： B01J29/08 , B01J29/40 , B01J29/70 , B01J29/82 , C10G11/05
CPC分类号： B01J29/06 , B01J29/084 , B01J29/085 , B01J29/40 , B01J29/82 , C10G11/05 , B01J2229/186 , B01J2229/26 , B01J2229/42 , B01J29/7026 , B01J29/703 , B01J29/7042 , B01J29/7046
摘要： A process for preparing a zeolite containing catalyst which has improved attrition resistance, and causes improved octane with no appreciable change in dry gas and coke make when used during catalytic cracking processes is disclosed. The catalyst is prepared by modifying the zeolite with a phosphate containing solution. The zeolite preferably includes an REY large pore zeolite. Treatment of the zeolite is best accomplished in an aqueous solution, at a pH range from about 2 to about 6, containing a water soluble phosphate compound. The phosphate treatment of the zeolite is carried out by deagglomerating the zeolite in an aqueous mixture in the presence of an aqueous phosphate containing solution, such as an aqueous solution of ammonium monohydrogen phosphate. The aqueous mixture containing phosphate modified zeolite is then combined with matrix precursors to form a slurry. The slurry is preferably spray dried to form the catalyst having a diameter less than 200 microns. The novel catalyst is used in the catalytic cracking of hydrocarbons in an FCC, moving bed or other catalytic cracking apparatus. The catalyst can be used for treating resids in which the hydrocarbon feedstock has a higher average molecular weight, a lower API gravity and/or a higher metals content than gas oil.
摘要翻译：公开了一种制备含有催化剂的沸石的方法，其具有改善的耐磨性，并且在催化裂化过程中使用时，引起干燥气体和焦炭产生明显变化的改进的辛烷。通过用含磷酸盐溶液改性沸石制备催化剂。沸石优选包括REY大孔沸石。沸石的处理最好在含有水溶性磷酸盐化合物的约2至约6的pH范围的水溶液中完成。沸石的磷酸盐处理通过在含磷酸盐水溶液如磷酸一氢铵的水溶液的存在下，在含水混合物中使沸石分解进行。然后将含磷酸盐改性沸石的含水混合物与基质前体合并形成浆料。浆料优选喷雾干燥以形成直径小于200微米的催化剂。新型催化剂用于FCC，移动床或其他催化裂化装置中烃的催化裂化。催化剂可用于处理其中烃原料具有比瓦斯油更高的平均分子量，较低的API比重和/或更高的金属含量的残渣。

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